Compound, luminescent material, delayed fluorescent material, and organic optical device

ABSTRACT

The compound represented by the following formula is useful as a light-emitting material. R 1  or R 2  is Het-L A -* or CN-L A -*; one to three of R 1  to R 5  are diarylamino groups; the rest are a hydrogen atom or an aryl group; Het is a heteroaryl group; and L A  is a single bond or an arylene group.

TECHNICAL FIELD

The present invention relates to a compound having good luminescence characteristics. Further, the present invention also relates to a light-emitting material using the compound, a delayed fluorescence material, and an organic optical device.

BACKGROUND ART

Research has been actively conducted to improve the luminous efficiency of organic optical devices such as organic light emitting diodes (OLEDs). For example, in relation to the material of a light emitting layer, research on the use of compounds in which inverse intersystem crossing can be caused from an excited triplet state to an excited singlet state have been energetically conducted. When a normal fluorescent light-emitting material is current-excited at room temperature, singlet excitons and triplet excitons are generated with a probability of 25:75. Among these, the singlet excitons are radiatively deactivated to a ground singlet state and emit fluorescence. Whereas the triplet excitons have a long lifetime, and thus lose energy due to thermal radiation prior to transition to a ground state and are deactivated without radiation. Therefore, the energy of triplet excitons having a high generation probability cannot be effectively used for light emission. On the other hand, in compounds in which inverse intersystem crossing can be caused from the excited triplet state to the excited singlet state, since singlet excitons generated by inverse intersystem crossing from the excited triplet state to the excited singlet state also emit fluorescence during the transition to the ground singlet state, the energy of triplet excitons having a high generation probability can also be indirectly allowed to contribute to the fluorescence emission. Therefore, a significantly high luminous efficiency can be expected as compared to in the case where the normal fluorescent light-emitting material not causing inverse intersystem crossing is used.

As for an organic optical device using a compound capable of causing such inverse intersystem crossing, many things having a single light emitting layer formed by co-depositing a thermal activation-type delayed fluorophore and a host material have been suggested (see, for example, Patent Document 1). Here, the thermal activation-type delayed fluorophore is a compound in which inverse intersystem crossing occurs from the excited triplet state to the excited singlet state due to absorption of heat energy. After the fluorescence radiation from the singlet excitons directly excited from the ground singlet state is observed, the fluorescence radiation (delayed fluorescence radiation) from the singlet excitons generated via the inverse intersystem crossing is observed with a delay.

CITATION LIST Patent Literature

-   Patent Document 1: WO2018/237393

SUMMARY OF INVENTION Technical Problem

However, in the conventionally suggested light-emitting material, there is room for further improvement in terms of luminous efficiency. Thus, the present inventors, etc. have found a light-emitting material having good luminescence characteristics, and have conducted intensive studies for the purpose of providing an organic optical device having high luminous efficiency.

Solution to Problem

The present inventors, etc. have conducted intensive studies, and as a result, have found that a compound having a specific structure has excellent luminescence characteristics. The present invention is suggested on the basis of such findings, and has the following configurations.

[1] A compound represented by the following formula (1).

[In the formula (1), among R¹ to R⁵,

one of R¹ and R² is A,

among the rest of R¹ to R⁵, p are D's, and

the remaining 4-p are R's.

Here,

A is a group represented by Het-L^(A)-* or CN-L^(A)-*, in which Het represents a substituted or unsubstituted heteroaryl group bonded via a carbon atom (meanwhile, at least one nitrogen atom is included as a ring skeleton-forming atom of the heteroaryl group), L^(A) represents a single bond or a substituted or unsubstituted arylene group, and * represents a bond position.

D is a group represented by the following formula (IIa), (IIb), (IIc) or (IId).

Here, X′ represents N—R^(D)′, an oxygen atom, or a sulfur atom, each R^(D) independently represents a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted amino group, a cyano group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted heteroaryl group, a substituted or unsubstituted heteroaryloxy group or a silyl group, and two or more R^(D)'s may be bonded to each other to form a cyclic structure,

R^(D)′ represents a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted amino group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heteroaryl group, and R^(D)′ may be bonded to one or more R^(D)'s to form a cyclic structure,

each L^(D) independently represents a single bond, a substituted or unsubstituted arylene group, or a substituted or unsubstituted heteroarylene group, and

* represents a bond position.

R is a hydrogen atom, a deuterium atom, or a substituted or unsubstituted aryl group (but, other than a group that may be A or D).

p is any integer of 1 to 3. When p is 2 or 3. D's present in the molecule may be the same or different. When p is 1 or 2. R's present in the molecule may be the same or different.]

[2] The compound described in [1], in which R² is A.

[3] The compound described in [1], in which R¹ is A.

[4] The compound described in any one of [1] to [3], in which at least one of R¹ to R⁵ is a hydrogen atom or a deuterium atom.

[5] The compound described in [2], in which R² is A. and moreover, at least one of R¹ and R³ is a hydrogen atom or a deuterium atom.

[6] The compound described in [3], in which R¹ is A. and moreover, R² is a hydrogen atom or a deuterium atom.

[7] The compound described in any one of [1] to [6], in which p is 3.

[8] The compound described in [7], in which R is a hydrogen atom or a deuterium atom.

[9] The compound described in any one of [1] to [6], in which p is 2.

[10] The compound described in [9], in which one of two R's is a hydrogen atom or a deuterium atom, and the other is a substituted or unsubstituted aryl group (but, other than a group that may be A or D).

[11] The compound described in [9], in which each of two R's is independently a hydrogen atom or a deuterium atom.

[12] The compound described in any one of [1] to [11], in which each of R⁴ and R⁵ is independently D.

[13] The compound described in any one of [1] to [11], in which one of R⁴ and R⁵ is D, and the other is a substituted or unsubstituted aryl group (but, other than a group that may be A or D).

[14] The compound described in any one of [1] to [13], in which A is Het-L^(A)-.

[15] The compound described in [14], in which A is represented by any of the following formulas (IIIa) to (IIIe).

[In the formulas (IIIa) to (IIIe), each of R²¹ to R²⁵ independently represents a hydrogen atom or a substituent. R²¹ and R²², R²² and R²³, R²³ and R²⁴, and R²⁴ and R²⁵ may be bonded to each other to form cyclic structures. L^(A) represents a single bond or a substituted or unsubstituted arylene group.]

[16] The compound described in [14] or [15], in which Het is not a dialkylphenyl-1,3,5-triazinyl group.

[17] The compound described in [16], in which L^(A) is a single bond.

[18] The compound described in any one of [1] to [17], in which D is a group represented by the formula (IIb).

[19] A light-emitting material including the compound described in any one of [1] to [18].

[20] A delayed fluorescence material including the compound described in any one of [1] to [18].

[21] An organic optical device including the compound described in any one of [1] to [18].

[22] The organic optical device described in [21], in which the device has a layer containing the compound, and the layer also contains a host material.

[23] The organic optical device described in [21], in which the device has a layer containing the compound, and the layer also contains a light-emitting material.

[24] The organic optical device described in any one of [21] to [23], in which among the materials contained in the device, the compound emits the maximum amount of light.

[25] The organic optical device described in [23], in which the amount of light emitted from the light-emitting material is larger than the amount of light emitted from the compound.

[26] The organic optical device described in any one of [21] to [25], which is an organic light emitting diode (OLED).

[27] The organic optical device described in any one of [21] to [26], which emits delayed fluorescence.

[28] A compound represented by the following formula (1′).

[In the formula (1′), R¹ to R⁵ satisfy the following condition 1 or condition 2.

(Condition 1) Among R¹ to R⁵,

one of R¹ and R² is a halogen atom,

among the rest of R¹ to R, p are D's, and

the remaining 4-p are R's.

(Condition 2) Among R¹ to R⁵,

one of R¹ and R² is A,

among the rest of R¹ to R⁵, p are halogen atoms, and

the remaining 4-p are R's.

Here,

A is a group represented by Het-L^(A)-* or CN-L^(A)-*, in which Het represents a substituted or unsubstituted heteroaryl group bonded via a carbon atom (meanwhile, at least one nitrogen atom is included as a ring skeleton-forming atom of the heteroaryl group), L^(A) represents a single bond or a substituted or unsubstituted arylene*group, and represents a bond position.

D is a group represented by the following formula (IIa), (IIb), (IIc) or (IId).

Here, X′ represents N—R^(D)′, an oxygen atom, or a sulfur atom,

each R^(D) independently represents a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted amino group, a cyano group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted heteroaryl group, a substituted or unsubstituted heteroaryloxy group or a silyl group, and two or more R^(D)'s may be bonded to each other to form a cyclic structure,

R^(D)′ represents a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heteroaryl group, and R^(D)′ may be bonded to one or more R^(D)'s to form a cyclic structure,

each L^(D) independently represents a single bond, a substituted or unsubstituted arylene group, or a substituted or unsubstituted heteroarylene group, and

* represents a bond position.

R is a hydrogen atom, a deuterium atom, or a substituted or unsubstituted aryl group (but, other than a group that may be A or D).

p is any integer of 1 to 3. When p is 2 or 3, D's present in the molecule may be the same or different. When p is 1 or 2, R's present in the molecule may be the same or different.]

[29] The compound described in [28], which satisfies the condition 1.

[30] The compound described in [29], in which p is 2.

[31] The compound described in [29] or [30], in which D is a group represented by the formula (lib).

[32] The compound described in any one of [29] to [31], in which the halogen atom is a chlorine atom or an iodine atom.

[33] The compound described in any one of [29] to [32], in which R is a substituted or unsubstituted aryl group.

[34] The compound described in [33], in which R is an unsubstituted phenyl group.

[35] The compound described in [28], which satisfies the condition 2.

[36] The compound described in [35], in which p is 2 or 3.

[37] The compound described in [35] or [36], in which A has a substituted or unsubstituted triazinyl group.

[38] The compound described in any one of [35] to [37], in which the halogen atom is a fluorine atom.

Advantageous Effects of Invention

According to the present invention, it is possible to provide a light-emitting material having good luminescence characteristics. Further, according to the present invention, it is possible to provide an organic optical device having high luminous efficiency.

DESCRIPTION OF EMBODIMENTS

Hereinafter, the contents of the present invention will be described in detail. The descriptions on constituent elements to be described below may be made on the basis of representative embodiments or specific examples of the present invention, but the present invention is not limited to such embodiments or specific examples. The numerical value range represented by using “to” in the present specification means a range including numerical values described before and after “to”, as the lower limit value and the upper limit value. The entire specification of Japanese Application No. 2020-017486, which is the basis of the priority claim of the present application, is cited herein as a part of the specification of the present application.

The present invention provides a compound represented by the following formula (1).

In the formula (1), among R¹ to R⁵, one of R¹ and R² is A, among the rest of R¹ to R⁵, p are D's, and the remaining 4-p are R's. Here, p is any integer of 1 to 3. In some embodiments, R² is A. In a preferred embodiment, R² is A, and moreover, at least one of R¹ and R³ is a hydrogen atom or a deuterium atom. For example, R² is A, R¹ is a hydrogen atom or a deuterium atom, and R³ is D or a substituted or unsubstituted aryl group (but, other than a group that may be A or D). For example, R² is A, R³ is a hydrogen atom or a deuterium atom, and R¹ is D or a substituted or unsubstituted aryl group (but, other than a group that may be A or D). For example, R² is A. and each of R¹ and R² is independently a hydrogen atom or a deuterium atom. In a preferred embodiment of the present invention, R² is A, and at least one of R⁴ and R⁵ is D. For example, R² is A, R⁴ is D. and R⁵ is R [more preferably a substituted or unsubstituted aryl group (but, other than a group that may be A or D)]. For example, R² is A, R⁵ is D, and R⁴ is R [more preferably, a substituted or unsubstituted aryl group (but, other than a group that may be A or D)]. For example, R² is A, and each of R⁴ and R⁵ is independently D. In a preferred embodiment of the present invention, R² is A, at least one of R¹ and R³ is a hydrogen atom or a deuterium atom, and at least one of R⁴ and R⁵ is D.

In some embodiments, R¹ is A. In a preferred embodiment, R¹ is A, and moreover, R² is a hydrogen atom or a deuterium atom. In another preferred embodiment, R¹ is A, and moreover, at least one of R⁴ and R⁵ is D. For example, R¹ is A, R⁴ is D, and R⁵ is R [more preferably a substituted or unsubstituted aryl group (but, other than a group that may be A or D)]. For example, R¹ is A, R⁵ is D, and R⁴ is R [more preferably, a substituted or unsubstituted aryl group (but, other than a group that may be A or D)]. For example, R¹ is A, and each of R⁴ and R⁵ is independently D. In a preferred embodiment of the present invention, R¹ is A, R² is a hydrogen atom or a deuterium atom, and at least one of R⁴ and R⁵ is D. Further, in some embodiments, R¹ is A, and R³ is R. For example, R¹ is A, and R³ is a hydrogen atom or a deuterium atom. For example, R¹ is A, and R³ is a substituted or unsubstituted aryl group (but, other than a group that may be A or D). Further, in some embodiments, R¹ is A, and R³ is D.

In some embodiments, R³ is a hydrogen atom or a deuterium atom. In some embodiments, R³ is a substituted or unsubstituted aryl group (but, other than a group that may be A or D). In some embodiments, R³ is D.

In some embodiments, at least one of R⁴ and R⁵ is D. In a preferred embodiment of the present invention, each of R⁴ and R⁵ is independently D. For example, R⁴ and R⁵ are the same D's. For example, R⁴ and R⁵ are different D's. In some embodiments, each of R¹, R⁴ and R⁵ is independently D. In some embodiments, each of R², R⁴ and R⁵ is independently D. In some embodiments, each of R³, R⁴ and R⁵ is independently D.

In some embodiments, at least one of R³ and R⁵ is D. For example, each of R³ and R⁵ is independently D. For example, R³ is D. and R⁵ is R [more preferably, a substituted or unsubstituted aryl group (but, other than a group that may be A or D)]. For example, R⁵ is D, and R³ is R [more preferably, a substituted or unsubstituted aryl group (but, other than a group that may be A or D)]. For example, R³ is D. and R⁵ is a hydrogen atom or a deuterium atom. For example, R⁵ is D, and R³ is a hydrogen atom or a deuterium atom.

In some embodiments, at least one of R¹ and R⁵ is D. For example, each of R¹ and R⁵ is independently D. For example, R¹ is D. and R⁵ is R [more preferably, a substituted or unsubstituted aryl group (but, other than a group that may be A or D)]. For example, R⁵ is D, and R¹ is R [more preferably, a substituted or unsubstituted aryl group (but, other than a group that may be A or D)]. For example, R⁵ is D, and R¹ is a hydrogen atom or a deuterium atom. For example, R¹ is D, and R⁵ is a hydrogen atom or a deuterium atom.

In some embodiments, at least one of R¹ and R⁴ is D. For example, each of R¹ and R⁴ is independently D. For example, R¹ is D. and R⁴ is R [more preferably, a substituted or unsubstituted aryl group (but, other than a group that may be A or D)]. For example, R⁴ is D. and R¹ is R [more preferably, a substituted or unsubstituted aryl group (but, other than a group that may be A or D)]. For example, R⁴ is D, and R¹ is a hydrogen atom or a deuterium atom. For example, R¹ is D, and R⁴ is a hydrogen atom or a deuterium atom.

In some embodiments, at least one of R¹, R⁴ and R⁵ is a substituted or unsubstituted aryl group (but, other than a group that may be A or D). In some embodiments, only one of R¹, R⁴ and R⁵ is a substituted or unsubstituted aryl group (but, other than a group that may be A or D). For example, R¹ is a substituted or unsubstituted aryl group (but, other than a group that may be A or D). For example, R⁴ is a substituted or unsubstituted aryl group (but, other than a group that may be A or D). For example, R⁵ is a substituted or unsubstituted aryl group (but, other than a group that may be A or D).

As a group of combinations of R¹ to R⁵, a group in which (R¹, R², R³, R⁴, R⁵) is (H, A, D, D, D), (D, A, H, D, D) or (H, A, H, D, D) may be exemplified. As another group, a group in which (R¹, R², R³, R⁴, R⁵) is (H, A, D, D, D), (H, A, Ar, D, D), (H, A, D, Ar, D) or (H, A, D, D, Ar) may be exemplified. As another group, a group in which (R¹, R², R³, R⁴, R⁵) is (H, A, D, D, D), (H, A, Ar, Ar, D), (H, A, D, Ar, Ar) or (H, A, Ar, D, Ar) may be exemplified. As another group, a group in which (R¹, R², R³, R⁴, R⁵) is (Ar, A, H, D, D), (D, A, H, Ar, D) or (D, A, H, D, Ar) may be exemplified. As another group, a group in which (R¹, R², R³, R⁴, R⁵) is (Ar, A, H, Ar, D), (Ar, A, H, D, Ar) or (D, A, H, Ar, Ar) may be exemplified. As another group, a group in which (R¹, R², R³, R⁴, R⁵) is (H, A, H, D, D), (H, A, H, Ar, D) or (H, A, H, D, Ar) may be exemplified. As another group, a group of (A, D, D, D, H), (A, D, D, D, Ar), (A, D, D, Ar, D) and (A, D, Ar, D, D) may be exemplified. As another group, a group of (A, D, H, D, Ar) and (A, D, Ar, D, H) may be exemplified. As another group, a group of (A, D, D, H, Ar) and (A, D, D, Ar, H) may be exemplified. As another group, a group of (A, D, Ar, H, D) and (A, D, H, Ar, D) may be exemplified. As another group, a group of (D, A, H, D, D), (D, A, H, H, D), (D, A, H, Ar, D) and (D, A, H, D, Ar) may be exemplified. As another group, (H, A, D, Ar, D) may be exemplified. Here, H represents a hydrogen atom, and Ar represents a substituted or unsubstituted aryl group (but, other than a group that may be A or D). In the present invention, combinations of R¹ to R⁵, which do not belong to the groups exemplified herein, can also be adopted.

In the formula (1), A is a group represented by Het-L^(A)-* or CN-L^(A)-*. Here, Het is a substituted or unsubstituted heteroaryl group bonded via a carbon atom, and the heteroaryl group mentioned herein contains at least one nitrogen atom as a ring skeleton-forming atom. L^(A) represents a single bond or a substituted or unsubstituted arylene group. * represents a bond position.

As A in the formula (1), Het-L^(A)-* can be preferably selected. Further, as A, CN-L^(A)-* can also be selected.

Het has a heteroaryl ring in which a nitrogen atom is contained as a ring skeleton-forming atom, and it is desirable that a ring skeleton-forming carbon atom of the heteroaryl ring is bonded to L^(A) (bonded to a ring skeleton-forming carbon atom of a pyridine ring of the formula (1) when L^(A) mentioned herein is a single bond). Het-L^(A)-* is preferably a group represented by any of the following formulas (IIIa), (IIIb), (IIIc), (IIId) and (IIIe).

Each of R²¹ to R²⁵ independently represents a hydrogen atom or a substituent. L^(A) represents a single bond or a substituted or unsubstituted arylene group. In some embodiments, each of R²¹ to R²⁵ is independently a hydrogen atom, a deuterium atom, a cyano group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heteroaryl group. The alkyl group mentioned herein may be substituted with, for example, one or more substituents selected from a deuterium atom, a substituted or unsubstituted aryl group, and a substituted or unsubstituted heteroaryl group. Each of the aryl group and the heteroaryl group mentioned herein may be independently substituted with, for example, one or more substituents selected from a deuterium atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, and a substituted or unsubstituted heteroaryl group. Two or more of these substituents may be bonded to form a cyclic structure. Further, R²¹ and R²², R²² and R²³, R²³ and R²⁴, and R²⁴ and R²⁵ may be bonded to each other to form cyclic structures. The cyclic structure mentioned herein may be a substituted or unsubstituted aromatic ring, or may be a substituted or unsubstituted aliphatic ring. Further, it may be a carbon ring or a hetero ring. In a preferred embodiment, each of R²¹ to R²⁵ is independently a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group. In another preferred embodiment, at least one of R²¹ to R²⁴ is an aryl group that may be substituted with an aryl group. In a more preferred embodiment, each of R²¹ to R²⁵ is independently a substituted or unsubstituted aryl group. R²¹ to R²⁵ may be the same or different, and, for example, can be the same. Further, in a preferred embodiment, a benzene ring is formed through bonding in one of R²¹ and R²², R²² and R²³, R²³ and R²⁴, and R²⁴ and R²⁵. In another preferred embodiment, a benzofuran ring or a benzothiophene ring is formed through bonding in one of R²¹ and R²², R²² and R²³, R²³ and R²⁴, and R²⁴ and R²⁵.

R²¹ and L^(A), and R²⁵ and L^(A) do not bond to each other and form cyclic structures.

Het-L^(A)-* can be, for example, a group represented by any of the formulas (IIIa), (IIIb) and (IIIc). Further, it can be a group represented by either the formula (IIIb) or (IIIc). Further, it can be a group represented by either the formula (IIId) or (IIIe). Further, in a preferred embodiment, Het-L^(A)-* is a group represented by the formula (IIIa).

In some embodiments. L^(A) is a single bond.

Further, in other embodiments of the present invention, L^(A) is a substituted or unsubstituted arylene group. L^(A) may be a linking group in which two or three substituted or unsubstituted arylene groups are linked. Further. L^(A) may be composed of only one substituted or unsubstituted arylene group. In some embodiments. L^(A) is an unsubstituted arylene group. Further, in some embodiments, L^(A) is a substituted arylene group. Here, the arylene group may be substituted with, for example, one or more substituents selected from a deuterium atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heteroaryl group, and a cyano group, and two or more of these substituents may be combined to form a cyclic structure. The cyclic structure mentioned herein may be a substituted or unsubstituted aromatic ring, or a substituted or unsubstituted aliphatic ring. Further, it may be a carbon ring, or may be a hetero ring. Further, the arylene group represented by L^(A) may be substituted with a group represented by any of (IIIa) to (IIIe). In some embodiments of the present invention, A is Het-L^(A)-*, and L^(A) an arylene group that may be substituted with one group selected from the group consisting of an alkyl group, an aryl group, and a cyano group, or a group formed by combining two or more thereof. In some embodiments of the present invention, A is CN-L^(A)-*, and L^(A) is an arylene group that may be substituted with an alkyl group or a cyano group. In some embodiments, L^(A) is a single bond, an unsubstituted phenylene group, or a phenylene group substituted with at least one alkyl group. Examples of the phenylene group include a 1,4-phenylene group, a 1,3-phenylene group, and a 1,2-phenylene group, and a 1,4-phenylene group and a 1,3-phenylene group are preferred.

In some embodiments, A is selected from the group consisting of A1 to A21 illustrated below. In some embodiments, A is selected from the group consisting of A1 to A5 and A12 to A21. In some embodiments, A is selected from the group consisting of A6 to A11. * represents a bond position.

In the formula (1), D is a group represented by the following formula (IIa), (IIb), (IIc) or (IId). In some embodiments, D is a group represented by the formula (IIa), (IIb) or (IId). In some embodiments, D is a group represented by the formula (IIa). In some embodiments. D is a group represented by the formula (IIb). In some embodiments, D is a group represented by the formula (IId).

Each R^(D) independently represents a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted amino group, a cyano group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted heteroaryl group, a substituted or unsubstituted heteroaryloxy group or a silyl group, and two or more R^(D)'s may be bonded to each other to form a cyclic structure. In some embodiments of the present invention, each R^(D) is independently selected from the group consisting of a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted amino group, a cyano group, and a substituted or unsubstituted aryl group. In some embodiments of the present invention, each R^(D) is independently selected from the group consisting of a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group, and a substituted or unsubstituted alkoxy group. In some embodiments of the present invention, each R^(D) is independently selected from the group consisting of a hydrogen atom, a deuterium atom, a substituted or unsubstituted aryl group, and a substituted or unsubstituted aryloxy group. In some embodiments of the present invention, each R^(D) is independently selected from the group consisting of a hydrogen atom, a deuterium atom, a substituted or unsubstituted heteroaryl group, and a substituted or unsubstituted heteroaryloxy group. In some embodiments of the present invention, each R^(D) is independently a hydrogen atom or a deuterium atom. Among R^(D)'s present in D, the number of substituents that are neither hydrogen atoms nor deuterium atoms is three or four in some embodiments, two in other embodiments of the present invention, or one in some embodiments.

X′ represents N—R^(D)′, an oxygen atom, or a sulfur atom. In some embodiments, X′ is N—R^(D)′. In some embodiments, X′ is an oxygen atom. In some embodiments, X′ is a sulfur atom.

R^(D)′ represents a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heteroaryl group, and R^(D)′ may be bonded to one or more R^(D)'s to form a cyclic structure. In some embodiments of the present invention, each R^(D)′ is independently a hydrogen atom or a deuterium atom. In some embodiments of the present invention, R^(D)′ is a substituted or unsubstituted alkyl group. In some embodiments of the present invention, R^(D)′ is a substituted or unsubstituted aryl group.

The cyclic structure formed by combining two or more R^(D)'s, or R^(D)′ and one or more R^(D)'s may be a substituted or unsubstituted aromatic ring, or a substituted or unsubstituted aliphatic ring. Further, it may be a carbon ring, or may be a hetero ring.

R^(D) and L^(D), and R^(D)′ and L^(D) do not bond to each other to form a cyclic structure.

Each L^(D) independently represents a single bond, a substituted or unsubstituted arylene group, or a substituted or unsubstituted heteroarylene group. In some embodiments, L^(D) is a single bond. In some embodiments, L^(D) is a substituted or unsubstituted arylene group. L^(D) may be a linking group in which two or three selected from the group consisting of a substituted or unsubstituted arylene group and a substituted or unsubstituted heteroarylene group are linked to each other. In some embodiments, L^(D) is a linking group in which two or three substituted or unsubstituted arylene groups are linked. In some embodiments, L^(D) is composed of only one substituted or unsubstituted arylene group. In some embodiments, L^(D) is an unsubstituted arylene group. Further, in some embodiments, L^(D) is a substituted arylene group. Here, an arylene group may be substituted with, for example, one or more substituents selected from a deuterium atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, and a substituted or unsubstituted heteroaryl group, and two or more of these substituents may be combined to form a cyclic structure. The cyclic structure mentioned herein may be a substituted or unsubstituted aromatic ring, or a substituted or unsubstituted aliphatic ring. Further, it may be a carbon ring, or may be a hetero ring.

In some embodiments, L^(D) is a single bond, an unsubstituted phenylene group, or a phenylene group substituted with at least one alkyl group. Examples of the phenylene group include a 1,4-phenylene group, a 1,3-phenylene group, and a 1,2-phenylene group, and the 1,4-phenylene group and the 1,3-phenylene group are preferred.

In some embodiments, D is selected from the group consisting of D1 to D96 illustrated below. In some embodiments, D is selected from the group consisting of D1 to D4, D41 to D43, D84, D86 to D88, and D94 to D96. In some embodiments, D is selected from the group consisting of D1 to D5, D16 to D19, and D21 to D24. In some embodiments, D is selected from the group consisting of D32 to D38, D40 to D43, and D60 to D88. In some embodiments, D is selected from the group consisting of D89 to D91 and D93 to D96. * represents a bond position. Ph represents an unsubstituted phenyl group.

In the formula (1), R is a hydrogen atom, a deuterium atom, or a substituted or unsubstituted aryl group (but, other than a group that may be A or D). In some embodiments, R is a hydrogen atom. In some embodiments, R is a substituted or unsubstituted aryl group (but, other than a group that may be A or D). For example, R is an unsubstituted aryl group. When R is a substituted aryl group, the aryl group may be substituted with, for example, one or more substituents selected from a deuterium atom, a substituted or unsubstituted alkyl group, and a substituted or unsubstituted aryl group. Two or more of these substituents may be bonded to form a cyclic structure. The cyclic structure mentioned herein may be a substituted or unsubstituted aromatic ring, or a substituted or unsubstituted aliphatic ring. Further, it may be a carbon ring, or may be a hetero ring. In a preferred embodiment, each R is independently a hydrogen atom, or a substituted or unsubstituted aryl group. In a more preferred embodiment, each R is independently a hydrogen atom or an unsubstituted aryl group. For example, each R can be independently a hydrogen atom or a phenyl group.

In the formula (1), p is any integer of 1 to 3. When p is 2 or 3, D's present in the molecule may be the same or different. When p is 1 or 2, R's present in the molecule may be the same or different. In some embodiments, p is 3. In some embodiments, p is 2.

In a preferred embodiment, in the formula (1), in R¹ and R², R² and R³, R³ and R⁴, and R⁴ and R⁵, none of these are bonded to each other to form a cyclic structure.

The molecular weight of the compound represented by the formula (1) is preferably 1500 or less, more preferably 1200 or less, further preferably 1000 or less, still further preferably 900 or less, for example, when there is an intention to form and use a film of an organic layer containing the compound represented by the formula (1), through a deposition method. The lower limit value of the molecular weight is the molecular weight of the smallest compound represented by the formula (1).

The compound represented by the formula (1) may be formed into a film through a coating method regardless of the molecular weight. When the coating method is used, it is possible to form a film even if the compound has a relatively large molecular weight.

Through an application of the present invention, a compound in which a plurality of structures represented by the formula (1) is included in the molecule may be prepared. The use of such a compound as, for example, a charge transport material may be taken into consideration.

For example, it is possible to obtain a polymer by allowing a polymerizable group to exist in the structure represented by the formula (1) in advance, and polymerizing the polymerizable group. Specifically, a monomer including a polymerizable functional group may be prepared in any of R¹ to R⁵ of the formula (1), and this may be polymerized alone or copolymerized with another monomer so as to obtain a polymer having repeating units. Alternatively, a dimer or a trimer may also be obtained by coupling compounds having the structures represented by the formula (1) with each other.

In some embodiments, the compound represented by the formula (1) does not include a metal atom. In some embodiments, the compound represented by the formula (1) is composed of only a hydrogen atom, a carbon atom, and a nitrogen atom. In some embodiments, the compound represented by the formula (1) is composed of only atoms selected from the group consisting of a hydrogen atom, a carbon atom, a nitrogen atom, and an oxygen atom. In some embodiments, the compound represented by the formula (1) is composed of only atoms selected from the group consisting of a hydrogen atom, a carbon atom, a nitrogen atom, and a sulfur atom. In some embodiments, the compound represented by the formula (1) is composed of only atoms selected from the group consisting of a hydrogen atom, a carbon atom, a nitrogen atom, an oxygen atom, a sulfur atom, and a silicon atom. In some embodiments, the compound represented by the formula (1) does not include a cyano group. In some embodiments, the compound represented by the formula (1) does not include a diarylamino group (meanwhile, two aryl groups constituting the diarylamino group do not bond to each other by a single bond or a linking group and form a cyclic structure).

Specific examples of a compound represented by the formula (1) will be mentioned below. Meanwhile, the scope of compounds of the present invention should not be construed as limiting to these specific examples.

TABLE 1 No R¹ R² R³ R⁴ R⁵ No R¹ R² R³ R⁴ R⁵ No R¹ R² R³ R⁴ R⁵ 1 A1 D1 D1 D1 H 51 A1 Ph H D2 D2 101 A1 Ph D4 H D4 2 A1 D1 D1 H D1 52 A1 H Ph D2 D2 102 A1 H D4 Ph D4 3 A1 D1 H D1 D1 53 A1 D3 D3 D3 H 103 A1 Ph H D4 D4 4 A1 H D1 D1 D1 54 A1 D3 D3 H D3 104 A1 H Ph D4 D4 5 A1 D1 D1 D1 Ph 55 A1 D3 H D3 D3 105 A1 D40 D40 D40 H 6 A1 D1 D1 Ph D1 56 A1 H D3 D3 D3 106 A1 D40 D40 H D40 7 A1 D1 Ph D1 D1 57 A1 D3 D3 D3 Ph 107 A1 D40 H D40 D40 8 A1 Ph D1 D1 D1 58 A1 D3 D3 Ph D3 108 A1 H D40 D40 D40 9 A1 D1 D1 H H 59 A1 D3 Ph D3 D3 109 A1 D40 D40 D40 Ph 10 A1 D1 H D1 H 60 A1 Ph D3 D3 D3 110 A1 D40 D40 Ph D40 11 A1 D1 H H D1 61 A1 D3 D3 H H 111 A1 D40 Ph D40 D40 12 A1 H D1 D1 H 62 A1 D3 H D3 H 112 A1 Ph D40 D40 D40 13 A1 H D1 H D1 63 A1 D3 H H D3 113 A1 D40 D40 H H 14 A1 H H D1 D1 64 A1 H D3 D3 H 114 A1 D40 H D40 H 15 A1 D1 D1 Ph H 65 A1 H D3 H D3 115 A1 D40 H H D40 16 A1 D1 D1 H Ph 66 A1 H H D3 D3 116 A1 H D40 D40 H 17 A1 D1 Ph D1 H 67 A1 D3 D3 Ph H 117 A1 H D40 H D40 18 A1 D1 H D1 Ph 68 A1 D3 D3 H Ph 118 A1 H H D40 P40 19 A1 D1 Ph H D1 69 A1 D3 Ph D3 H 119 A1 D40 D40 Ph H 20 A1 D1 H Ph D1 70 A1 D3 H D3 Ph 120 A1 D40 D40 H Ph 21 A1 Ph D1 D1 H 71 A1 D3 Ph H D3 121 A1 D40 Ph D40 H 22 A1 H D1 D1 Ph 72 A1 D3 H Ph D3 122 A1 D40 H D40 Ph 23 A1 Ph D1 H D1 73 A1 Ph D3 D3 H 123 A1 D40 Ph H D40 24 A1 H D1 Ph D1 74 A1 H D3 D3 Ph 124 A1 D40 H Ph D40 25 A1 Ph H D1 D1 75 A1 Ph D3 H D3 125 A1 Ph D40 D40 H 26 A1 H Ph D1 D1 76 A1 H D3 Ph D3 126 A1 H D40 D40 Ph 27 A1 D2 D2 D2 H 77 A1 Ph H D3 D3 127 A1 Ph D40 H D40 28 A1 D2 D2 H D2 78 A1 H Ph D3 D3 128 A1 H D40 Ph D40 29 A1 D2 H D2 D2 79 A1 D4 D4 D4 H 129 A1 Ph H D40 D40 30 A1 H D2 D2 D2 80 A1 D4 D4 H D4 130 A1 H Ph D40 D40 31 A1 D2 D2 D2 Ph 81 A1 D4 H D4 D4 131 A1 D41 D41 D41 H 32 A1 D2 D2 Ph D2 82 A1 H D4 D4 D4 132 A1 D41 D41 H D41 33 A1 D2 Ph D2 D2 83 A1 D4 D4 D4 Ph 133 A1 D41 H D41 D41 34 A1 Ph D2 D2 D2 84 A1 D4 D4 Ph D4 134 A1 H D41 D41 D41 35 A1 D2 D2 H H 85 A1 D4 Ph D4 D4 135 A1 D41 D41 D41 Ph 36 A1 D2 H D2 H 86 A1 Ph D4 D4 D4 136 A1 D41 D41 Ph D41 37 A1 D2 H H D2 87 A1 D4 D4 H H 137 A1 D41 Ph D41 D41 38 A1 H D2 D2 H 88 A1 D4 H D4 H 138 A1 Ph D41 D41 D41 39 A1 H D2 H D2 89 A1 D4 H H D4 139 A1 D41 D41 H H 40 A1 H H D2 D2 90 A1 H D4 D4 H 140 A1 D41 H D41 H 41 A1 D2 D2 Ph H 91 A1 H D4 H D4 141 A1 D41 H H D41 42 A1 D2 D2 H Ph 92 A1 H H D4 D4 142 A1 H D41 D41 H 43 A1 D2 Ph D2 H 93 A1 D4 D4 Ph H 143 A1 H D41 H D41 44 A1 D2 H D2 Ph 94 A1 D4 D4 H Ph 144 A1 H H D41 D41 45 A1 D2 Ph H D2 95 A1 D4 Ph D4 H 145 A1 D41 D41 Ph H 46 A1 D2 H Ph D2 96 A1 D4 H D4 Ph 146 A1 D41 D41 H Ph 47 A1 Ph D2 D2 H 97 A1 D4 Ph H D4 147 A1 D41 Ph D41 H 48 A1 H D2 D2 Ph 98 A1 D4 H Ph D4 148 A1 D41 H D41 Ph 49 A1 Ph D2 H D2 99 A1 Ph D4 D4 H 149 A1 D41 Ph H D41 50 A1 H D2 Ph D2 100 A1 H D4 D4 Ph 150 A1 D41 H Ph D41 151 A1 Ph D41 D41 H 201 A1 D43 Ph H D43 251 A1 D86 Ph D86 H 152 A1 H D41 D41 Ph 202 A1 D43 H Ph D43 252 A1 D86 H D86 Ph 153 A1 Ph D41 H D41 203 A1 Ph D43 D4 H 253 A1 D86 Ph H D86 154 A1 H D41 Ph D41 204 A1 H D43 D4 Ph 254 A1 D86 H Ph D86 155 A1 Ph H D41 D41 205 A1 Ph D43 H D43 255 A1 Ph D86 D86 H 156 A1 H Ph D41 D41 206 A1 H D43 Ph D43 256 A1 H D86 D86 Ph 157 A1 D42 D42 D42 H 207 A1 Ph H D43 D43 257 A1 Ph D86 H D86 158 A1 D42 D42 H D42 208 A1 H Ph D43 D43 258 A1 H D86 Ph D86 159 A1 D42 H D42 D42 209 A1 D84 D84 D84 H 259 A1 Ph H D86 D86 160 A1 D42 D42 D42 210 A1 D84 D84 H D84 260 A1 H Ph D86 D86 161 A1 D42 D42 D42 Ph 211 A1 D84 H D84 D84 261 A1 D87 D87 D87 H 162 A1 D42 D42 Ph D42 212 A1 H D84 D84 D84 262 A1 D87 D87 H D87 163 A1 D42 Ph D42 D42 213 A1 D84 D84 D84 Ph 263 A1 D87 H D87 D87 164 A1 Ph D42 D42 D42 214 A1 D84 D84 Ph D84 264 A1 H D87 D87 D87 165 A1 D42 D42 H H 215 A1 D84 Ph D84 D84 265 A1 D87 D87 D87 Ph 166 A1 D42 H D42 H 216 A1 Ph D84 D84 D84 266 A1 D87 D87 Ph D87 167 A1 D42 H H D42 217 A1 D84 D84 H H 267 A1 D87 Ph D87 D87 168 A1 H D42 D42 H 218 A1 D84 H D84 H 268 A1 Ph D87 D87 D87 169 A1 H D42 H D42 219 A1 D84 H H D84 269 A1 D87 D87 H H 170 A1 H H D42 D42 220 A1 H D84 D84 H 270 A1 D87 H D87 H 171 A1 D42 D42 Ph H 221 A1 H D84 H D84 271 A1 D87 H H D87 172 A1 D42 D42 H Ph 222 A1 H H D84 D84 272 A1 H D87 D87 H 173 A1 D42 Ph D42 H 223 A1 D84 D84 Ph H 273 A1 H D87 H D87 174 A1 D42 H D42 Ph 224 A1 D84 D84 H Ph 274 A1 H H D87 D87 175 A1 D42 Ph H D42 225 A1 D84 Ph D84 H 275 A1 D87 D87 Ph H 176 A1 D42 H Ph D42 226 A1 D84 H D84 Ph 276 A1 D87 D87 H Ph 177 A1 Ph D42 D42 H 227 A1 D84 Ph H D84 277 A1 D87 Ph D87 H 178 A1 H D42 D42 Ph 228 A1 D84 H Ph D84 278 A1 D87 H D87 Ph 179 A1 Ph D42 H D42 229 A1 Ph D84 D84 H 279 A1 D87 Ph H D87 180 A1 H D42 Ph D42 230 A1 H D84 D84 Ph 280 A1 D87 H Ph D87 181 A1 Ph H D42 D42 231 A1 Ph D84 H D84 281 A1 Ph D87 D87 H 182 A1 H Ph D42 D42 232 A1 H D84 Ph D84 282 A1 H D87 D87 Ph 183 A1 D43 D43 D43 H 233 A1 Ph H D84 D84 283 A1 Ph D87 H D87 184 A1 D43 D43 H D43 234 A1 H Ph D84 D84 284 A1 H D87 Ph D87 185 A1 D43 H D43 D43 235 A1 D86 D86 D86 H 285 A1 Ph H D87 D87 186 A1 D43 D43 D43 236 A1 D86 D86 H D86 286 A1 H Ph D87 D87 187 A1 D43 D43 D43 Ph 237 A1 D86 H D86 D86 287 A1 D88 D88 D88 H 188 A1 D43 D41 Ph D43 238 A1 H D86 D86 D86 288 A1 D88 D88 H D88 189 A1 D43 Ph D43 D43 239 A1 D86 D86 D86 Ph 289 A1 D88 H D88 D88 190 A1 Ph D43 D43 D43 240 A1 D86 D86 Ph D86 290 A1 H D88 D88 D88 191 A1 D43 D43 H H 241 A1 D86 Ph D86 D86 291 A1 D88 D88 D88 Ph 192 A1 D43 H D43 H 242 A1 Ph D86 D86 D86 292 A1 D88 D88 Ph D88 193 A1 D43 H H D43 243 A1 D86 D86 H H 293 A1 D88 Ph D88 D88 194 A1 H D43 D43 H 244 A1 D86 H D86 H 294 A1 Ph D88 D88 D88 195 A1 H D43 H D43 245 A1 D86 H H D86 295 A1 D88 D88 H H 196 A1 H H D43 D43 246 A1 H D86 D86 H 296 A1 D88 H D88 H 197 A1 D43 D43 Ph H 247 A1 H D86 H D86 297 A1 D88 H H D88 198 A1 D43 D43 H Ph 248 A1 H H D8 D86 298 A1 H D88 D88 H 199 A1 D43 Ph D43 H 249 A1 D86 D86 Ph H 299 A1 H D88 H D88 200 A1 D43 H D43 Ph 250 A1 D86 D86 H Ph 300 A1 H H D88 D88 301 A1 D88 D88 Ph H 351 A2 H D2 H D2 401 A2 D4 H H D4 302 A1 D88 D88 H Ph 352 A2 H H D2 D2 402 A2 H D4 D4 H 303 A1 D88 Ph D88 H 353 A2 D2 D2 Ph H 403 A2 H D4 H D4 304 A1 D88 H D88 Ph 354 A2 D2 D2 H Ph 404 A2 H H D4 D4 305 A1 D88 Ph H D88 355 A2 D2 Ph D2 H 405 A2 D4 D4 Ph H 306 A1 D88 H Ph D88 356 A2 D2 H D2 Ph 406 A2 D4 D4 H Ph 307 A1 Ph D88 D88 H 357 A2 D2 Ph H D2 407 A2 D4 Ph D4 H 308 A1 H D88 D88 Ph 358 A2 D2 H Ph D2 408 A2 D4 H D4 Ph 309 A1 Ph D88 H D88 359 A2 Ph D2 D2 H 409 A2 D4 Ph H D4 310 A1 H D88 Ph D88 380 A2 H D2 D2 Ph 410 A2 D4 H Ph D4 311 A1 Ph H D88 D88 361 A2 Ph D2 H D2 411 A2 Ph D4 D4 H 312 A1 H Ph D88 D88 362 A2 H D2 Ph D2 412 A2 H D4 D4 Ph 313 A2 D1 D1 D1 H 363 A2 Ph H D2 D2 413 A2 Ph D4 H D4 314 A2 D1 D1 H D1 364 A2 H Ph D2 D2 414 A2 H D4 Ph D4 315 A2 D1 H D1 D1 365 A2 D3 D3 D3 H 415 A2 Ph H D4 D4 316 A2 H D1 D1 D1 366 A2 D3 D3 H D3 416 A2 H Ph D4 D4 317 A2 D1 D1 D1 Ph 367 A2 D3 H D3 D3 417 A2 D40 D40 D40 H 318 A2 D1 D1 Ph D1 368 A2 H D3 D3 D3 418 A2 D40 D40 H D40 319 A2 D1 Ph D1 D1 369 A2 D3 D3 D3 Ph 419 A2 D40 H D40 D40 320 A2 Ph D1 D1 D1 370 A2 D3 D3 Ph D3 420 A2 H D40 D40 D40 321 A2 D1 D1 H H 371 A2 D3 Ph D3 D3 421 A2 D40 D40 D40 Ph 322 A2 D1 H D1 H 372 A2 Ph D3 D3 D3 422 A2 D40 D40 Ph D40 323 A2 D1 H H D1 373 A2 D3 D3 H H 423 A2 D40 Ph D40 D40 324 A2 H D1 D1 H 374 A2 03 H D3 H 424 A2 Ph D40 D40 D40 325 A2 H D1 H D1 375 A2 D3 H H D3 425 A2 D40 D40 H H 326 A2 H H D1 D1 376 A2 H D3 D3 H 426 A2 D40 H D40 H 327 A2 D1 D1 Ph H 377 A2 H D3 H D3 427 A2 D40 H H D40 328 A2 D1 D1 H Ph 378 A2 H H D3 D3 428 A2 H D40 D40 H 329 A2 D1 Ph D1 H 379 A2 D3 D3 Ph H 429 A2 H D40 H D40 330 A2 D1 H D1 Ph 380 A2 D3 D3 H Ph 430 A2 H H D40 D40 331 A2 D1 Ph H D1 381 A2 D3 Ph D3 H 431 A2 D40 D40 Ph H 332 A2 D1 H Ph D1 382 A2 D3 H D3 Ph 432 A2 D40 D40 H Ph 333 A2 Ph D1 D1 H 383 A2 D3 Ph H D3 433 A2 D40 Ph D40 H 334 A2 H D1 D1 Ph 384 A2 D3 H Ph D3 434 A2 D40 H D40 Ph 335 A2 Ph D1 H D1 385 A2 Ph D3 D3 H 435 A2 D40 Ph H D40 336 A2 H D1 Ph D1 386 A2 H D3 D3 Ph 436 A2 D40 H Ph D40 337 A2 Ph H D1 D1 387 A2 Ph D3 H D3 437 A2 Ph D40 D40 H 338 A2 H Ph D1 D1 388 A2 H D3 Ph D3 438 A2 H D40 D40 Ph 339 A2 D2 D2 D2 H 389 A2 Ph H D3 D3 439 A2 Ph D40 H D40 340 A2 D2 D2 H D2 390 A2 H Ph D3 D3 440 A2 H D40 Ph D40 341 A2 D2 H D2 D2 391 A2 D4 D4 D4 H 441 A2 Ph H D40 D40 342 A2 H D2 D2 D2 392 A2 D4 D4 H D4 442 A2 H Ph D40 D40 343 A2 D2 D2 D2 Ph 393 A2 D4 H D4 D4 443 A2 D41 D41 D41 H 344 A2 D2 D2 Ph D2 394 A2 H D4 D4 D4 444 A2 D41 D41 H D41 345 A2 D2 Ph D2 D2 395 A2 D4 D4 D4 Ph 445 A2 D41 H D41 D41 346 A2 Ph D2 D2 D2 396 A2 D4 D4 Ph D4 446 A2 H D41 D41 D41 347 A2 D2 D2 H H 397 A2 D4 Ph D4 D4 447 A2 D41 D41 D41 Ph 348 A2 D2 H D2 H 398 A2 Ph D4 D4 D4 448 A2 D41 D41 Ph D41 349 A2 D2 H H D2 389 A2 D4 D4 H H 449 A2 D41 Ph D41 D41 350 A2 H D2 D2 H 400 A2 D4 H D4 H 450 A2 Ph D41 D41 D41 451 A2 D41 D41 H H 501 A2 D43 Ph D43 D43 551 A2 D86 D86 D86 Ph 452 A2 D41 H D41 H 502 A2 Ph D43 D43 D43 552 A2 D86 D86 Ph D86 453 A2 D41 H H D41 503 A2 D43 D43 H H 553 A2 D86 Ph D86 D86 454 A2 H D41 D41 H 504 A2 D43 H D43 H 554 A2 Ph D86 D86 D86 455 A2 H D41 H D41 505 A2 D43 H H D43 555 A2 D86 D86 H H 458 A2 H H D41 D41 506 A2 H D43 D43 H 556 A2 D86 H D86 H 457 A2 D41 D41 Ph H 507 A2 H D43 H D43 557 A2 D86 H H D86 458 A2 D41 D41 H Ph 508 A2 H H D43 D43 558 A2 H D86 D86 H 459 A2 D41 Ph D41 H 509 A2 D43 D43 Ph H 559 A2 H D86 H D86 460 A2 D41 H D41 Ph 510 A2 D43 D43 H Ph 560 A2 H H D86 D86 461 A2 D41 Ph H D41 511 A2 D43 Ph D43 H 561 A2 D86 D86 Ph H 462 A2 D41 H Ph D41 512 A2 D43 H D43 Ph 562 A2 D86 D86 H Ph 463 A2 Ph D41 D41 H 513 A2 D43 Ph H D43 563 A2 D86 Ph D86 H 464 A2 H D41 D41 Ph 514 A2 D43 H Ph D43 564 A2 D86 H D86 Ph 465 A2 Ph D41 H D41 515 A2 Ph D43 D43 H 565 A2 D86 Ph H D86 466 A2 H D41 Ph D41 516 A2 H D43 D43 Ph 566 A2 D86 H Ph D86 467 A2 Ph H D41 D41 517 A2 Ph D43 H D43 567 A2 Ph D86 D86 H 468 A2 H Ph D41 D41 518 A2 H D43 Ph D43 568 A2 H D86 D86 Ph 469 A2 D42 D42 D42 H 519 A2 Ph H D43 D43 569 A2 Ph D86 H D86 470 A2 D42 D42 H D42 520 A2 H Ph D43 D43 570 A2 H D86 Ph D86 471 A2 D42 H D42 D42 521 A2 D84 D84 D84 H 571 A2 Ph H D86 D86 472 A2 H D42 D42 D42 522 A2 D84 D84 H D84 572 A2 H Ph D86 D86 473 A2 D42 D42 D42 Ph 523 A2 D84 H D84 D84 573 A2 D87 D87 D87 H 474 A2 D42 D42 Ph D42 524 A2 H D84 D84 D84 574 A2 D87 D87 H D87 475 A2 D42 Ph D42 D42 525 A2 D84 D84 D84 Ph 575 A2 D87 H D87 D87 476 A2 Ph D42 D42 D42 526 A2 D84 D84 Ph D84 576 A2 H D87 D87 D87 477 A2 D42 D42 H H 527 A2 D84 Ph D84 D84 577 A2 D87 D87 D87 Ph 478 A2 D42 H D42 H 528 A2 Ph D84 D84 D84 578 A2 D87 D87 Ph D87 479 A2 D42 H H D42 529 A2 D84 D84 H H 573 A2 D87 Ph D87 D87 480 A2 H D42 D42 H 530 A2 D84 H D84 H 580 A2 Ph D87 D87 D87 481 A2 H D42 H D42 531 A2 D84 H H D84 581 A2 D87 D87 H H 482 A2 H H D42 D42 532 A2 H D84 D84 H 582 A2 D87 H D87 H 483 A2 D42 D42 Ph H 533 A2 H D84 H D84 583 A2 D87 H H D87 484 A2 D42 D42 H Ph 534 A2 H H D84 D84 584 A2 H D87 D87 H 485 A2 D42 Ph D42 H 535 A2 D84 D84 Ph H 585 A2 H D87 H D87 486 42 D42 H D42 Ph 536 A2 D84 D84 H Ph 586 A2 H H D87 D87 487 A2 D42 Ph H D42 537 A2 D84 Ph D84 H 587 A2 D87 D87 Ph H 488 A2 D42 H Ph D42 538 A2 D84 H D84 Ph 588 A2 D87 D87 H Ph 489 A2 Ph D42 D42 H 539 A2 D84 Ph H D84 589 A2 D87 Ph D87 H 490 A2 H D42 D42 Ph 540 A2 D84 H Ph D84 590 A2 D87 H D87 Ph 491 A2 Ph D42 H D42 541 A2 Ph D84 D84 H 591 A2 D87 Ph H D87 492 A2 H D42 Ph D42 542 A2 H D84 D84 Ph 592 A2 D87 H Ph D87 493 A2 Ph H D42 D42 543 A2 Ph D84 H D84 593 A2 Ph D87 D87 H 434 A2 H Ph D42 D42 544 A2 H D84 Ph D84 594 A2 H D87 D87 Ph 495 A2 D43 D43 D43 H 545 A2 Ph H D84 D84 595 A2 Ph D87 H D87 496 A2 D43 D43 H D43 546 A2 H Ph D84 D84 596 A2 H D87 Ph D87 497 A2 D43 H D43 D43 547 A2 D86 D86 D86 H 597 A2 Ph H D87 D87 498 A2 H D43 D43 D43 548 A2 D86 D86 H D86 598 A2 H Ph D87 D87 499 A2 D43 D43 D43 Ph 549 A2 D86 H D86 D86 599 A2 D88 D88 D88 H 500 A2 D43 D43 Ph D43 550 A2 H D86 D86 D86 600 A2 D88 D88 H D88 601 A2 D88 H D88 D88 651 A3 D2 D2 D2 H 701 A3 Ph H D3 D3 602 A2 H D88 D88 D88 652 A3 D2 D2 H D2 702 A3 H Ph D3 D3 603 A2 D88 D88 D88 Ph 653 A3 D2 H D2 D2 703 A3 D4 D4 D4 H 604 A2 D88 D88 Ph D88 654 A3 H D2 D2 D2 704 A3 D4 D4 H D4 605 A2 D88 Ph D88 D88 655 A3 D2 D2 D2 Ph 705 A3 D4 H D4 D4 606 A2 Ph D88 D88 D88 656 A3 D2 D2 Ph D2 706 A3 H D4 D4 D4 607 A2 D88 D88 H H 657 A3 D2 Ph D2 D2 707 A3 D4 D4 D4 Ph 608 A2 D88 H D88 H 658 A3 Ph D2 D2 D2 708 A3 D4 D4 Ph D4 609 A2 D88 H H D88 659 A3 D2 D2 H H 709 A3 D4 Ph D4 D4 610 A2 H D88 D88 H 660 A3 D2 H D2 H 710 A3 Ph D4 D4 D4 611 A2 H D88 H D88 661 A3 D2 H H D2 711 A3 D4 D4 H H 612 A2 H H D88 D88 662 A3 H D2 D2 H 712 A3 D4 H D4 H 613 A2 D88 D88 Ph H 663 A3 H D2 H D2 713 A3 D4 H H D4 614 A2 D88 D88 H Ph 664 A3 H H DP DP 714 A3 H D4 D4 H 615 A2 D88 Ph D88 H 665 A3 D2 D2 Ph H 715 A3 H D4 H D4 616 A2 D88 H D88 Ph 666 A3 D2 D2 H Ph 716 A3 H H D4 D4 617 A2 D88 Ph H D88 667 A3 D2 Ph D2 H 717 A3 D4 D4 Ph H 618 A2 D88 H Ph D88 668 A3 D2 H D2 Ph 718 A3 D4 D4 H Ph 619 A2 Ph D88 D88 H 669 A3 D2 Ph H D2 719 A3 D4 Ph D4 H 620 A2 H D88 D88 Ph 670 A3 D2 H Ph D2 720 A3 D4 H D4 Ph 621 A2 Ph D88 H D88 671 A3 Ph D2 D2 H 721 A3 D4 Ph H D4 622 A2 H D88 Ph D88 672 A3 H D2 D2 Ph 722 A3 D4 H Ph D4 623 A2 Ph H D88 D88 673 A3 Ph D2 H D2 723 A3 Ph D4 D4 H 624 A2 H Ph D88 D88 674 A3 H D2 Ph D2 724 A3 H D4 D4 Ph 625 A3 D1 D1 D1 H 675 A3 Ph H D2 D2 725 A3 Ph D4 H D4 626 A3 D1 D1 H D1 676 A3 H Ph D2 D2 726 A3 H D4 Ph D4 627 A3 D1 H D1 D1 677 A3 D3 D3 D3 H 727 A3 Ph H D4 D4 628 A3 H D1 D1 D1 678 A3 D3 D3 H D3 728 A3 H Ph D4 D4 629 A3 D1 D1 D1 Ph 679 A3 D3 H D3 D3 729 A3 D40 D40 D40 H 630 A3 D1 D1 Ph D1 680 A3 H D3 D3 D3 730 A3 D40 D40 H D40 631 A3 D1 Ph D1 D1 681 A3 D3 D3 D3 Ph 731 A3 D40 H D40 D40 632 A3 Ph D1 D1 D1 682 A3 D3 D3 Ph D3 732 A3 H D40 D40 D40 633 A3 D1 D1 H H 683 A3 D3 Ph D3 D3 733 A3 D40 D40 D40 Ph 634 A3 D1 H D1 H 684 A3 Ph D3 D3 D3 734 A3 D40 D40 Ph D40 635 A3 D1 H H D1 685 A3 D3 D3 H H 735 A3 D40 Ph D40 D40 636 A3 H D1 D1 H 688 A3 D3 H D3 H 735 A3 Ph D40 D40 D40 637 A3 H D1 H D1 687 A3 D3 H H D3 737 A3 D40 D40 H H 638 A3 H H D1 D1 688 A3 H D3 D3 H 738 A3 D40 H D40 H 639 A3 D1 D1 Ph H 689 A3 H D3 H D3 739 A3 D40 H H D40 640 A3 D1 D1 H Ph 690 A3 H H D3 D3 740 A3 H D40 D40 H 641 A3 D1 Ph D1 H 691 A3 D3 D3 Ph H 741 A3 H D40 H D40 642 A3 D1 H D1 Ph 692 A3 D3 D3 H Ph 742 A3 H H D40 D40 643 A3 D1 Ph H D1 693 A3 D3 Ph D3 H 743 A3 D40 D40 Ph H 644 A3 D1 H Ph D1 694 A3 D3 H D3 Ph 744 A3 D40 D40 H Ph 645 A3 Ph D1 D1 H 695 A3 D3 Ph H D3 745 A3 D40 Ph D40 H 646 A3 H D1 D1 Ph 696 A3 D3 H Ph D3 745 A3 D40 H D40 Ph 647 A3 Ph D1 H D1 697 A3 Ph D3 D3 H 747 A3 D40 Ph H D40 648 A3 H D1 Ph D1 698 A3 H D3 D3 Ph 748 A3 D40 H Ph D40 649 A3 Ph H D1 D1 699 A3 Ph D3 H D3 749 A3 Ph D40 D40 H 650 A3 H Ph D1 D1 700 A3 H D3 Ph D3 750 A3 H D40 D40 Ph 751 A3 Ph D40 H D40 801 A3 Ph D42 D42 H 851 A3 D84 Ph H D84 752 A3 H D40 Ph D40 802 A3 H D42 D42 Ph 852 A3 D84 H Ph D84 753 A3 Ph H D40 D40 803 A3 Ph D42 H D42 853 A3 Ph D84 D84 H 754 A3 H Ph D40 D40 804 A3 H D42 Ph D42 854 A3 H D84 D84 Ph 755 A3 D41 D41 D41 H 805 A3 Ph H D42 D42 855 A3 Ph D84 H D84 756 A3 D41 D41 H D41 806 A3 H Ph D42 D42 856 A3 H D84 Ph D84 757 A3 D41 H D41 D41 807 A3 D43 D43 D43 H 857 A3 Ph H D84 D84 758 A3 H D41 D41 D41 808 A3 D43 D43 H D43 858 A3 H Ph D84 D84 759 A3 D41 D41 D41 Ph 809 A3 D43 H D43 D43 859 A3 D86 D86 D86 H 760 A3 D41 D41 Ph D41 810 H D43 D43 D43 860 A3 D86 D86 H D86 761 A3 D41 Ph D41 D41 811 A3 D43 D43 D43 Ph 861 A3 D86 H D86 D86 762 A3 Ph D41 D41 D41 812 A3 D43 D43 Ph D43 862 A3 H D86 D86 D86 763 A3 D41 D41 H H 813 A3 D43 Ph D43 D43 863 A3 D86 D86 D86 Ph 764 A3 D41 H D41 H 814 A3 Ph D43 D43 D43 864 A3 D86 D86 Ph D86 765 A3 D41 H H D41 815 A3 D43 D43 H H 865 A3 D86 Ph D86 D86 766 A3 H D41 D41 H 816 A3 D43 H D43 H 866 A3 Ph D86 D86 D86 767 A3 H D41 H D41 817 A3 D43 H H D43 867 A3 D86 D86 H H 768 A3 H H D41 D41 818 A3 H D43 D43 H 868 A3 D86 H D86 H 769 A3 D41 D41 Ph H 819 A3 H D43 H D43 869 A3 D86 H H D86 770 A3 D41 D41 H Ph 820 A3 H H D43 D43 870 A3 H D86 D86 H 771 A3 D41 Ph D41 H 821 A3 D43 D43 Ph H 871 A3 H D86 H D86 772 A3 D41 H D41 Ph 822 A3 D43 D43 H Ph 872 A3 H H D86 D86 773 A3 D41 Ph H D41 823 A3 D43 Ph D43 H 873 A3 D86 D86 Ph H 774 A3 D41 H Ph D41 824 A3 D43 H D43 Ph 874 A3 D86 D86 H Ph 775 A3 Ph D41 D41 H 825 A3 D43 Ph H D43 875 A3 D86 Ph D86 H 776 A3 H D41 D41 Ph 826 A3 D43 H Ph D43 876 A3 D86 H D86 Ph 777 A3 Ph D41 H D41 827 A3 Ph D43 D43 H 877 A3 D86 Ph H D86 778 A3 H D41 Ph D41 828 A3 H D43 D43 Ph 878 A3 D86 H Ph D86 779 A3 Ph H D41 D41 829 A3 Ph D43 H D43 879 A3 Ph D86 D86 H 780 A3 H Ph D41 D41 830 A3 H D43 Ph D43 880 A3 H D86 D86 Ph 781 A3 D42 D42 D42 H 831 A3 Ph H D43 D43 881 A3 Ph D86 H D86 782 A3 D42 D42 H D42 832 A3 H Ph D43 D43 882 A3 H D86 Ph D86 783 A3 D42 H D42 D42 833 A3 D84 D84 D84 H 883 A3 Ph H D86 D86 784 A3 H D42 D42 D42 834 A3 D84 D84 H D84 884 A3 H Ph D86 D86 785 A3 D42 D42 D42 Ph 835 A3 D84 H D84 D84 885 A3 D87 D87 D87 H 786 A3 D42 D42 Ph D42 836 A3 H D84 D84 D84 886 A3 D87 D87 H D87 787 A3 D42 Ph D42 D42 837 A3 D84 D84 D84 Ph 887 A3 D87 H D87 D87 788 A3 Ph D42 D42 D42 838 A3 D84 D84 Ph D84 888 A3 H D87 D87 D87 789 A3 D42 D42 H H 839 A3 D84 Ph D84 D84 889 A3 D87 D87 D87 Ph 790 A3 D42 H D42 H 840 A3 Ph D84 D84 D84 890 A3 D87 D87 Ph D87 791 A3 D42 H H D42 841 A3 D84 D84 H H 891 A3 D87 Ph D87 D87 792 A3 H D42 D42 H 842 A3 D84 H D84 H 892 A3 Ph D87 D87 D87 793 A3 H D42 H D42 843 A3 D84 H H D84 893 A3 D87 D87 H H 794 A3 H H D42 D42 844 A3 H D84 D84 H 894 A3 D87 H D87 H 795 A3 D42 D42 Ph H 845 A3 H D84 H D84 895 A3 D87 H H D87 796 A3 D42 D42 H Ph 846 A3 H H D84 D84 896 A3 H D87 D87 H 797 A3 D42 Ph D42 H 847 A3 D84 D84 Ph H 897 A3 H D87 H D87 798 A3 D42 H D42 Ph 848 A3 D84 D84 H Ph 898 A3 H H D87 D87 799 A3 D42 Ph H D42 849 A3 D84 Ph D84 H 899 A3 D87 D87 Ph H 800 A3 D42 H Ph D42 850 A3 D84 H D84 Ph 900 A3 D87 D87 H Ph 901 A3 D87 Ph D87 H 951 D1 A1 D1 Ph H 1001 H A1 D3 H D3 902 A3 D87 H D87 Ph 952 D1 A1 D1 H Ph 1002 H A1 H D3 D3 903 A3 D87 Ph H D87 953 D1 A1 Ph D1 H 1003 D3 A1 D3 Ph H 904 A3 D87 H Ph D87 954 D1 A1 H D1 Ph 1004 D3 A1 D3 H Ph 905 A3 Ph D87 D87 H 955 D1 A1 Ph H D1 1005 D3 A1 Ph D3 H 908 A3 H D87 D87 Ph 956 D1 A1 H Ph D1 1006 D3 A1 H D3 Ph 907 A3 Ph D87 H D87 957 Ph A1 D1 D1 H 1007 D3 A1 Ph H D3 908 A3 H D87 Ph DR7 958 H A1 D1 D1 Ph 1008 DR A1 H Ph D3 909 A3 Ph H D87 D87 959 Ph A1 D1 H D1 1009 Ph A1 D3 D3 H 910 A3 H Ph D87 D87 960 H A1 D1 Ph D1 1010 H A1 D3 D3 Ph 911 A3 D88 D88 D88 H 961 Ph A1 H D1 D1 1011 Ph A1 D3 H D3 912 A3 D88 D88 H D88 962 H A1 Ph D1 D1 1012 H A1 D3 Ph D3 913 A3 D88 H D88 D88 963 D2 A1 D2 D2 H 1013 Ph A1 H D3 D3 914 A3 H D88 D88 D88 964 D2 A1 D2 H D2 1014 H A1 Ph D3 D3 915 A3 D88 D88 D88 Ph 965 D2 A1 H D2 D2 1015 D4 A1 D4 D4 H 916 A3 D88 D88 Ph D88 966 H A1 D2 D2 D2 1016 D4 A1 D4 H D4 917 A3 D88 Ph D88 D88 967 D2 A1 D2 D2 Ph 1017 D4 A1 H D4 D4 918 A3 Ph D88 D88 D88 968 D2 A1 D2 Ph D2 1018 H A1 D4 D4 D4 919 A3 D88 D88 H H 969 D2 A1 Ph D2 D2 1019 D4 A1 D4 D4 Ph 920 A3 D88 H D88 H 970 Ph A1 D2 D2 D2 1020 D4 A1 D4 Ph D4 921 A3 D88 H H D88 971 D2 A1 D2 H H 1021 D4 A1 Ph D4 D4 922 A3 H D88 D88 H 972 D2 A1 H D2 H 1022 Ph 41 D4 D4 D4 923 A3 H D88 H D88 973 D2 A1 H H D2 1023 D4 A1 D4 H H 924 A3 H H D88 D88 974 H A1 D2 D2 H 1024 D4 A1 H D4 H 925 A3 D88 D88 Ph H 975 H 41 D2 H D2 1025 D4 A1 H H D4 926 A3 D88 D88 H Ph 976 H A1 H D2 D2 1026 H A1 D4 D4 H 927 A3 D88 Ph D88 H 977 D2 A1 D2 Ph H 1027 H A1 D4 H D4 928 A3 D88 H D88 Ph 978 D2 A1 D2 H Ph 1028 H A1 H D4 D4 929 A3 D88 Ph H D88 979 D2 A1 Ph D2 H 1029 D4 A1 D4 Ph H 930 A3 D88 H Ph D88 980 D2 A1 H D2 Ph 1030 D4 A1 D4 H Ph 931 A3 Ph D88 D88 H 981 D2 A1 Ph H D2 1031 D4 A1 Ph D4 H 932 A3 H D88 D88 Ph 982 D2 A1 H Ph D2 1032 D4 A1 H D4 Ph 933 A3 Ph D88 H D88 983 Ph A1 D2 D2 H 1033 D4 A1 Ph H D4 934 A3 H D88 Ph D88 984 H A1 D2 D2 Ph 1034 D4 A1 H Ph D4 935 A3 Ph H D88 D88 985 Ph A1 D2 H D2 1035 Ph A1 D4 D4 H 936 A3 H Ph D88 D88 986 H A1 D2 Ph D2 1036 H A1 D4 D4 Ph 937 D1 A1 D1 D1 H 987 Ph A1 H D2 D2 1037 Ph A1 D4 H D4 938 D1 A1 D1 H D1 988 H A1 Ph D2 D2 1038 H A1 D4 Ph D4 939 D1 A1 H D1 D1 989 D3 A1 D3 D3 H 1039 Ph A1 H D4 D4 940 H A1 D1 D1 D1 990 D3 A1 D3 H D3 1040 H A1 Ph D4 D4 941 D1 A1 D1 D1 Ph 991 D3 A1 H D3 D3 1041 D40 A1 D40 D40 H 942 D1 A1 D1 Ph D1 992 H A1 D3 D3 D3 1042 D40 A1 D40 H D40 943 D1 A1 Ph D1 D1 993 D3 A1 D3 D3 Ph 1043 D40 A1 H D40 D40 944 Ph A1 D1 D1 D1 994 D3 A1 D3 Ph D3 1044 H A1 D40 D40 D40 945 D1 A1 D1 H H 995 D3 A1 Ph D3 D3 1045 D40 A1 D40 D40 Ph 946 D1 A1 H D1 H 996 Ph A1 D3 D3 D3 1046 D40 A1 D40 Ph D40 947 D1 A1 H H D1 997 D3 A1 D3 H H 1047 D40 A1 Ph D40 D40 948 H A1 D1 D1 H 998 D3 A1 H D3 H 1048 Ph A1 D40 D40 D40 949 H A1 D1 H D1 999 D3 A1 H H D3 1049 D40 A1 D40 H H 950 H A1 H D1 D1 1000 H A1 D3 D3 H 1050 D40 A1 H D40 H 1051 D40 A1 H H D40 1101 D42 A1 D42 H H 1151 D84 A1 Ph D84 D84 1052 H A1 D40 D40 H 1102 D42 A1 H D42 H 1152 Ph A1 D84 D84 D84 1053 H A1 D40 H D40 1103 D42 A1 H H D42 1153 D84 A1 D84 H H 1054 H A1 H D40 D40 1104 H A1 D42 D42 H 1154 D84 A1 H D84 H 1055 D40 A1 D40 Ph H 1105 H A1 D42 H D42 1155 D84 A1 H H D84 1056 D40 A1 D40 H Ph 1106 H A1 H D42 D42 1156 H A1 D84 D84 H 1057 D40 A1 Ph D40 H 1107 D42 A1 D42 Ph H 1157 H A1 D84 H D84 1058 D40 A1 H D40 Ph 1108 D42 A1 D42 H Ph 1158 H A1 H D84 D84 1059 D40 A1 Ph H D40 1109 D42 A1 Ph D42 H 1159 D84 A1 D84 Ph H 1060 P40 A1 H Ph D40 1110 D42 A1 H D42 Ph 1160 D84 A1 D84 H Ph 1061 Ph A1 D40 D40 H 1111 D42 A1 Ph H D42 1161 D84 A1 Ph D84 H 1062 H A1 D40 D40 Ph 1112 D42 A1 H Ph D42 1162 D84 A1 H D84 Ph 1063 Ph A1 D40 H D40 1113 Ph A1 D42 D42 H 1163 D84 A1 Ph H D84 1054 H A1 D40 Ph D40 1114 H A1 D42 D42 Ph 1164 D84 A1 H Ph D84 1065 Ph A1 H D40 D40 1115 Ph A1 D42 H D42 1165 Ph A1 D84 D84 H 1066 H A1 Ph D40 D40 1116 H A1 D42 Ph D42 1166 H A1 D84 D84 Ph 1067 D86 A1 D86 D88 H 111 Ph A1 H D42 D42 1167 Ph A1 D84 H D84 1068 D86 A1 D86 H D86 1118 H A1 Ph D42 D42 1168 H A1 D84 Ph D84 1069 D86 A1 H D86 D86 1119 D43 A1 D43 D43 H 1169 Ph A1 H D84 D84 1070 H A1 D86 D86 D86 1120 D43 A1 D43 H D43 1170 H A1 Ph D84 D84 1071 D86 A1 D86 D86 Ph 1121 D43 A1 H D43 D43 1171 D86 A1 D86 D86 H 1072 D86 A1 D86 Ph D86 1122 H A1 D43 D43 D43 1172 D86 A1 D86 H D86 1073 D86 A1 Ph D86 D86 1123 D43 A1 D43 D43 Ph 1173 D86 A1 H D86 D86 1074 Ph A1 D86 D86 D86 1124 D43 A1 D43 Ph D43 1174 H A1 D86 D86 D86 1075 D86 A1 D86 H H 1125 D43 A1 Ph D43 D43 1175 D86 A1 D86 D86 Ph 1076 D86 A1 H D86 H 1126 Ph A1 D43 D43 D43 1176 D86 A1 D86 Ph D86 1077 D86 A1 H H D86 1127 D43 A1 D43 H H 1177 D86 A1 Ph D86 D86 1078 H A1 D86 D86 H 1128 D43 A1 H D43 H 1178 Ph A1 D86 D86 D86 1079 H A1 D86 H D86 1129 D43 A1 H H D43 1179 D86 A1 D86 H H 1080 H A1 H D86 D86 1130 H A1 D43 D43 H 1180 D86 A1 H D86 H 1081 D86 A1 D86 Ph H 1131 H A1 D43 H D43 1181 D86 A1 H H D86 1082 D86 A1 D86 H Ph 1132 H A1 H D43 D43 1182 H A1 D86 D86 H 1083 D86 A1 Ph D86 H 1133 D43 A1 D43 Ph H 1183 H A1 D86 H D86 1084 D86 A1 H D86 Ph 1134 D43 A1 D43 H Ph 1184 H A1 H D86 D86 1085 D36 A1 Ph H D86 1135 D43 A1 Ph D43 H 1185 D86 A1 D86 Ph H 1086 D86 A1 H Ph D86 1136 D43 A1 H D43 Ph 1186 D86 A1 D86 H Ph 1087 Ph A1 D86 D86 H 1137 D43 A1 Ph H D43 1187 D86 A1 Ph D86 H 1088 H A1 D86 D86 Ph 1138 D43 A1 H Ph D43 1188 D86 A1 H D86 Ph 1089 Ph A1 D86 H D86 1139 Ph A1 D43 D43 H 1189 D86 A1 Ph H D86 1090 H A1 D86 Ph D86 1140 H A1 D43 D43 Ph 1190 D86 A1 H Ph D86 1091 Ph A1 H D86 D86 1141 Ph A1 D43 H D43 1191 Ph A1 D86 D86 H 1092 H A1 Ph D86 D86 1142 H A1 D43 Ph D43 1192 H A1 D86 D86 Ph 1093 D42 A1 D42 D42 H 1143 Ph A1 H D43 D43 1193 Ph A1 D86 H D86 1094 D42 A1 D42 H D42 1144 H A1 Ph D43 D43 1194 H A1 D86 Ph D86 1095 D42 A1 H D42 D42 1145 D84 A1 D84 D84 H 1195 Ph A1 H D86 D86 1096 H A1 D42 D42 D42 1146 D84 A1 D84 H D84 1196 H A1 Ph D86 D86 1097 D42 A1 D42 D42 Ph 1147 D84 A1 H D84 D84 1197 D87 A1 D87 D87 H 1098 D42 A1 D42 Ph D42 1148 H A1 D84 D84 D84 1198 D87 A1 D87 H D87 1099 D42 A1 Ph D42 D42 1149 D84 A1 D84 D84 Ph 1199 D87 A1 H D87 D87 1100 Ph A1 D42 D42 D42 1150 D84 A1 D84 Ph D84 1200 H A1 D87 D87 D87 1201 D87 A1 D87 D87 Ph 1251 D1 A2 H D1 D1 1301 D3 A2 D3 D3 H 1202 D87 A1 D87 Ph D87 1252 H A2 D1 D1 D1 1302 D3 A2 D3 H D3 1203 D87 A1 Ph D87 D87 1253 D1 A2 D1 D1 Ph 1303 D3 A2 H D3 D3 1204 Ph A1 D87 D87 D87 1254 D1 A2 D1 Ph D1 1304 H A2 D3 D3 D3 1205 D87 A1 D87 H H 1255 D1 A2 Ph D1 D1 1305 D3 A2 D3 D3 Ph 1206 D87 A1 H D87 H 1256 Ph A2 D1 D1 D1 1306 D3 A2 D3 Ph D3 1207 D87 A1 H H D87 1257 D1 A2 D1 H H 1307 D3 A2 Ph D3 D3 1208 H A1 D87 D87 H 1258 D1 A2 H D1 H 1308 Ph A2 D3 D3 D3 1209 H A1 D87 H D87 1259 D1 A2 H H D1 1309 D3 A2 D3 H H 1210 H A1 H D87 D87 1260 H A2 D1 D1 H 1310 D3 A2 H D3 H 1211 D87 A1 D87 Ph H 1261 H A2 D1 H D1 131 D3 A2 H H D3 1212 D87 A1 D87 H Ph 1262 H A2 H D1 D1 1312 H A2 D3 D3 H 1213 D87 A1 Ph D87 H 1263 D1 A2 D1 Ph H 1313 H A2 D3 H D3 1214 D87 A1 H D87 Ph 1264 D1 A2 D1 H Ph 1314 H A2 H D3 D3 1215 D87 A1 Ph H D87 1265 D1 A2 Ph D1 H 1315 D3 A2 D3 Ph H 1216 D87 A1 H Ph D87 1266 D1 A2 H D1 Ph 1316 D3 A2 D3 H Ph 1217 Ph A1 D87 D87 H 1267 D1 A2 Ph H D1 1317 D3 A2 Ph D3 H 1218 H A1 D87 D87 Ph 1268 D1 A2 H Ph D1 1318 D3 A2 H D3 Ph 1219 Ph A1 D87 H D87 1269 Ph A2 D1 D1 H 1319 D3 A2 Ph H D3 1220 H A1 D87 Ph D87 1270 H A2 D1 D1 Ph 1320 D3 A2 H Ph D3 1221 Ph A1 H D87 D87 1271 Ph A2 D1 H D1 1321 Ph A2 D3 D3 H 1222 H A1 Ph D87 D87 1272 H A2 D1 Ph D1 1322 H A2 D3 D3 Ph 1223 D88 A1 D88 D88 H 1273 Ph A2 H D1 D1 1323 Ph A2 D3 H D3 1224 D88 A1 D88 H D88 1274 H A2 Ph D1 D1 1324 H A2 D3 Ph D3 1225 D88 A1 H D88 D88 1275 D2 A2 D2 D2 H 1325 Ph A2 H D3 D3 1226 H A1 D88 D88 D88 1276 D2 A2 D2 H D2 1326 H A2 Ph D3 D3 1227 D88 A1 D88 D88 Ph 1277 D2 A2 H D2 D2 1327 D4 A2 D4 D4 H 1228 D88 A1 D88 Ph D88 1278 H A2 D2 D2 D2 1328 D4 A2 D4 H D4 1229 D88 A1 Ph D88 D88 1279 D2 A2 D2 D2 Ph 1329 D4 A2 H D4 D4 1230 Ph A1 D88 D88 D88 1280 D2 A2 D2 Ph D2 1330 H A2 D4 D4 D4 1231 D88 A1 D88 H H 1281 D2 A2 Ph D2 D2 1331 D4 A2 D4 D4 Ph 1232 D88 A1 H D88 H 1282 Ph A2 D2 D2 D2 1332 D4 A2 D4 Ph D4 1233 D88 A1 H H D88 1283 D2 A2 D2 H H 1333 D4 A2 Ph D4 D4 1234 H A1 D88 D88 H 1284 D2 A2 H D2 H 1334 Ph A2 D4 D4 D4 1235 H A1 D88 H D88 1285 D2 A2 H H D2 1335 D4 A2 D4 H H 1236 H A1 H D88 D88 1288 H A2 D2 D2 H 1336 D4 A2 H D4 H 1237 D88 A1 D88 Ph H 1287 H A2 D2 H D2 1337 D4 A2 H H D4 1238 D88 A1 D88 H Ph 1288 H A2 H D2 D2 1338 H A2 D4 D4 H 1239 D88 A1 Ph D88 H 1283 D2 A2 D2 Ph H 1339 H A2 D4 H D4 1240 D88 A1 H D88 Ph 1230 D2 A2 D2 H Ph 1340 H A2 H D4 D4 1241 D88 A1 Ph H D88 1291 D2 A2 Ph D2 H 1341 D4 A2 D4 Ph H 1242 D88 A1 H Ph D88 1292 D2 A2 H D2 Ph 1342 D4 A2 D4 H Ph 1243 Ph A1 D88 D88 H 1293 D2 A2 Ph H D2 1343 D4 A2 Ph D4 H 1244 H A1 D88 D88 Ph 1294 D2 A2 H Ph D2 1344 D4 A2 H D4 Ph 1245 Ph A1 D88 H D88 1235 Ph A2 D2 D2 H 1345 D4 A2 Ph H D4 1246 H A1 D88 Ph D88 1236 H A2 D2 D2 Ph 1346 D4 A2 H Ph D4 1247 Ph A1 H D88 D88 1297 Ph A2 D2 H D2 1347 Ph A2 D4 D4 H 1248 H A1 Ph D88 D88 1298 H A2 D2 Ph D2 1348 H A2 D4 D4 Ph 1249 D1 A2 D1 D1 H 1299 Ph A2 H D2 D2 1349 Ph A2 D4 H D4 1250 D1 A2 D1 H D1 1300 H A2 Ph D2 D2 1350 H A2 D4 Ph D4 1351 Ph A2 H D4 D4 1401 Ph A2 D86 H D86 1451 Ph A2 D43 D43 H 1352 H A2 Ph D4 D4 1402 H A2 D86 Ph D86 1452 H A2 D43 D43 Ph 1353 D40 A2 D40 D4 H 1403 Ph A2 H D86 D8B 1453 Ph A2 D43 H D43 1354 D40 A2 D40 H D40 1404 H A2 Ph D86 D86 1454 H A2 D43 Ph D43 1355 D40 A2 H D4 D40 1405 D42 A2 D42 D42 H 1455 Ph A2 H D43 D43 1356 H A2 D40 D4 D40 1406 D42 A2 D42 H D42 1456 H A2 Ph D43 D43 1357 D40 A2 D40 D4 Ph 1407 D42 A2 H D42 D42 1457 D84 A2 D84 D84 H 1358 D40 A2 D40 Ph D40 1408 H A2 D42 D42 D42 1458 D84 A2 D84 H D84 1359 D40 A2 Ph D4 D40 1409 D42 A2 D42 D42 Ph 1459 D84 A2 H D84 D84 1360 Ph A2 D40 D4 D40 1410 D42 A2 D42 Ph D42 1460 H A2 D84 D84 D84 1361 D40 A2 D40 H H 1411 D42 A2 Ph D42 D42 1461 D84 A2 D84 D84 Ph 1362 D40 A2 H D4 H 1412 Ph A2 D42 D42 D42 1462 D84 A2 D84 Ph D84 1363 D40 A2 H H D40 1413 D42 A2 D42 H H 1463 D84 A2 Ph D84 D84 1354 H A2 D40 D4 H 1414 D42 A2 H D42 H 1454 Ph A2 D84 D84 D84 1365 H A2 D40 H D40 1415 D42 A2 H H D42 1465 D84 A2 D84 H H 1366 H A2 H D4 D40 1416 H A2 D42 D42 H 1466 D84 A2 H D84 H 1367 D40 A2 D40 Ph H 1417 H A2 D42 H D42 1467 D84 A2 H H D84 1368 D40 A2 D40 H Ph 1418 H A2 H D42 D42 1468 H A2 D84 D84 H 1369 D40 A2 Ph D4 H 1419 D42 A2 D42 Ph H 1469 H A2 D84 H D84 1370 D40 A2 H D4 Ph 1420 D42 A2 D42 H Ph 1470 H A2 H D84 D84 1371 D40 A2 Ph H D40 1421 D42 A2 Ph D42 H 1471 D84 A2 D84 Ph H 1372 D40 A2 H Ph D40 1422 D42 A2 H D42 Ph 1472 D84 A2 D84 H Ph 1373 Ph A2 D40 D4 H 1423 D42 A2 Ph H D42 1473 D84 A2 Ph D84 H 1374 H A2 D40 D4 Ph 1424 D42 A2 H Ph D42 1474 D84 A2 H D84 Ph 1375 Ph A2 D40 H D40 1425 Ph A2 D42 D42 H 1475 D84 A2 Ph H D84 1376 H A2 D40 Ph D40 1426 H A2 D42 D42 Ph 1476 D84 A2 H Ph D84 1377 Ph A2 H D40 D40 1427 Ph A2 D42 H D42 1477 Ph A2 D84 D84 H 1373 H A2 Ph D40 D40 1428 H A2 D42 Ph D42 1478 H A2 D84 D84 Ph 1379 D86 A2 D86 D86 H 1429 Ph A2 H D42 D42 1479 Ph A2 D84 H D84 1380 D86 A2 D86 H D86 1430 H A2 Ph D42 D42 1480 H A2 D84 Ph D84 1381 D86 A2 H D86 D86 1431 D43 A2 D43 D43 H 1481 Ph A2 H D84 D84 1382 H A2 D86 D86 D86 1432 D43 A2 D43 H D43 1482 H A2 Ph D84 D84 1383 D86 A2 D86 D86 Ph 1433 D43 A2 H D43 D43 1483 D86 A2 D86 D86 H 1384 D86 A2 D86 Ph D86 1434 H A2 D43 D43 D43 1484 D86 A2 D86 H D86 1385 D86 A2 Ph D86 D86 1435 D43 A2 D43 D43 Ph 1485 D86 A2 H D86 D86 1386 Ph A2 D86 D86 D86 1436 D43 A2 D43 Ph D43 1486 H A2 D86 D86 D86 1387 D86 A2 D86 H H 1437 D43 A2 Ph D43 D43 1487 D86 A2 D86 D86 Ph 1388 D86 A2 H D86 H 1438 Ph A2 D43 D43 D43 1488 D86 A2 D86 Ph D86 1389 D86 A2 H H D86 1439 D43 A2 D43 H H 1489 D86 A2 Ph D86 D86 1390 H A2 D86 D86 H 1440 D43 A2 H D43 H 1490 Ph A2 D86 D86 D86 1391 H A2 D86 H D86 1441 D43 A2 H H D43 1491 D86 A2 D86 H H 1392 H A2 H D86 D86 1442 H A2 D43 D43 H 1492 D86 A2 H D86 H 1393 D86 A2 D86 Ph H 1443 H A2 D43 H D43 1493 D86 A2 H H D86 1394 D86 A2 D86 H Ph 1444 H A2 H D43 D43 1494 H A2 D86 D86 H 1395 D86 A2 Ph D8 H 1445 D43 A2 D43 Ph H 1495 H A2 D86 H D86 1396 D86 A2 H D8 Ph 1446 D43 A2 D43 H Ph 1496 H A2 H D86 D86 1397 D86 A2 Ph H D86 1447 D43 A2 Ph D43 H 1497 D86 A2 D86 Ph H 1398 D86 A2 H Ph D86 1448 D43 A2 H D43 Ph 1498 D86 A2 D86 H Ph 1399 Ph A2 D86 D86 H 1449 D43 A2 Ph H D43 1499 D86 A2 Ph D86 H 1400 H A2 D86 D86 Ph 1450 D43 A2 H Ph D43 1500 D86 A2 H D86 Ph 1501 D86 A2 Ph H D86 1551 D88 A2 Ph D88 H 1601 D2 A3 D2 Ph H 1502 D86 A2 H Ph D86 1552 D88 A2 H D88 Ph 1602 D2 A3 D2 H Ph 1503 Ph A2 D86 D86 H 1553 D88 A2 Ph H D88 1603 D2 A3 Ph D2 H 1504 H A2 D86 Ph 1554 D88 A2 H Ph D88 1604 D2 A3 H D2 Ph 1505 Ph A2 D86 H D86 1555 Ph A2 D88 D88 H 1605 D2 A3 Ph H D2 1506 H A2 D86 Ph D88 1556 H A2 D88 D88 Ph 1606 D2 A3 H Ph D2 1507 Ph A2 H D86 D86 1557 Ph A2 D88 H D88 1607 Ph A3 D2 D2 H 1508 H A2 Ph D86 D86 1558 H A2 D88 Ph D88 1608 H A3 D2 D2 Ph 1509 D87 A2 D87 D87 H 1559 Ph A2 H D88 D88 1609 Ph A3 D2 H D2 1510 D87 A2 D87 H D87 1560 H A2 Ph D88 D88 1610 H A3 D2 Ph D2 1511 D87 A2 H D87 D87 1561 D1 A3 D1 D1 H 1611 Ph A3 H D2 D2 1512 H A2 D87 D87 D87 1562 D1 A3 D1 H D1 1612 H A3 Ph D2 D2 1513 D87 A2 D87 D87 Ph 1563 D1 A3 H D1 D1 1613 D3 A3 D3 D3 H 1514 D87 A2 D87 Ph D87 1564 H A3 D1 D1 D1 1614 D3 A3 D3 H D3 1515 D87 A2 Ph D87 D87 1565 D1 A3 D1 D1 Ph 1615 D3 A3 H D3 D3 1516 Ph A2 D87 D87 D87 1566 D1 A3 D1 Ph D1 1616 H A3 D3 D3 D3 1517 D87 A2 D87 H H 1567 D1 A3 Ph D1 D1 1617 D3 A3 D3 D3 Ph 1518 D87 A2 H D87 H 1568 Ph A3 D1 D1 D1 1618 D3 A3 D3 Ph D3 1519 D87 A2 H H D87 1569 D1 A3 D1 H H 1619 D3 A3 Ph D3 D3 1520 H A2 D87 D87 H 1570 D1 A3 H D1 H 1620 Ph A3 D3 D3 D3 1521 H A2 D87 H D87 1571 D1 A3 H H D1 1621 D3 A3 D3 H H 1522 H A2 H D87 D87 1572 H A3 D1 D1 H 1622 D3 A3 H D3 H 1523 D87 A2 D87 Ph H 1573 H A3 D1 H D1 1623 D3 A3 H H D3 1524 D87 A2 D87 H Ph 1574 H A3 H D1 D1 1624 H A3 D3 D3 H 1525 D87 A2 Ph D87 H 1575 D1 A3 D1 Ph H 1625 H A3 DS H D3 1526 D87 A2 H D87 Ph 1576 D1 A3 D1 H Ph 1626 H A3 H D3 D3 1527 D87 A2 Ph H D87 1577 D1 A3 Ph D1 H 1627 D3 A3 D3 Ph H 1528 D87 A2 H Ph D87 1578 D1 A3 H D1 Ph 1628 D3 A3 D3 H Ph 1529 Ph A2 D87 D87 H 1579 D1 A3 Ph H D1 1629 D3 A3 Ph D3 H 1530 H A2 ns7 D87 Ph 1580 D1 A3 H Ph D1 1630 D3 A3 H D3 Ph 1531 Ph A2 D87 H D87 1581 Ph A3 D1 D1 H 1631 D3 A3 Ph H D3 1532 H A2 D87 Ph D87 1582 H A3 D1 D1 Ph 1632 D3 A3 H Ph D3 1533 Ph A2 H D87 D87 1583 Ph A3 D1 H D1 1633 Ph A3 D3 D3 H 1534 H A2 Ph D87 D87 1584 H A3 D1 Ph D1 1634 H A3 D3 D3 Ph 1535 D88 A2 D88 D88 H 1585 Ph A3 H D1 D1 1635 Ph A3 D3 H D3 1536 D88 A2 D88 H D88 1586 H A3 Ph D1 D1 1636 H A3 D3 Ph D3 1537 D88 A2 H D88 D88 1587 D2 A3 D2 D2 H 1637 Ph A3 H D3 D3 1538 H A2 D88 D88 D88 1588 D2 A3 D2 H D2 1638 H A3 Ph D3 D3 1539 D88 A2 D88 D88 Ph 1589 D2 A3 H D2 D2 1639 D4 A3 D4 D4 H 1540 D88 A2 D88 Ph D88 1590 H A3 D2 D2 D2 1640 D4 A3 D4 H D4 1541 D88 A2 Ph D88 D88 1591 D2 A3 D2 Ph 1641 D4 A3 H D4 D4 1542 Ph A2 D88 D88 D88 1592 D2 A3 D2 Ph D2 1642 H A3 D4 D4 D4 1543 D88 A2 D88 H H 1593 D2 A3 Ph D2 D2 1643 D4 A3 D4 D4 Ph 1544 D88 A2 H D88 H 1594 Ph A3 D2 D2 D2 1644 D4 A3 D4 Ph D4 1545 D88 A2 H H D88 1595 D2 A3 D2 H H 1645 D4 A3 Ph D4 D4 1546 H A2 D88 D88 H 1596 D2 A3 H D2 H 1646 Ph A3 D4 D4 D4 1547 H A2 D88 H D88 1597 D2 A3 H H D2 1647 D4 A3 D4 H H 1548 H A2 H D86 D88 1598 H A3 D2 D2 H 1648 D4 A3 H D4 H 1549 D88 A2 D88 Ph H 1599 H A3 D2 H D2 1649 D4 A3 H H D4 1550 D88 A2 D88 H Ph 1600 H A3 H D2 D2 1650 H A3 D4 D4 H 1651 H A3 D4 H D4 1701 D86 A3 H H D86 1751 D43 A3 D43 H H 1652 H A3 H D4 D4 1702 H A3 D86 D86 H 1752 D43 A3 H D43 H 1653 D4 A3 D4 Ph H 1703 H A3 D86 H D86 1753 D43 A3 H H D43 1654 D4 A3 D4 H Ph 1704 H A3 H D86 D86 1754 H A3 D43 D43 H 1655 D4 A3 Ph D4 H 1705 D86 A3 D86 Ph H 1755 H A3 D43 H D43 1656 D4 A3 H D4 Ph 1706 D86 A3 D86 H Ph 1756 H A3 H D43 D43 1657 D4 A3 Ph H D4 1707 D86 A3 Ph D86 H 1757 D43 A3 D43 Ph H 1658 D4 A3 H Ph D4 1708 D86 A3 H D86 Ph 1758 D43 A3 D43 H Ph 1659 Ph A3 D4 D4 H 1709 D86 A3 Ph H D86 1759 D43 A3 Ph D43 H 1660 H A3 D4 D4 Ph 1710 D86 A3 H Ph D86 1760 D43 A3 H D43 Ph 1661 Ph A3 D4 H D4 1711 Ph A3 D86 D86 H 1761 D43 A3 Ph H D43 1662 H A3 D4 Ph D4 1712 H A3 D86 D86 Ph 1762 D43 A3 H Ph D43 1663 Ph A3 H D4 D4 1713 Ph A3 D86 H D86 1763 Ph A3 D43 D43 H 1664 H A3 Ph D4 D4 1714 H A3 D86 Ph D86 1764 H A3 D43 D43 Ph 1665 D40 A3 D40 D40 H 1715 Ph A3 H D86 D86 1765 Ph A3 D43 H D43 1666 D40 A3 D40 H D40 1716 H A3 Ph D86 D86 1766 H A3 D43 Ph D43 1667 D40 A3 H D40 D40 1717 D42 A3 D42 D42 H 1767 Ph A3 H D43 D43 1668 H A3 D40 D40 D40 1718 D42 A3 D42 H D42 1768 H A3 Ph D43 D43 1669 D40 A3 D40 D40 Ph 1719 D42 A3 H D42 D42 1769 D84 A3 D84 D84 H 1670 D40 A3 D40 Ph D40 1720 H A3 D42 D42 D42 1770 D84 A3 D84 H D84 1671 D40 A3 Ph D40 D40 1721 D42 A3 D42 D42 Ph 1771 D84 A3 H D84 D84 1672 Ph A3 D40 D40 D40 1722 D42 A3 D42 Ph D42 1772 H A3 D84 D84 D84 1673 D40 A3 D40 H H 1723 D42 A3 Ph D42 D42 1773 D84 A3 D84 D84 Ph 1674 D40 A3 H D40 H 1724 Ph A3 D42 D42 D42 1774 D84 A3 D84 Ph D84 1675 D40 A3 H H D40 1725 D42 A3 D42 H H 1775 D84 A3 Ph D84 D84 1676 H A3 D40 D40 H 1726 D42 A3 H D42 H 1776 Ph A3 D84 D84 D84 1677 H A3 D40 H D40 1727 D42 A3 H H D42 1777 D84 A3 D84 H H 1678 H A3 H D40 D40 1728 H A3 D42 D42 H 1778 D84 A3 H D84 H 1679 D40 A3 D40 Ph H 1729 H A3 D42 H D42 1779 D84 A3 H H D84 1680 D40 A3 D40 H Ph 1730 H A3 H D42 D42 1780 H A3 D84 D84 H 1681 D40 A3 Ph D40 H 1731 D42 A3 D42 Ph H 1781 H A3 D84 H D84 1682 D40 A3 H D40 Ph 1732 D42 A3 D42 H Ph 1782 H A3 H D84 D84 1683 D40 A3 Ph H D40 1733 D42 A3 Ph D42 H 1783 D84 A3 D84 Ph H 1684 D40 A3 H Ph D40 1734 D42 A3 H D42 Ph 1784 D84 A3 D84 H Ph 1685 Ph A3 D40 D40 H 1735 D42 A3 Ph H D42 1785 D84 A3 Ph D84 H 1686 H A3 D40 D40 Ph 1736 D42 A3 H Ph D42 1786 D84 A3 H D84 Ph 1687 Ph A3 D40 H D40 1737 Ph A3 D42 D42 H 1787 D84 A3 Ph H D84 1688 H A3 D40 Ph D40 1738 H A3 D42 D42 Ph 1788 D84 A3 H Ph D84 1689 Ph A3 H D40 D40 1739 Ph A3 D42 H D42 1789 Ph A3 D84 D84 H 1690 H A3 Ph D40 D40 1740 H A3 D42 Ph D42 1790 H A3 D84 D84 Ph 1691 D86 A3 D86 D86 H 1741 Ph A3 H D42 D42 1791 Ph A3 D84 H D84 1692 D86 A3 D86 H D86 1742 H A3 Ph D42 D42 1792 H A3 D84 Ph D84 1693 D86 A3 H D8R D86 1743 D43 A3 D43 D43 H 1793 Ph A3 H D84 D84 1694 H A3 D86 D86 D86 1744 D43 A3 D43 H D43 1794 H A3 Ph D84 D84 1695 D86 A3 D86 D86 Ph 1745 D43 A3 H D43 D43 1795 D86 A3 D86 D86 H 1696 D86 A3 D86 Ph D86 1746 H A3 D43 D43 D43 1796 D86 A3 D86 H D86 1697 D86 A3 Ph D86 D86 1747 D43 A3 D43 D43 Ph 1797 D86 A3 H D86 D86 1698 Ph A3 D86 D86 D86 1748 D43 A3 D43 Ph D43 1798 H A3 D86 D86 D86 1699 D86 A3 D86 H H 1749 D43 A3 Ph D43 D43 1799 D86 A3 D86 D86 Ph 1700 D86 A3 H D86 H 1750 Ph A3 D43 D43 D43 1800 D86 A3 D86 Ph D86 1801 D86 A3 Ph D86 D86 1851 D88 A3 D88 D88 Ph 1901 A13 H D84 D84 D84 1802 Ph A3 D86 D86 D86 1852 D88 A3 D88 Ph D88 1902 A13 D84 H D84 D84 1803 D86 A3 D86 H H 1853 D88 A3 Ph D88 D88 1903 A13 DB4 1>84 H D84 1804 D86 A3 H D86 H 1854 Ph A3 D88 D88 D88 1904 A13 D84 DR4 DR4 H 1805 D86 A3 H H D86 1855 D88 A3 D88 H H 1905 A14 H D84 D84 D84 1806 H A3 D86 D86 H 1856 D88 A3 H D88 H 1906 A14 D84 H D84 D84 1807 H A3 D86 H D86 1857 D88 A3 H H D88 1907 A14 D84 D84 H D84 1808 H A3 H D86 D86 1858 H A3 D88 D88 H 1908 A14 D84 D84 D84 H 1809 D86 A3 D86 Ph H 1859 H A3 D88 H D88 1909 A13 Ph D1 D1 H 1810 D86 A3 D86 H Ph 1860 H A3 H D88 D88 1910 A13 D1 Ph D1 H 1811 D86 A3 Ph D86 H 1861 D88 A3 D88 Ph H 1911 A13 D1 D1 Ph H 1812 D86 A3 H D86 Ph 1862 D88 A3 D88 H Ph 1912 A13 Ph D1 H D1 1813 D86 A3 Ph H D86 1863 D88 A3 Ph D88 H 1913 A13 D1 Ph H D1 1814 D86 A3 H Ph D86 1864 A3 H D88 Ph 1914 A13 D1 D1 H Ph 1815 Ph A3 D86 D86 H 1865 D88 A3 Ph H D88 1915 A13 Ph H D1 D1 1816 H A3 D86 P86 Ph 1866 D88 A3 H Ph D88 1916 A13 D1 H Ph D1 1817 Ph A3 D86 H D86 1867 Ph A3 D88 D88 H 1917 A13 D1 H D1 Ph 1818 H A3 D86 Ph D86 1868 H A3 D88 D88 Ph 1918 A13 H Ph D1 D1 1819 Ph A3 H D86 D86 1869 Ph A3 D88 H D88 1919 A13 H D1 Ph D1 1820 H A3 Ph D86 D86 1870 H A3 D88 Ph D88 1920 A13 H D1 D1 Ph 1821 D87 A3 D87 D87 H 1871 Ph A3 H D88 D88 1921 A14 Ph D1 D1 H 1822 D87 A3 D87 H D87 1872 H A3 Ph D88 D88 1922 A14 D1 Ph D1 H 1823 D87 A3 H D87 D87 1873 A1 D94 D1 D1 D1 1923 A14 D1 D1 Ph H 1824 H A3 D87 D87 D87 1874 A1 D95 D1 D1 D1 1924 A14 Ph D1 H D1 1825 D87 A3 D87 D87 Ph 1875 A1 D96 D1 D1 D1 1925 A14 D1 Ph H D1 1826 D87 A3 D87 Ph D87 1876 A1 D94 D86 D86 D86 1926 A14 D1 D1 H Ph 1827 D87 A3 Ph D87 D87 1877 A1 D95 D86 D86 D86 1927 A14 Ph H D1 D1 1828 Ph A3 D87 D87 D87 1878 A1 D96 D86 D86 D86 1928 A14 D1 H Ph D1 1829 D87 A3 D87 H H 1879 A1 H D94 D1 D1 1929 A14 D1 H D1 Ph 1830 D87 A3 H D87 H 1880 A1 H D95 D1 D1 1930 A14 H Ph D1 D1 1831 D87 A3 H H D87 1881 A1 H D96 D1 D1 1931 A14 H D1 Ph D1 1832 H A3 D87 D87 H 1882 A1 H D94 D86 D86 1932 A14 H D1 D1 Ph 1833 H A3 D87 H D87 1883 A1 H D95 D86 D86 1933 A13 Ph D84 D84 H 1834 H A3 H D87 D87 1884 A1 H D96 D86 D86 1934 A13 D84 Ph D84 H 1835 D87 A3 D87 Ph H 1885 A13 H D1 D1 D1 1935 A13 D84 D84 Ph H 1836 D87 A3 D87 H Ph 1886 A13 D1 H D1 D1 1938 A13 Ph D84 H D84 1837 D87 A3 Ph D87 H 1887 A13 D1 D1 H D1 1937 A13 D84 Ph H D84 1838 D87 A3 H D87 Ph 1888 A13 D1 D1 D1 H 1938 A13 D84 DR4 H Ph 1839 D87 A3 Ph H D87 1889 A14 H D1 D1 D1 1939 A13 Ph H D84 D84 1840 D87 A3 H Ph D87 1890 A14 D1 H D1 D1 1940 A13 D84 H Ph D84 1841 Ph A3 D87 D87 H 1891 A14 D1 D1 H D1 1941 A13 D84 H D84 Ph 1842 H A3 D87 D87 Ph 1892 A14 D1 D1 D1 H 1942 A13 H Ph D84 D84 1843 Ph A3 D87 H D87 1833 A13 H D1 D1 D84 1943 A13 H D84 Ph D84 1844 H A3 D87 Ph D87 1894 A13 P1 H D84 D1 1944 A13 H D84 DR4 Ph 1845 Ph A3 H D87 D87 1895 A13 D1 D84 H D1 1945 A14 Ph DR4 D84 H 1846 H A3 Ph D87 D87 1896 A13 D84 D1 D1 H 1946 A14 D84 Ph D84 H 1847 D88 A3 D88 D88 H 1897 A14 H D1 D1 D84 1947 A14 D84 D84 Ph H 1848 D88 A3 D88 H D88 1898 A14 D1 H D84 D1 1948 A14 Ph D84 H D84 1849 D88 A3 H D88 D88 1899 A14 P1 D84 H D1 1949 A14 DM Ph H DM 1850 H A3 D88 D88 D88 1900 A14 D84 D1 D1 H 1950 A14 D84 D84 H Ph 1951 A14 Ph H D84 D84 2001 D86 A1 H D86 D96 2051 H A14 Ph D1 D1 1952 A14 D84 H Ph D84 2002 D86 A1 H D96 D88 2052 H A14 D1 Ph D1 1953 A14 DR4 H D84 Ph 2003 H A1 D96 D86 D86 2053 H A14 D1 11 Ph 1954 A14 H Ph D84 D84 2004 D96 A1 H D86 D86 2054 Ph A13 D84 84 H 1955 A14 H D84 Ph D84 2005 H A14 H D1 D1 2055 D84 A13 Ph D84 H 1956 A14 H D84 DR4 Ph 2006 H A13 D1 D1 D1 2056 D84 A13 D84 Ph H 1957 A13 Ph D1 D1 D1 2007 D1 A13 H D1 D1 2057 Ph A13 D84 H D84 1958 A13 D1 Ph D1 D1 2008 D1 A13 D1 H D1 2058 D84 A13 Ph H D84 1959 A13 D1 D1 Ph D1 2009 D1 13 D1 D1 H 2059 D84 A13 D84 H Ph 1960 A13 D1 D1 D1 Ph 2010 H A14 D1 D1 D1 2060 Ph A13 H D84 D84 1961 A14 Ph D1 D1 D1 2011 D1 A14 H D1 D1 2061 D84 A13 H Ph D84 1962 A14 D1 Ph D1 D1 2012 D1 A14 D1 H D1 2062 D84 A13 H D84 Ph 1963 A14 D1 D1 Ph D1 2013 D1 A14 D1 D1 H 2063 H A13 Ph D84 D84 1964 A14 D1 D1 D1 Ph 2014 H 1R D1 D1 D84 2064 H A13 D84 Ph DR4 1965 A13 Ph D1 D1 D84 2015 D1 A13 H D84 D1 2065 H A13 D84 D84 Ph 1966 A13 D1 Ph D84 D1 2016 D1 A13 D84 H D1 2066 Ph A14 D84 D84 H 1967 A13 D1 D84 Ph D1 2017 D84 A13 D1 D1 H 2067 D84 A14 Ph D84 H 1968 A13 D84 D1 D1 Ph 2018 H A14 D1 D1 D84 2068 D84 A14 D84 Ph H 1969 A14 Ph D1 D1 D84 2019 D1 A14 H D84 D1 2069 Ph A14 D84 H D84 1970 A14 D1 Ph D84 D1 2020 D1 A14 D84 H D1 2070 D84 A14 Ph H D84 1971 A14 D1 D84 Ph D1 2021 D84 A14 D1 D1 H 2071 D84 A14 D84 H Ph 1972 A14 D84 D1 D1 Ph 2022 H A13 D84 D84 D84 2072 Ph A14 H D84 D84 1973 A13 Ph D84 D84 D84 2023 D84 A13 H D84 D84 2073 D84 A14 H Ph D84 1974 A13 D84 Ph D84 D84 2024 D84 A13 D84 H D84 2074 D84 A14 H D84 Ph 1975 A13 D84 D84 Ph D84 2025 D84 A13 D84 D84 H 2075 H A14 Ph D84 D84 1976 A13 D84 D84 D84 Ph 2026 H A14 D84 D84 D84 2076 H A14 D84 Ph D84 1977 A14 Ph D84 D84 D84 2027 D84 A14 H D84 D84 2077 H A14 D84 D84 Ph 1978 A14 D84 Ph D84 D84 2028 D84 A14 D84 H D84 2078 Ph A13 D1 D1 D1 1979 A14 D84 D84 Ph D84 2029 D84 A14 D84 D84 H 2079 D1 A13 Ph D1 D1 1980 A14 D84 D84 D84 Ph 2030 Ph A13 D1 D1 H 2080 D1 A13 D1 Ph D1 1981 D1 A1 H D1 D95 2031 D1 A13 Ph D1 H 2081 D1 A13 D1 D1 Ph 1982 D1 A1 H D95 D1 2032 D1 A13 D1 Ph H 2082 Ph A14 D1 D1 D1 1983 H A1 D95 D1 D1 2033 Ph A13 D1 H D1 2083 D1 A14 Ph D1 D1 1984 D95 A1 H D1 D1 2034 D1 A13 Ph H D1 2084 D1 A14 D1 Ph D1 1985 D1 A1 H D1 D94 2035 D1 A13 D1 H Ph 2085 D1 A14 D1 D1 Ph 1986 D1 A1 H D94 D1 2036 Ph A13 H D1 D1 2086 Ph A13 D1 D1 D84 1987 H A1 D94 D1 D1 2037 D1 A13 H Ph D1 2087 D1 A13 Ph D84 D1 1988 D94 A1 H D1 D1 2038 D1 A13 H D1 Ph 2088 D1 A13 D84 Ph D1 1989 D1 A1 H D1 D96 2039 H A13 Ph D1 D1 2089 D84 A13 D1 D1 Ph 1990 D1 A1 H D96 D1 2040 H A13 D1 Ph D1 2090 Ph A14 D1 D1 D84 1991 H A1 D96 171 M 2041 H A13 D1 D1 Ph 2091 D1 A14 Ph D84 D1 1992 D96 A1 H D1 D1 2042 Ph A14 D1 D1 H 2092 D1 A14 D84 Ph D1 1993 D86 A1 H D86 D95 2043 D1 A14 Ph D1 H 2093 D84 A14 D1 D1 Ph 1994 D86 A1 H D95 D86 2044 D1 A14 D1 Ph H 2094 Ph A13 D84 D84 D84 1995 H A1 D95 D86 D86 2045 Ph A14 D1 H D1 2095 D84 A13 Ph D84 D84 1996 D95 A1 H D86 D86 2046 D1 A14 Ph H D1 2096 D84 A13 D84 Ph D84 1997 D86 1 H D86 D94 2047 D1 14 D1 H Ph 2097 D84 A13 D84 D84 Ph 1998 D86 A1 H D94 D86 2048 Ph A14 H D1 D1 2098 Ph A14 D84 D84 D84 1999 H A1 D94 D86 D86 2049 D1 A14 H Ph D1 2099 D84 A14 Ph D84 D84 2000 D94 A1 H D86 D86 2050 D1 A14 H D1 Ph 2100 D84 A14 D84 Ph D84 2101 D84 A14 D84 D84 Ph 2151 A4 H D2 Ph D2 2201 A4 H D4 D4 Ph 2102 A4 D1 D1 D1 H 2152 A4 Ph H D2 D2 2202 A4 Ph D4 H D4 2103 A4 D1 D1 H D1 2153 A4 H Ph D2 D2 2203 A4 H D4 Ph D4 2104 A4 D1 H D1 D1 2154 A4 D3 D3 D3 H 2204 A4 Ph H D4 D4 2105 A4 H D1 D1 D1 2155 A4 D3 D3 H D3 2205 A4 H Ph D4 D4 2106 A4 D1 D1 D1 Ph 2156 A4 D3 H D3 D3 2206 A4 D40 D40 D40 H 2107 A4 D1 D1 Ph D1 2157 A4 H D3 D3 D3 2207 A4 D40 D40 H D40 2108 A4 D1 Ph D1 D1 2158 A4 D3 D3 D3 Ph 2208 A4 D40 H D40 D40 2109 A4 Ph D1 D1 D1 2159 A4 D3 D3 Ph D3 2209 A4 H D40 D40 D40 2110 A4 D1 D1 H H 2160 A4 D3 Ph D3 D3 2210 A4 D40 D40 D40 Ph 2111 A4 D1 H D1 H 2161 A4 D3 D3 D3 D3 2211 A4 D40 D40 Ph D40 2112 A4 D1 H H D1 2162 A4 D3 D3 H H 2212 A4 D40 Ph D40 D40 2113 A4 H D1 D1 H 2163 A4 D3 H D3 H 2213 A4 Ph D40 D40 D40 2114 A4 H D1 H D1 2164 A4 D3 H H D3 2214 A4 D40 D40 H H 2115 A4 H H D1 D1 2165 A4 H D3 D3 H 2215 A4 D40 H D40 H 2116 A4 D1 D1 Ph H 2166 A4 H D3 H D3 2216 A4 D40 H H D40 2117 A4 D1 D1 H Ph 2167 A4 H H D3 D3 2217 A4 H D40 D40 H 2118 A4 D1 Ph D1 H 2168 A4 D3 D3 Ph H 2218 A4 H D40 H D40 2119 A4 D1 H D1 Ph 2169 A4 D3 D3 H Ph 2219 A4 H H D40 D40 2120 A4 D1 Ph H D1 2170 A4 D3 Ph D3 H 2220 A4 D40 D40 Ph H 2121 A4 D1 H Ph D1 2171 A4 D3 H D3 Ph 2221 A4 D40 D40 H Ph 2122 A4 Ph D1 D1 H 2172 A4 D3 Ph H D3 2222 A4 D40 Ph D40 H 2123 A4 H D1 D1 Ph 2173 A4 D3 H Ph D3 2223 A4 D40 H D40 Ph 2124 A4 Ph D1 H D1 2174 A4 Ph D3 D3 H 2224 A4 D40 Ph H D40 2125 A4 H D1 Ph D1 2175 A4 H D3 D3 Ph 2225 A4 D40 H Ph D40 2126 A4 Ph H D1 D1 2176 A4 Ph D3 H D3 2226 A4 Ph D40 D4D H 2127 A4 H Ph D1 D1 2177 A4 H D3 Ph D3 2227 A4 H D40 D40 Ph 2128 A4 D2 D2 D2 H 2178 A4 Ph H D3 D3 2228 A4 Ph D40 H D40 2129 A4 D2 D2 H D2 2179 A4 H Ph D3 D3 2229 A4 H D40 Ph D40 2130 A4 D2 H D2 D2 2180 A4 D4 D4 D4 H 2230 A4 Ph H D40 D40 2131 A4 H D2 D2 D2 2181 A4 D4 D4 H D4 2231 A4 H Ph D40 D40 2132 A4 D2 D2 D2 Ph 2182 A4 D4 H D4 D4 2232 A4 D41 D41 D41 H 2133 A4 D2 D2 Ph D2 2183 A4 H D4 D4 D4 2233 A4 D41 D41 H D41 2134 A4 D2 Ph D2 D2 2184 A4 D4 D4 D4 Ph 2234 A4 D41 H D41 D41 2135 A4 Ph D2 D2 D2 2185 A4 D4 D4 Ph D4 2235 A4 H D41 D41 D41 2136 A4 D2 D2 H H 2186 A4 D4 Ph D4 D4 2236 A4 D41 D41 D41 Ph 2137 A4 D2 H D2 H 2187 A4 Ph D4 D4 D4 2237 A4 D41 D41 Ph D41 2138 A4 D2 H H D2 2188 A4 D4 D4 H H 2238 A4 D41 Ph D41 D41 2139 A4 H D2 D2 H 2189 A4 D4 H D4 H 2239 A4 Ph D41 D41 D41 2140 A4 H D2 H D2 2190 A4 D4 H H D4 2240 A4 D41 D41 H H 2141 A4 H H D2 D2 2191 A4 H D4 D4 H 2241 A4 D41 H D41 H 2142 A4 D2 D2 Ph H 2192 A4 H D4 H D4 2242 A4 D41 H H D41 2143 A4 D2 D2 H Ph 2193 A4 H H D4 D4 2243 A4 H D41 D41 H 2144 A4 D2 Ph D2 H 2194 A4 D4 D4 Ph H 2244 A4 H D41 H D41 2145 A4 D2 H D2 Ph 2195 A4 D4 D4 H Ph 2245 A4 H H D41 D41 2146 A4 D2 Ph H D2 2136 A4 D4 Ph D4 H 2246 A4 D41 D41 Ph H 2147 A4 D2 H Ph D2 2197 A4 D4 H D4 Ph 2247 A4 D41 D41 H Ph 2148 A4 Ph D2 D2 H 2198 A4 D4 Ph H D4 2248 A4 D41 Ph D41 H 2149 A4 H D2 D2 Ph 2199 A4 D4 H Ph D4 2249 A4 D41 H D41 Ph 2150 A4 Ph D2 H D2 2200 A4 Ph D4 D4 H 2250 A4 D41 Ph H D41 2251 A4 D41 H Ph D41 2301 A4 D43 H D43 Ph 2351 A4 D86 D86 H Ph 2252 A4 Ph D41 D41 H 2302 A4 D43 Ph H D43 2352 A4 D86 Ph D86 H 2253 A4 H D41 D41 Ph 2303 A4 D43 H Ph D43 2353 A4 D86 H D86 Ph 2254 A4 Ph D41 H D41 2304 A4 Ph D43 D43 H 2354 A4 D86 Ph H D86 2255 A4 H D41 Ph D41 2305 A4 H D43 D43 Ph 2355 A4 D86 H Ph D86 2256 A4 Ph H D41 D41 2306 A4 Ph D43 H D43 2356 A4 Ph D86 D86 H 2257 A4 H Ph D41 D41 2307 A4 H D43 Ph D43 2357 A4 H D86 D86 Ph 2258 A4 D42 D42 D42 H 2308 A4 Ph H D43 D43 2358 A4 Ph D86 H D86 2259 A4 D42 D42 H D42 2309 A4 H Ph D43 D43 2359 A4 H D86 Ph D86 2260 A4 D42 H D42 D42 2310 A4 D84 D84 D84 H 2360 A4 Ph H D86 D86 2261 A4 H D42 D42 D42 2311 A4 D84 D84 H D84 2361 A4 H Ph D86 D86 2262 A4 D42 D42 D42 Ph 2312 A4 D84 H D84 D84 2362 A4 D87 D87 D87 H 2263 A4 D42 D42 Ph D42 2313 A4 H D84 D84 D84 2363 A4 D87 D87 H D87 2264 A4 D42 Ph D42 D42 2314 A4 D84 D84 D84 Ph 2364 A4 D87 H D87 D87 2265 A4 Ph D42 D42 D42 2315 A4 D84 D84 Ph D84 2365 A4 H D87 D87 D87 2266 A4 D42 D42 H H 2316 A4 D84 Ph D84 D84 2366 A4 D87 D87 D87 Ph 2267 A4 D42 H D42 H 2317 A4 Ph D84 D84 D84 2367 A4 D87 D87 Ph D87 2268 A4 D42 H H D42 2318 A4 D84 D84 H H 2368 A4 D87 Ph D87 D87 2269 A4 H D42 D42 H 2319 A4 D84 H D84 H 2369 A4 Ph D87 D87 D87 2270 A4 H D42 H D42 2320 A4 D84 H H D84 2370 A4 D87 D87 H H 2271 A4 H H D42 D42 2321 A4 H D84 D84 H 2371 A4 D87 H D87 H 2272 A4 D42 D42 Ph H 2322 A4 H D84 H D84 2372 A4 D87 H H D87 2273 A4 D42 D42 H Ph 2323 A4 H H D84 D84 2373 A4 H D87 D87 H 2274 A4 D42 Ph D42 H 2324 A4 D84 D84 Ph H 2374 A4 H D87 H D87 2275 A4 D42 H D42 Ph 2325 A4 D84 D84 H Ph 2375 A4 H H D87 D87 2276 A4 D42 Ph H D42 2326 A4 D84 Ph D84 H 2376 A4 D87 D87 Ph H 2277 A4 D42 H Ph D42 2327 A4 D84 H D84 Ph 2377 A4 D87 D87 H Ph 2278 A4 Ph D42 D42 H 2328 A4 D84 Ph H D84 2378 A4 D87 Ph D87 H 2279 A4 H D42 D42 Ph 2329 A4 D84 H Ph D84 2379 A4 D87 H D87 Ph 2280 A4 Ph D42 H D42 2330 A4 Ph D84 D84 H 2380 A4 D87 Ph H D87 2281 A4 H D42 Ph D42 2331 A4 H D84 D84 Ph 2381 A4 D87 H Ph D87 2282 A4 Ph H D42 D42 2332 A4 Ph D84 H D84 2382 A4 Ph D87 D87 H 2283 A4 H Ph D42 D42 2333 A4 H D84 Ph D84 2383 A4 H D87 D87 Ph 2284 A4 D43 D43 D43 H 2334 A4 Ph H D84 D84 2384 A4 Ph D87 H D87 2285 A4 D43 D43 H D43 2335 A4 H Ph D84 D84 2385 A4 H D87 Ph D87 2286 A4 D43 H D43 D43 2336 A4 D86 D86 D86 H 2386 A4 Ph H D87 D87 2287 A4 H D43 D43 D43 2337 A4 D86 D86 H D86 2387 A4 H Ph D87 D87 2288 A4 D43 D43 D43 Ph 2338 A4 D86 H D86 D86 2388 A4 D88 D88 D88 H 2289 A4 D43 D43 Ph D43 2339 A4 H D86 D86 D86 2389 A4 D88 D88 H D88 2290 A4 D43 Ph D43 D43 2340 A4 D86 D86 D86 Ph 2390 A4 D88 H D88 D88 2291 A4 Ph D43 D43 D43 2341 A4 D86 D86 Ph D86 2391 A4 H D88 D88 D88 2292 A4 D43 D43 H H 2342 A4 D86 Ph D86 D86 2392 A4 D88 D88 D88 Ph 2293 A4 D43 H D43 H 2343 A4 Ph D86 D86 D86 2393 A4 D88 D88 Ph D88 2294 A4 D43 H H D43 2344 A4 D86 D86 H H 2394 A4 D88 Ph D88 D88 2295 A4 H D43 D43 H 2345 A4 D86 H D86 H 2395 A4 Ph D88 D88 D88 2296 A4 H D43 H D43 2346 A4 D86 H H D86 2396 A4 D88 D88 H H 2297 A4 H H D43 D43 2347 A4 H D86 D86 H 2397 A4 D88 H D88 H 2298 A4 D43 D43 Ph H 2348 A4 H D86 H D86 2398 A4 D88 H H D88 2299 A4 D43 D43 H Ph 2349 A4 H H D86 D86 2399 A4 H D88 D88 H 2300 A4 D43 Ph D43 H 2350 A4 D86 D86 Ph H 2400 A4 H D88 H D88 2401 A4 H H D88 D88 2451 A12 H D2 D2 H 2501 A12 D4 H D4 H 2402 A4 D88 D88 Ph H 2452 A12 H D2 H D2 2502 A12 D4 H H D4 2403 A4 D88 D88 H Ph 2453 A12 H H D2 D2 2503 A12 H D4 D4 H 2404 A4 D88 Ph D88 H 2454 A12 D2 D2 Ph H 2504 A12 H D4 H D4 2405 A4 D88 H D88 Ph 2455 A12 D2 D2 H Ph 2505 A12 H H D4 D4 2406 A4 D88 Ph H D88 2456 A12 D2 Ph D2 H 2506 A12 D4 D4 Ph H 2407 A4 D38 H Ph D88 2457 A12 D2 H D2 Ph 2507 A12 D4 D4 H Ph 2408 A4 Ph D88 D88 H 2458 A12 D2 Ph H D2 2508 A12 D4 Ph D4 H 2409 A4 H D88 D88 Ph 2459 A12 D2 H Ph D2 2509 A12 D4 H D4 Ph 2410 A4 Ph D88 H D88 2480 A12 Ph D2 D2 H 2510 A12 D4 Ph H D4 2411 A4 H D88 Ph D88 2461 A12 H D2 D2 Ph 2511 A12 D4 H Ph D4 2412 A4 Ph H D88 D88 2462 A12 Ph D2 H D2 2512 A12 Ph D4 D4 H 2413 A4 H Ph D88 D88 2463 A12 H D2 Ph D2 2513 A12 H D4 D4 Ph 2414 A12 D1 D1 D1 H 2464 A12 Ph H D2 D2 2514 A12 Ph D4 H D4 2415 A12 D1 D1 H D1 2465 A12 H Ph D2 D2 2515 A12 H D4 Ph D4 2416 A12 D1 H D1 D1 2466 A12 D3 D3 D3 H 2516 A12 Ph H D4 D4 2417 A12 H D1 D1 D1 2467 A12 D3 D3 H D3 2517 A12 H Ph D4 D4 2418 A12 D1 D1 D1 Ph 2468 A12 D3 H D3 D3 2518 A12 D40 D40 D40 H 2410 A12 D1 D1 Ph D1 2469 A12 H D3 D3 D3 2519 A12 D40 D40 H D40 2420 A12 D1 Ph D1 D1 2470 A12 D3 D3 D3 Ph 2520 A12 D40 H D40 D40 2421 A12 Ph D1 D1 D1 2471 A12 D3 D3 Ph D3 2521 A12 H D40 D40 D40 2422 A12 D1 D1 H H 2472 A12 D3 Ph D3 D3 2522 A12 D40 D40 D40 Ph 2423 A12 D1 H D1 H 2473 A12 Ph D3 D3 D3 2523 A12 D40 D40 Ph D40 2424 A12 D1 H H D1 2474 A12 D3 D3 H H 2524 A12 D40 Ph D40 D40 2425 A12 H D1 D1 H 2475 A12 D3 H D3 H 2525 A12 Ph D40 D40 D40 2426 A12 H D1 H D1 2476 A12 D3 H H D3 2526 A12 D40 D40 H H 2427 A12 H H D1 D1 2477 A12 H D3 D3 H 2527 A12 D40 H D40 H 2428 A12 D1 D1 Ph H 2478 A12 H D3 H D3 2528 A12 D40 H H D40 2429 A12 D1 D1 H Ph 2479 A12 H H D3 D3 2529 A12 H D40 D40 H 2430 A12 D1 Ph D1 H 2480 A12 D3 D3 Ph H 2530 A12 H D40 H D40 2431 A12 D1 H D1 Ph 2481 A12 D3 D3 H Ph 2531 A12 H H D40 D40 2432 A12 D1 Ph H D1 2482 A12 D3 Ph D3 H 2532 A12 D40 D40 Ph H 2433 A12 D1 H Ph D1 2483 A12 D3 H D3 Ph 2533 A12 D40 D40 H Ph 2434 A12 Ph D1 D1 H 2484 A12 D3 Ph H D3 2534 A12 D40 Ph D40 H 2435 A12 H D1 D1 Ph 2485 A12 D3 H Ph D3 2535 A12 D40 H D40 Ph 2436 A12 Ph D1 H D1 2486 A12 Ph D3 D3 H 2536 A12 D40 Ph H D40 2437 A12 H D1 Ph D1 2487 A12 H D3 D3 Ph 2537 A12 D40 H Ph D40 2438 A12 Ph H D1 D1 2488 A12 Ph D3 H D3 2538 A12 Ph D40 D40 H 2439 A12 H Ph D1 D1 2489 A12 H D3 Ph D3 2539 A12 H D40 D40 Ph 2440 A12 D2 D2 D2 H 2490 A12 Ph H D3 D3 2540 A12 Ph D40 H D40 2441 A12 D2 D2 H D2 2491 A12 H Ph D3 D3 2541 A12 H D40 Ph D40 2442 A12 D2 H D2 D2 2492 A12 D4 D4 D4 H 2542 A12 Ph H D40 D40 2443 A12 H D2 D2 D2 2493 A12 D4 D4 H D4 2543 A12 H Ph D40 D40 2444 A12 D2 D2 D2 Ph 2494 A12 D4 H D4 D4 2544 A12 D41 D41 D41 H 2445 A12 D2 D2 Ph D2 2495 A12 H D4 D4 D4 2545 A12 D41 D41 H D41 2446 A12 D2 Ph D2 D2 2496 A12 D4 D4 D4 Ph 2546 A12 D41 H D41 D41 2447 A12 Ph D2 D2 D2 2497 A12 D4 D4 Ph D4 2547 A12 H D41 D41 D41 2448 A12 D2 D2 H H 2498 A12 D4 Ph D4 D4 2548 A12 D41 D41 D41 Ph 2449 A12 D2 H D2 H 2499 A12 Ph D4 D4 D4 2549 A12 D41 D41 Ph D41 2450 A12 D2 H H D2 2500 A12 D4 D4 H H 2550 A12 D41 Ph D41 D41 2551 A12 Ph D41 D41 D41 2601 A12 D43 D43 Ph D43 2651 A12 H D86 D86 D86 2552 A12 D41 D41 H H 2602 A12 D43 Ph D43 D43 2652 A12 D86 D86 D86 Ph 2553 A12 D41 H D41 H 2603 A12 Ph D43 D43 D43 2653 A12 D86 D86 Ph D86 2554 A12 D41 H H D41 2604 A12 D43 D43 H H 2654 A12 D86 Ph D86 D86 2555 A12 H D41 D41 H 2605 A12 D43 H D43 H 2655 A12 Ph D86 D86 D86 2556 A12 H D41 H D41 2606 A12 D43 H H D43 2656 A12 D86 D86 H H 2557 A12 H H D41 D41 2607 A12 H D43 D43 H 265 A12 D86 H D86 H 2558 A12 D41 D41 Ph H 2608 A12 H D43 H D43 2658 A12 D86 H H D86 2559 A12 D41 D41 H Ph 2608 A12 H H D43 D43 2659 A12 H D86 D86 H 2560 A12 D41 Ph D41 H 2610 A12 D43 D43 Ph H 2660 A12 H D86 H D86 2561 A12 D41 H D41 Ph 2611 A12 D43 D43 H Ph 266 A12 H H D86 D86 2562 A12 D41 Ph H D41 2612 A12 D43 Ph D43 H 2662 A12 D86 D86 Ph H 2553 A12 D41 H Ph D41 2613 A12 D43 H D43 Ph 2663 A12 D86 D86 H Ph 2554 A12 Ph D41 D41 H 2614 A12 D43 Ph H D43 2664 A12 D86 Ph D86 H 2565 A12 H D41 D41 Ph 2615 A12 D43 H Ph D43 2665 A12 D86 H D86 Ph 2566 A12 Ph D41 H D41 2616 A12 Ph D43 D43 H 2666 A12 D86 Ph H D86 2567 A12 H D41 Ph D41 2617 A12 H D43 D43 Ph 2667 A12 D86 H Ph D86 2568 A12 Ph H D41 D41 2618 A12 Ph D43 H D43 2668 A12 Ph D86 D86 H 2569 A12 H Ph D41 D41 2619 A12 H D43 Ph D43 2669 A12 H D86 D86 Ph 2570 A12 D42 D42 D42 H 2620 A12 Ph H D43 D43 2670 A12 Ph D86 H D86 2571 A12 D42 D42 H D42 2621 A12 H Ph D43 D43 2671 A12 H D86 Ph D86 2572 A12 D42 H D42 D42 2622 A12 D84 D84 D84 H 2672 A12 Ph H D86 D86 2573 A12 H D42 D42 D42 2623 A12 D84 D84 H D84 2673 A12 H Ph D86 D86 2574 A12 D42 D42 D42 Ph 2624 A12 D84 H D84 D84 2674 A12 D87 D87 D87 H 2575 A12 D42 D42 Ph D42 2625 A12 H D84 D84 D84 2675 A12 D87 D87 H D87 2576 A12 D42 Ph D42 D42 2626 A12 D84 D84 D84 Ph 2676 A12 D87 H D87 D87 2577 A12 Ph D42 D42 D42 2627 A12 D84 D84 Ph D84 2677 A12 H D87 D87 D87 2578 A12 D42 D42 H H 2628 A12 D84 Ph D84 D84 2678 A12 D87 D87 D87 Ph 2579 A12 D42 H D42 H 2629 A12 Ph D84 D84 D84 2679 A12 D87 D87 Ph D87 2580 A12 D42 H H D42 2630 A12 D84 D84 H H 2680 A12 D87 Ph D87 D87 2581 A12 H D42 D42 H 2631 A12 D84 H D84 H 2681 A12 Ph D87 D87 D87 2582 A12 H D42 H D42 2632 A12 D84 H H D84 2682 A12 D87 D87 H H 2583 A12 H H D42 D42 2633 A12 H D84 D84 H 2683 A12 D87 H D87 H 2584 A12 D42 D42 Ph H 2634 A12 H D84 H D84 2684 A12 D87 H H D87 2585 A12 D42 D42 H Ph 2635 A12 H H D84 D84 2685 A12 H D87 D87 H 2586 A12 D42 Ph D42 H 2636 A12 D84 D84 Ph H 2686 A12 H D87 H D87 2587 A12 D42 H D42 Ph 2637 A12 D84 D84 H Ph 2687 A12 H H D87 D87 2588 A12 D42 Ph H D42 2638 A12 D84 Ph D84 H 2688 A12 D87 D87 Ph H 2589 A12 D42 H Ph D42 2639 A12 D84 H D84 Ph 2689 A12 D87 D87 H Ph 2590 A12 Ph D42 D42 H 2640 A12 D84 Ph H D84 2690 A12 D87 Ph D87 H 2591 A12 H D42 D42 Ph 2641 A12 D84 H Ph D84 2691 A12 D87 H D87 Ph 2592 A12 Ph D42 H D42 2642 A12 Ph D84 D84 H 2692 A12 D87 Ph H D87 2593 A12 H D42 Ph D42 2643 A12 H D84 D84 Ph 2693 A12 D87 H Ph D87 2594 A12 Ph H D42 D42 2644 A12 Ph D84 H D84 2694 A12 Ph D87 D87 H 2595 A12 H Ph D42 D42 2645 A12 H D84 Ph D84 2695 A12 H D87 D87 Ph 2596 A12 D43 D43 D43 H 2646 A12 Ph H D84 D84 2696 A12 Ph D87 H D87 2597 A12 D43 D43 H D43 2647 A12 H Ph D84 D84 2697 A12 H D87 Ph D87 2598 A12 D43 H D43 D43 2648 A12 D86 D86 D86 H 2698 A12 Ph H D87 D87 2599 A12 H D43 D43 D43 2649 A12 D86 D86 H D86 2699 A12 H Ph D87 D87 2600 A12 D43 D43 D43 Ph 2650 A12 D86 H D86 D86 2700 A12 D88 D88 D88 H 2701 A12 D88 D88 H D88 2751 H A4 Ph D1 D1 2801 H A4 D3 Ph D3 2702 A12 D88 H D88 D88 2752 D2 A4 D2 D2 H 2802 Ph A4 H D3 D3 2703 A12 H D88 D88 D88 2753 D2 A4 D2 H D2 2803 H A4 Ph D3 D3 2704 A12 D88 D88 D88 Ph 2754 D2 A4 H D2 D2 2804 D4 A4 D4 D4 H 2705 A12 D88 D88 Ph D88 2755 H A4 D2 D2 D2 2805 D4 A4 D4 H D4 2706 A12 D88 Ph D88 D88 2756 D2 A4 D2 D2 Ph 2806 D4 A4 H D4 D4 2707 A12 Ph D88 D88 D88 2757 D2 A4 D2 Ph D2 2807 H A4 D4 D4 D4 2708 A12 D88 D88 H H 2758 D2 A4 Ph D2 D2 2808 D4 A4 D4 D4 Ph 2709 A12 D88 H D88 H 2759 Ph A4 D2 D2 D2 2809 D4 A4 D4 Ph D4 2710 A12 D88 H H D88 2760 D2 A4 D2 H H 2810 D4 A4 Ph D4 D4 2711 A12 H D88 D88 H 2761 D2 A4 H D2 H 2811 Ph A4 D4 D4 D4 2712 A12 H D88 H D88 2762 D2 A4 H H D2 2812 D4 A4 D4 H H 2713 A12 H H D88 D88 2763 H A4 D2 D2 H 2813 D4 A4 H D4 D4 2714 A12 D88 D88 Ph H 2764 H A4 D2 H D2 2814 D4 A4 H H D4 2715 A12 D88 D88 H Ph 2765 H A4 H D2 D2 2815 H A4 D4 D4 H 2716 A12 D88 Ph D88 H 2766 D2 A4 D2 Ph H 2816 H A4 D4 H D4 2717 A12 D88 H D88 Ph 2767 D2 A4 D2 H Ph 2817 H A4 H D4 D4 2718 A12 D88 Ph H D88 2768 D2 A4 Ph D2 H 2818 D4 A4 D4 Ph H 2719 A12 D88 H Ph D88 2769 D2 A4 H D2 Ph 2819 D4 A4 D4 H Ph 2720 A12 Ph D88 D88 H 2770 D2 A4 Ph H D2 2820 D4 A4 Ph D4 H 2721 A12 H D88 D88 Ph 2771 D2 A4 H Ph D2 2821 D4 A4 H D4 Ph 2722 A12 Ph D88 H D88 2772 Ph A4 D2 D2 H 2822 D4 A4 Ph H D4 2723 A12 H D88 Ph D88 2773 H A4 D2 D2 Ph 2823 D4 A4 H Ph D4 2724 A12 Ph H D88 D88 2774 Ph A4 D2 H D2 2824 Ph A4 D4 D4 H 2725 A12 H Ph D88 D88 2775 H A4 D2 Ph D2 2825 H A4 D4 D4 Ph 2726 D1 A4 D1 D1 H 2776 Ph A4 H D2 D2 2826 Ph A4 D4 H D4 2727 D1 A4 D1 H D1 2777 H A4 Ph D2 D2 2827 H A4 D4 Ph D4 2728 D1 A4 H D1 D1 2778 D3 A4 D3 D3 H 2828 Ph A4 H D4 D4 2729 H A4 D1 D1 D1 2779 D3 A4 D3 H D3 2829 H A4 Ph D4 D4 2730 D1 A4 D1 D1 Ph 2780 D3 A4 H D3 D3 2830 D40 A4 D40 D40 H 2731 D1 A4 D1 Ph D1 2781 H A4 D3 D3 D3 2831 D40 A4 D40 H D40 2732 D1 A4 Ph D1 D1 2782 D3 A4 D3 D3 Ph 2832 D40 A4 H D40 D40 2733 Ph A4 D1 D1 D1 2783 D3 A4 D3 Ph D3 2833 H A4 D40 D40 D40 2734 D1 A4 D1 H H 2784 D3 A4 Ph D3 D3 2834 D40 A4 D40 D40 Ph 2735 D1 A4 H D1 H 2785 Ph A4 D3 D3 D3 2835 D40 A4 D40 Ph D40 2736 D1 A4 H H D1 2786 D3 A4 D3 H H 2836 D40 A4 Ph D40 D40 2737 H A4 D1 D1 H 2787 D3 A4 H D3 H 2837 Ph A4 D40 D40 D40 2738 H A4 D1 H D1 2788 D3 A4 H H D3 2838 D40 A4 D40 H H 2739 H A4 H D1 D1 2789 H A4 D3 D3 H 2839 D40 A4 H D40 H 2740 D1 A4 D1 Ph H 2790 H A4 D3 H D3 2840 D40 A4 H H D40 2741 D1 A4 D1 H Ph 2791 H A4 H D3 D3 2841 H A4 D40 D40 H 2742 D1 A4 Ph D1 H 2792 D3 A4 D3 Ph H 2842 H A4 D40 H D40 2743 D1 A4 H D1 Ph 2793 D3 A4 D3 H Ph 2843 H A4 H D40 D40 2744 D1 A4 Ph H D1 2794 D3 A4 Ph D3 H 2844 D40 A4 D40 Ph H 2745 D1 A4 H Ph D1 2795 D3 A4 H D3 Ph 2845 D40 A4 D40 H Ph 2746 Ph A4 D1 D1 H 2796 D3 A4 Ph H D3 2846 D40 A4 Ph D40 H 2747 H A4 D1 D1 Ph 2797 D3 A4 H Ph D3 2847 D40 A4 H D40 Ph 2748 Ph A4 D1 H D1 2798 Ph A4 D3 D3 H 2846 D40 A4 Ph H D40 2749 H A4 D1 Ph D1 2799 H A4 D3 D3 Ph 2849 D40 A4 H Ph D40 2750 Ph A4 H D1 D1 2800 Ph A4 D3 H D3 2850 Ph A4 D40 D40 H 2851 H A4 D40 D40 Ph 2901 D42 A4 H Ph D42 2951 D84 A4 H D84 Ph 2852 Ph A4 D40 H D40 2902 Ph A4 D42 D42 H 2952 D84 A4 Ph H D84 2853 H A4 D40 Ph D40 2903 H A4 D42 D42 Ph 2953 D84 A4 H Ph D84 2854 Ph A4 H D40 D40 2904 Ph A4 D42 H D42 2954 Ph A4 D84 D84 H 2855 H A4 Ph D40 D40 2905 H A4 D42 Ph D42 2955 H A4 D84 D84 Ph 2856 A4 D86 D86 H 2906 Ph A4 H D42 D42 2956 Ph A4 D84 H D84 2857 D86 A4 D86 H D86 2907 H A4 Ph D42 D42 2957 H A4 D84 Ph D84 2858 D86 A4 H D86 D86 2908 D43 A4 D43 D43 H 2958 Ph A4 H D84 D84 2859 H A4 D88 D86 D86 2909 D43 A4 D43 H D43 2959 H A4 Ph D84 D84 2860 D86 A4 D86 D86 Ph 2910 D43 A4 H D43 D43 2960 D86 A4 D86 D86 H 2861 D86 A4 D86 Ph D86 2911 H A4 D43 D43 D43 2961 D86 A4 D86 H D86 2862 D86 A4 Ph D86 D86 2912 D43 A4 D43 D43 Ph 2962 D86 A4 H D86 D86 2863 Ph A4 D86 D86 D86 2913 D43 A4 D43 Ph D43 2963 H A4 D86 D86 D86 2864 D86 A4 D86 H H 2914 D43 A4 Ph D43 D43 2964 D86 A4 D86 D86 Ph 2865 D86 A4 H D86 H 2915 Ph A4 D43 D43 D43 2965 D86 A4 D86 Ph D86 2866 D86 A4 H H D86 2916 D43 A4 D43 H H 2966 D86 A4 Ph D86 D86 2867 H A4 D86 D86 H 2917 D43 A4 H D43 H 2967 Ph A4 D86 D86 D86 2868 H A4 D86 H D86 2918 D43 A4 H H D43 2968 D86 A4 D86 H H 2869 H A4 H D86 D86 2919 H A4 D43 D43 H 2969 D86 A4 H D86 H 2870 D86 A4 D86 Ph H 2920 H A4 D43 H D43 2970 D86 A4 H H D86 2871 D86 A4 D86 H Ph 2921 H A4 H D43 D43 2971 H A4 D86 D86 H 2872 D86 A4 Ph D86 H 2922 D43 A4 D43 Ph H 2972 H A4 D86 H D86 2873 D86 A4 H D86 Ph 2923 D43 A4 D43 H Ph 2973 H A4 H D86 D86 2874 D86 A4 Ph H D86 2924 D43 A4 Ph D43 H 2974 D86 A4 D86 Ph H 2875 D86 A4 H Ph D86 2925 D43 A4 H D43 Ph 2975 D86 A4 D86 H Ph 2876 Ph A4 D86 D86 H 2926 D43 A4 Ph H D43 2976 D86 A4 Ph D86 H 2877 H A4 D86 D86 Ph 2927 D43 A4 H Ph D43 2977 D86 A4 H D86 Ph 2878 Ph A4 D86 H D86 2928 Ph A4 D43 D43 H 2978 D86 A4 Ph H D86 2879 H A4 D86 Ph D86 2929 H A4 D43 D43 Ph 2979 D86 A4 H Ph D86 2880 Ph A4 H D86 D86 2930 Ph A4 D43 H D43 2980 Ph A4 D86 D86 H 2881 H A4 Ph D86 D86 2931 H A4 D43 Ph D43 2981 H A4 D86 D86 Ph 2882 D42 A4 D42 D42 H 2932 Ph A4 H D43 D43 2982 Ph A4 D86 H D86 2883 D42 A4 D42 H D42 2933 H A4 Ph D43 D43 2983 H A4 D86 Ph D86 2884 D42 A4 H D42 D42 2934 D84 A4 D84 D84 H 2984 Ph A4 H D86 D86 2885 H A4 D42 D42 D42 2935 D84 A4 D84 H D84 2985 H A4 Ph D86 D86 2886 D42 A4 D42 D42 Ph 2936 D84 A4 H D84 D84 2986 D87 A4 D87 D87 H 2887 D42 A4 D42 Ph D42 2937 H A4 D84 D84 D84 2987 D87 A4 D87 H D87 2888 D42 A4 Ph D42 D42 2938 D84 A4 D84 D84 Ph 2988 D87 A4 H D87 D87 2889 Ph A4 D42 D42 D42 2939 D84 A4 D84 Ph D84 2989 H A4 D87 D87 D87 2890 D42 A4 D42 H H 2940 D84 A4 Ph D84 D84 2990 D87 A4 D87 D87 Ph 2891 D42 A4 H D42 H 2941 Ph A4 D84 D84 D84 2991 D87 A4 D87 Ph D87 2892 D42 A4 H H D42 2942 D84 A4 D84 H H 2992 D87 A4 Ph D87 D87 2893 H A4 D42 D42 H 2943 D84 A4 H D84 H 2993 Ph A4 D87 D87 D87 2894 H A4 D42 H D42 2944 D84 A4 H H D84 2994 D87 A4 D87 H H 2895 H A4 H D42 D42 2945 H A4 D84 D84 H 2995 D87 A4 H D87 H 2896 D42 A4 D42 Ph H 2946 H A4 D84 H D84 2996 D87 A4 H H D87 2897 D42 A4 D42 H Ph 2947 H A4 H D84 D84 2997 H A4 D87 D87 H 2898 D42 A4 Ph D42 H 2948 D84 A4 D84 Ph H 2998 H A4 D87 H D87 2899 D42 A4 H D42 Ph 2949 D84 A4 D84 H Ph 2999 H A4 H D87 D87 2900 D42 A4 Ph H D42 2950 D84 A4 Ph D84 H 3000 D87 A4 D87 Ph H 3001 D87 A4 D87 H Ph 3051 H A12 H D1 D2 3101 H A12 D3 D3 H 3002 D87 A4 Ph D87 H 3052 D1 A12 D1 Ph H 3102 H A12 D3 H D3 3003 D87 A4 H D87 Ph 3053 D1 A12 D1 H Ph 3103 H A12 H D3 D3 3004 D87 A4 Ph H D87 3054 D1 A12 Ph D1 H 3104 D3 A12 D3 Ph H 3005 D87 A4 H Ph D87 3055 D1 A12 H D1 Ph 3105 D3 A12 D3 H Ph 3006 Ph A4 D87 D87 H 3056 D1 A12 Ph H D1 3106 D3 A12 Ph D3 H 3007 H A4 D87 D87 Ph 3057 D1 A12 H Ph D1 3107 D3 A12 H D3 Ph 3008 Ph A4 D87 H D87 3058 Ph A12 D1 D1 H 3108 D3 A12 Ph H D3 3009 H A4 D87 Ph D87 3059 H A12 D1 D1 Ph 3109 D3 A12 H Ph D3 3010 Ph A4 H D87 D87 3060 Ph A12 D1 H D1 3110 Ph A12 D3 D3 H 3011 H A4 Ph D87 D87 3061 H A12 D1 Ph D1 3111 H A12 D3 D3 Ph 3012 D88 A4 D88 D88 H 3062 Ph A12 H D1 D1 3112 Ph A12 D3 H D3 3013 D88 A4 D88 H D88 3063 H A12 Ph D1 D1 3113 H A12 D3 Ph D3 3014 D88 A4 H D88 D88 3064 D2 A12 D2 D2 H 3114 Ph A12 H D3 D3 3015 H A4 D88 D88 D88 3065 D2 A12 D2 H D2 3115 H A12 Ph D3 D3 3016 D88 A4 D88 D88 Ph 3066 D2 A12 H D2 D2 3116 D4 A12 D4 D4 H 3017 D88 A4 D88 Ph D88 3067 H A12 D2 D2 D2 3117 D4 A12 D4 H D4 3018 D88 A4 Ph D88 D88 3068 D2 A12 D2 D2 Ph 3118 D4 A12 H D4 D4 3019 Ph A4 D88 D88 D88 3069 D2 A12 D2 Ph D2 3119 H A12 D4 D4 D4 3020 D88 A4 D88 H H 3070 D2 A12 Ph D2 D2 3120 D4 A12 D4 D4 Ph 3021 D88 A4 H D88 H 3071 Ph A12 D2 D2 D2 3121 D4 A12 D4 Ph D4 3022 D88 A4 H H D88 3072 D2 A12 D2 H H 3122 D4 A12 Ph D4 D4 3023 H A4 D88 D88 H 3073 D2 A12 H D2 H 3123 Ph A12 D4 D4 D4 3024 H A4 D88 H D88 3074 D2 A12 H H D2 3124 D4 A12 D4 H H 3025 H A4 H D88 D88 3075 H A12 D2 D2 H 3125 D4 A12 H D4 H 3026 D88 A4 D88 Ph H 3076 H A12 D2 H D2 3126 D4 A12 H H D4 3027 D88 A4 D88 H Ph 3077 H A12 H D2 D2 3127 H A12 D4 D4 H 3028 D88 A4 Ph D88 H 3078 D2 A12 D2 Ph H 3128 H A12 D4 H D4 3029 D88 A4 H D88 Ph 3079 D2 A12 D2 H Ph 3129 H A12 H D4 D4 3030 D88 A4 Ph H D88 3080 D2 A12 Ph D2 H 3130 D4 A12 D4 Ph H 3031 D88 A4 H Ph D88 3081 D2 A12 H D2 Ph 3131 D4 A12 D4 H Ph 3032 Ph A4 D88 D88 H 3082 D2 A12 Ph H D2 3132 D4 A12 Ph D4 H 3033 H A4 D88 D88 Ph 3083 D2 A12 H Ph D2 3133 D4 A12 H D4 Ph 3034 Ph A4 D88 H D88 3084 Ph A12 D2 D2 H 3134 D4 A12 Ph H D4 3035 H A4 D88 Ph D88 3085 H A12 D2 D2 Ph 3135 D4 A12 H Ph D4 3036 Ph A4 H D88 D88 3086 Ph A12 D2 H D2 3136 Ph A12 D4 D4 H 3037 H A4 Ph D88 D88 3087 H A12 D2 Ph D2 3137 H A12 D4 D4 Ph 3038 D1 A12 D1 D1 H 3088 Ph A12 H D2 D2 3138 Ph A12 D4 H D4 3039 D1 A12 D1 H D1 3089 H A12 Ph D2 D2 3139 H A12 D4 Ph D4 3040 D1 A12 H D1 D1 3090 D3 A12 D3 D3 H 3140 Ph A12 H D4 D4 3041 H A12 D1 D1 D1 3091 D3 A12 D3 H D3 3141 H A12 Ph D4 D4 3042 D1 A12 D1 D1 Ph 3092 D3 A12 H D3 D3 3142 D40 A12 D40 D40 H 3043 D1 A12 D1 Ph D1 3093 H A12 D3 D3 D3 3143 D40 A12 D40 H D40 3044 D1 A12 Ph D1 D1 3094 D3 A12 D3 D3 Ph 3144 D40 A12 H D40 D40 3045 Ph A12 D1 D1 D1 3095 D3 A12 D3 Ph D3 3145 H A12 D40 D40 D40 3046 D1 A12 D1 H H 3096 D3 A12 Ph D3 D3 3146 D40 A12 D40 D40 Ph 3047 D1 A12 H D1 H 3097 Ph A12 D3 D3 D3 3147 D40 A12 D40 Ph D40 3048 D1 A12 H H D1 3098 D3 A12 D3 H H 3148 D40 A12 Ph D40 D40 3049 H A12 D1 D1 H 3099 D3 A12 H D3 H 3149 Ph A12 D40 D40 D40 3050 H A12 D1 H D1 3100 D3 A12 H H D3 3150 D40 A12 D40 H H 3151 D40 A12 H D40 H 3201 Ph A12 D42 D42 D42 3251 D84 A12 D84 Ph D84 3152 D40 A12 H H D40 3202 D42 A12 D42 H H 3252 D84 A12 Ph D84 D84 3153 H A12 D40 D40 H 3203 D42 A12 H D42 H 3253 Ph A12 D84 D84 D84 3154 H A12 D40 H D40 3204 D42 A12 H H D42 3254 D84 A12 D84 H H 3155 H A12 H D40 D40 3205 H A12 D42 D42 H 3255 D84 A12 H D84 H 3156 D40 A12 D40 Ph H 3206 H A12 D42 H D42 3256 D84 A12 H H D84 3157 D40 A12 D40 H Ph 3207 H A12 H D42 D42 3257 H A12 D84 D84 H 3158 D40 A12 Ph D40 H 3208 D42 A12 D42 Ph H 3258 H A12 D84 H D84 3159 D40 A12 H D40 Ph 3209 D42 A12 D42 H Ph 3259 H A12 H D84 D84 3160 D40 A12 Ph H D40 3210 D42 A12 Ph D42 H 3260 D84 A12 D84 Ph H 3161 D40 A12 H Ph D40 3211 D42 A12 H D42 Ph 3261 D84 A12 D84 H Ph 3162 Ph A12 D40 D40 H 3212 D42 A12 Ph H D42 3262 D84 A12 Ph D84 H 3163 H A12 D40 D40 Ph 3213 D42 A12 H Ph D42 3263 D84 A12 H D84 Ph 3164 Ph A12 D40 H D40 3214 Ph A12 D42 D42 H 3264 D84 A12 Ph H D84 3165 H A12 D40 Ph D40 3215 H A12 D42 D42 Ph 3265 D84 A12 H Ph D84 3166 Ph A12 H D40 D40 3216 Ph A12 D42 H D42 3266 Ph A12 D84 D84 H 3167 H A12 Ph D40 D40 3217 H A12 D42 Ph D42 3267 H A12 D84 D84 Ph 3168 D86 A12 D86 D86 H 3218 Ph A12 H D42 D42 3268 Ph A12 D84 H D84 3169 D86 A12 D86 H D86 3219 H A12 Ph D42 D42 3269 H A12 D84 Ph D84 3170 D86 A12 H D86 D86 3220 D43 A12 D43 D43 H 3270 Ph A12 H D84 D84 3171 H A12 D86 D86 D86 3221 D43 A12 D43 H D43 3271 H A12 Ph D84 D84 3172 D86 A12 D86 D86 Ph 3222 D43 A12 H D43 D43 3272 D86 A12 D86 D86 H 3173 D86 A12 D86 Ph D86 3223 H A12 D43 D43 D43 3273 D86 A12 D86 H D86 3174 D86 A12 Ph D86 D86 3224 D43 A12 D43 D43 Ph 3274 D86 A12 H D86 D86 3175 Ph A12 D86 D86 D86 3225 D43 A12 D43 Ph D43 3275 H A12 D86 D86 D86 3176 D86 A12 D86 H H 3226 D43 A12 Ph D43 D43 3276 D86 A12 D86 D86 Ph 3177 D86 A12 H D86 H 3227 Ph A12 D43 D43 D43 3277 D86 A12 D86 Ph D86 3178 D86 A12 H H D86 3228 D43 A12 D43 H H 3278 D86 A12 Ph D86 D86 3179 H A12 D86 D86 H 3229 D43 A12 H D43 H 3279 Ph A12 D86 D86 D86 3180 H A12 D86 H D86 3230 D43 A12 H H D43 3280 D86 A12 D86 H H 3181 H A12 H D86 D86 3231 H A12 D43 D43 H 3281 D86 A12 H D86 H 3182 D86 A12 D86 Ph H 3232 H A12 D43 H D43 3282 D86 A12 H H D86 3183 D86 A12 D86 H Ph 3233 H A12 H D43 D43 3283 H A12 D86 D86 H 3184 D86 A12 Ph D86 H 3234 D43 A12 D43 Ph H 3284 H A12 D86 H D86 3185 D86 A12 H D86 Ph 3235 D43 A12 D43 H Ph 3285 H A12 H D86 D86 3186 D86 A12 Ph H D86 3236 D43 A12 Ph D43 H 3286 D86 A12 D86 Ph H 3187 D86 A12 H Ph D86 3237 D43 A12 H D43 Ph 3287 D86 A12 D86 H Ph 3188 Ph A12 D86 D86 H 3238 D43 A12 Ph H D43 3288 D86 A12 Ph D86 H 3188 H A12 D86 D86 Ph 3239 D43 A12 H Ph D43 3289 D86 A12 H D86 Ph 3190 Ph A12 D86 H D86 3240 Ph A12 D43 D43 H 3290 D86 A12 Ph H D86 3191 H A12 D86 Ph D86 3241 H A12 D43 D43 Ph 3291 D86 A12 H Ph D86 3192 Ph A12 H D86 D86 3242 Ph A12 D43 H D43 3292 Ph A12 D86 D86 H 3193 H A12 Ph D86 D86 3243 H A12 D43 Ph D43 3293 H A12 D86 D86 Ph 3194 D42 A12 D42 D42 H 3244 Ph A12 H D43 D43 3294 Ph A12 D86 H D86 3195 D42 A12 D42 H D42 3245 H A12 Ph D43 D43 3295 H A12 D86 Ph D86 3196 D42 A12 H D42 1742 3246 D84 A12 D84 D84 H 3296 Ph A12 H D86 D86 3197 H A12 D42 D42 D42 3247 D84 A12 D84 H D84 3297 H A12 Ph D86 D86 3198 D42 A12 D42 D42 Ph 3248 D84 A12 H D84 D84 3298 D87 A12 D87 D87 H 3199 D42 A12 D42 Ph D42 3249 H A12 D84 D84 D84 3299 D87 A12 D87 H D87 3200 D42 A12 Ph D42 D42 3250 D84 A12 D84 D84 Ph 3300 D87 A12 H D87 D87 3301 H A12 D87 D87 D87 3351 A13 D86 H D86 D86 3401 A13 D86 D1 D1 Ph 3302 D87 A12 D87 D87 Ph 3352 A13 D86 D86 H D86 3402 A14 Ph D1 D1 D86 3303 D87 A12 D87 Ph D87 3353 A13 D86 D86 D86 H 3403 A14 D1 Ph D86 D1 3304 D87 A12 Ph D87 D87 3354 A14 H D86 D86 D86 3404 A14 D1 D86 Ph D1 3305 Ph A12 D87 D87 D87 3355 A14 D86 H D86 D86 3405 A14 D86 D1 D1 Ph 3306 D87 A12 D87 H H 3356 A14 D86 D86 H D86 3406 A13 H DD D86 3307 D87 A12 H D87 H 3357 A14 D86 D86 D86 H 3407 A13 D84 H D86 D84 3308 D87 A12 H H D87 3358 A13 Ph D86 D86 H 3408 A13 D84 D86 H D84 3309 H A12 D87 D87 H 3359 A13 D86 Ph D86 H 3409 A13 D86 D84 D84 H 3310 H A12 D87 H D87 3360 A13 D86 D86 Ph H 3410 A14 H D84 D84 D86 3311 H A12 H D87 D87 3361 A13 Ph D86 H D86 3411 A14 D84 H D86 D84 3312 DR7 A12 D87 Ph H 3362 A13 D86 Ph H D86 3412 A14 D84 D86 H D84 3313 D87 A12 D87 H Ph 3363 A13 D86 D86 H Ph 3413 A14 D86 D84 D84 H 3314 D87 A12 Ph D87 H 3364 A13 Ph H D86 D86 3414 A13 Ph D84 D84 D86 3315 D87 A12 H D87 Ph 3365 A13 D86 H Ph D86 3415 A13 D84 Ph D86 D84 3316 D87 A12 Ph H D87 3366 A13 D86 H D86 Ph 3416 A13 D84 D86 Ph D84 3317 D87 A12 H Ph D87 3367 A13 H Ph D86 D86 3417 A13 D86 D84 D84 Ph 3318 Ph A12 D87 D87 H 3368 A13 H D86 Ph D86 3418 A14 Ph D84 D84 D86 3319 H A12 D87 D87 Ph 3369 A13 H D86 D86 Ph 3419 A14 D84 Ph D86 D84 3320 Ph A12 D87 H D87 3370 A14 Ph D86 D86 H 3420 A14 D84 D86 Ph D84 3321 H A12 D87 Ph D87 3371 A14 D86 Ph D86 H 3421 A14 D86 D84 D84 Ph 3322 Ph A12 H D87 D87 3372 A14 D86 D86 Ph H 3422 H A13 D86 D86 D86 3323 H A12 Ph D87 D87 3373 A14 Ph D86 H D86 3423 D86 A13 H D86 D86 3324 D88 A12 D88 D88 H 3374 A14 D86 Ph H D86 3424 D86 A13 D86 H D86 3325 D88 A12 D88 H D88 3375 A14 D86 D86 H Ph 3425 D86 A13 D86 D86 H 3326 D88 A12 H D88 D88 3376 A14 Ph H D86 D86 3426 H A14 D86 D86 D86 3327 H A12 D88 D88 D88 3377 A14 D86 H Ph D86 3427 D86 A14 H D86 D86 3328 D88 A12 D88 D88 Ph 3378 A14 D86 H D86 Ph 3428 D86 A14 D86 H D86 3329 D88 A12 D88 Ph D88 3379 A14 H Ph D86 D86 3429 D86 A14 D86 D86 H 3330 D88 A12 Ph D88 D88 3380 A14 H D86 Ph D86 3430 Ph A13 D86 D86 H 3331 Ph A12 D88 D88 D88 3381 A14 H D86 D86 Ph 3431 D86 A13 Ph D86 H 3332 D88 A12 D88 H H 3382 A13 Ph D86 D86 D86 3432 D86 A13 D86 Ph H 3333 D88 A12 H D88 H 3383 A13 D86 Ph D86 D86 3433 Ph A13 D86 H D86 3334 D88 A12 H H D88 3384 A13 D86 D86 Ph D86 3434 D86 A13 Ph H D86 3335 H A12 D88 D88 H 3385 A13 D86 D86 D86 Ph 3435 D86 A13 D86 H Ph 3336 H A12 D88 H D88 3386 A14 Ph D86 D86 D86 3436 Ph A13 H D86 D86 3337 H A12 H D88 D88 3387 A14 D86 Ph D86 D86 3437 D86 A13 H Ph D86 3338 D88 A12 D88 Ph H 3388 A14 D86 D86 Ph D86 3438 D86 A13 H D86 Ph 3339 D88 A12 D88 H Ph 3389 A14 D86 D86 D86 Ph 3439 H A13 Ph D86 D86 3340 D88 A12 Ph D88 H 3390 A13 H D1 D1 D86 3440 H A13 D86 Ph D86 3341 D88 412 H D88 Ph 3391 A13 D1 H D86 D1 3441 H A13 D86 D86 Ph 3342 D88 A12 Ph H D88 3392 A13 D1 D86 H D1 3442 Ph A14 D86 D86 H 3343 D88 A12 H Ph D88 3393 A13 D86 D1 D1 H 3443 D86 A14 Ph D86 H 3344 Ph A12 D88 D88 H 3394 A14 H D1 D1 D86 3444 D86 A14 D86 Ph H 3345 H A12 D88 D88 Ph 3395 A14 D1 H D86 D1 3445 Ph A14 D86 H D86 3346 Ph A12 D88 H D88 3396 A14 D1 D86 H D1 3446 D86 A14 Ph H D86 3347 H A12 D88 Ph D88 3397 A14 D86 D1 D1 H 3447 D86 A14 D86 H Ph 3348 Ph A12 H D88 D88 3398 A13 Ph D1 D1 D86 3448 Ph A14 H D86 D86 3349 H A12 Ph D88 D88 3399 A13 D1 Ph D86 D1 3449 D86 A14 H Ph D86 3350 A13 H D86 D86 D86 3400 A13 D1 D86 Ph D1 3450 D86 A14 H D86 Ph 3451 H A14 Ph D88 D86 3501 A1 D57 D57 D57 Ph 3551 A1 D1 D64 D64 Ph 3452 H A14 D86 Ph D86 3502 A1 D60 D60 D60 Ph 3552 A1 D1 D65 D65 Ph 3453 H A14 D86 D86 Ph 3503 A1 D64 D64 D64 Ph 3553 A1 D1 D76 D76 Ph 3454 Ph A13 D86 D86 D86 3504 A1 D65 D65 D65 Ph 3554 A1 D56 D1 D56 Ph 3455 D86 A13 Ph D86 D86 3505 A1 D76 D76 D76 Ph 3555 A1 D57 D1 D57 Ph 3456 D86 A13 D86 Ph D86 3506 A20 D56 D56 D56 H 3556 A1 D60 D1 D60 Ph 3457 D86 A13 D86 D88 Ph 3507 A20 D57 D57 D57 H 3557 A1 D64 D1 D64 Ph 3458 Ph A14 D86 D86 D86 3508 A20 D60 D60 D60 H 3558 A1 D65 D1 D65 Ph 3459 D86 A14 Ph D86 D86 3509 A20 D64 D64 D64 H 3559 A1 D76 D1 D76 Ph 3460 D86 A14 D86 Ph D86 3510 A20 D65 D65 DB5 H 3560 A1 D56 D56 D1 Ph 3461 D86 A14 D86 D86 Ph 3511 A20 D78 D76 D76 H 3561 A1 D57 D57 D1 Ph 3462 H A13 D1 D1 D86 3512 A20 D56 D56 D56 Ph 3562 A1 D60 D60 D1 Ph 3463 D1 A13 H D86 D1 3513 A20 D57 D57 D57 Ph 3563 A1 D64 D64 D1 Ph 3464 D1 A13 D86 H D1 3514 A20 D60 D60 D60 Ph 3564 A1 D65 D65 D1 Ph 3465 D86 A13 D1 D1 H 3515 A20 D64 D64 D64 Ph 3565 A1 D76 D76 D1 Ph 3466 H A14 D1 D1 D86 3516 A20 D65 D65 D65 Ph 3566 A20 D1 D56 D56 Ph 3467 D1 A14 H D86 D1 3517 A20 D78 D76 D76 Ph 3567 A20 D1 D57 D57 Ph 3468 D1 A14 D86 H D1 3518 A21 D56 D56 D56 H 3568 A20 D1 D60 D60 Ph 3469 D86 A14 D1 D1 H 3519 A21 D57 D57 D57 H 3569 A20 D1 D64 D64 Ph 3470 Ph A13 D1 D1 D86 3520 A21 D60 D60 D60 H 3570 A20 D1 D65 D65 Ph 3471 D1 A13 Ph D86 D1 3521 A21 D64 D64 D64 H 3571 A20 D1 D76 D76 Ph 3472 D1 A13 D86 Ph D1 3522 A21 D65 D65 D65 H 3572 A20 D56 D1 D56 Ph 3473 D86 A13 D1 D1 Ph 3523 A21 D76 D76 D76 H 3573 A20 D57 D1 D57 Ph 3474 Ph A14 D1 D1 D86 3524 A21 D58 D56 D56 Ph 3574 A20 D60 D1 D60 Ph 3475 D1 A14 Ph D86 D1 3525 A21 D57 D57 D57 Ph 3575 A20 D64 D1 D64 Ph 3476 D1 A14 D86 Ph D1 3526 A21 D60 D60 D60 Ph 3576 A20 D65 D1 D65 Ph 3477 D86 A14 D1 D1 Ph 3527 A21 D64 D64 D64 Ph 3577 A20 D76 D1 D76 Ph 3478 H A13 D84 D84 D86 3528 A21 D65 D65 D65 Ph 3578 A20 D56 D56 D1 Ph 3479 D84 A13 H D86 D84 3529 A21 D76 D76 D76 Ph 3579 A20 D57 D57 D1 Ph 3480 D84 A13 D86 H D84 3530 A1 D1 D56 D56 Ph 3580 A20 D60 D60 D1 Ph 3481 D86 A13 D84 D84 H 3531 A1 D1 D57 D57 Ph 3581 A20 D64 D64 D1 Ph 3482 H A14 D84 D84 D86 3532 A1 D1 D60 D60 Ph 3582 A20 D65 D65 D1 Ph 3483 D84 A14 H D86 D84 3533 A1 D1 D64 D64 Ph 3583 A20 D76 D76 D1 Ph 3484 D84 A14 D86 H D84 3534 A1 D1 D65 D65 Ph 3584 A20 D1 D56 D56 Ph 3485 D86 A14 D84 D84 H 3535 A1 D1 D76 D76 Ph 3585 A20 D1 D57 D57 Ph 3486 Ph A13 D84 D84 D86 3536 A1 D56 D1 D56 Ph 3586 A20 D1 D60 D60 Ph 3487 D84 A13 Ph D86 D84 3537 A1 D57 D1 D57 Ph 3587 A20 D1 D64 D64 Ph 3488 D84 A13 D86 Ph D84 3538 A1 D60 D1 D60 Ph 3588 A20 D1 D65 D65 Ph 3489 D86 A13 D84 D84 Ph 3539 A1 D64 D1 D64 Ph 3589 A20 D1 D76 D76 Ph 3490 Ph A14 D84 D84 D86 3540 A1 D65 D1 D65 Ph 3590 A20 D56 D1 D56 Ph 3491 D84 A14 Ph D88 D84 3541 A1 D76 D1 D76 Ph 3591 A20 D57 D1 D57 Ph 3492 D84 A14 D86 Ph D84 3542 A1 D56 D56 D1 Ph 3592 A20 D60 D1 D60 Ph 3493 D86 A14 D84 D84 Ph 3543 A1 D57 D57 D1 Ph 3593 A20 D64 D1 D64 Ph 3494 A1 D56 D56 D56 H 3544 A1 D60 D60 D1 Ph 3594 A20 D65 D1 D65 Ph 3495 A1 D57 D57 D57 H 3545 A1 D64 D64 D1 Ph 3595 A20 D76 D1 D76 Ph 3496 A1 D60 D60 D60 H 3546 A1 D65 D65 D1 Ph 3596 A20 D56 D56 D1 Ph 3497 A1 D64 D64 D64 H 3547 A1 D76 D76 D1 Ph 3597 A20 D57 D57 D1 Ph 3498 A1 D65 D65 D65 H 3548 A1 D1 D56 D56 Ph 3598 A20 D60 D60 D1 Ph 3499 A1 D76 D76 D76 H 3549 A1 D1 D57 D57 Ph 3599 A20 D64 D64 D1 Ph 3500 A1 D56 D56 D56 Ph 3550 A1 D1 D60 D60 Ph 3600 A20 D65 D65 D1 Ph 3601 A20 D76 D76 D1 Ph 3651 A21 D57 H D57 H 3701 A1 D64 H D1 H 3602 A1 D56 H D56 H 3652 A21 D60 H D60 H 3702 A1 D65 H D1 H 3603 A1 D57 H D57 H 3653 A21 D64 H D64 H 3703 A1 D76 H D1 H 3604 A1 D60 H D60 H 3654 A21 D65 H D65 H 3704 A1 D56 Ph D1 H 3605 A1 D64 H D64 H 3655 A21 D76 H D76 H 3705 A1 D57 Ph D1 H 3606 A1 D65 H D65 H 3656 A21 D50 Ph D56 H 3706 A1 D60 Ph D1 H 3607 A1 D76 H D76 H 3657 A21 D57 Ph D57 H 3707 A1 D64 Ph D1 H 3608 A1 D56 Ph D56 H 3658 A21 D60 Ph D60 H 3708 A1 D65 Ph D1 H 3609 A1 D57 Ph D57 H 3659 A21 D84 Ph D64 H 3709 A1 D76 Ph D1 H 3610 A1 D60 Ph D60 H 3660 A21 D65 Ph D65 H 3710 A1 D56 H D1 Ph 3611 A1 D64 Ph D64 H 3661 A21 D76 Ph D76 H 3711 A1 D57 H D1 Ph 3612 A1 D65 Ph D65 H 3662 A21 D50 H D56 Ph 3712 A1 D60 H D1 Ph 3613 A1 D76 Ph D76 H 3663 A21 D57 H D57 Ph 3713 A1 D64 H D1 Ph 3614 A1 D56 H D56 Ph 3664 A21 D60 H D60 Ph 3714 A1 D65 H D1 Ph 3616 A1 D57 H D57 Ph 3665 A21 D64 H D64 Ph 3715 A1 D76 H D1 Ph 3616 A1 D60 H D60 Ph 3666 A21 D55 H D65 Ph 3716 A1 D56 Ph D1 Ph 3617 A1 D64 H D64 Ph 3667 A21 D76 H D76 Ph 3717 A1 D57 Ph D1 Ph 3618 A1 D65 H D65 Ph 3668 A21 D56 Ph D56 Ph 3718 A1 D60 Ph D1 Ph 3619 A1 D76 H D76 Ph 3669 A21 D57 Ph D57 Ph 3719 A1 D64 Ph D1 Ph 3620 A1 D56 Ph D56 Ph 3670 A21 D60 Ph D60 Ph 3720 A1 D65 Ph D1 Ph 3621 A1 D57 Ph D57 Ph 3671 A21 D64 Ph D64 Ph 3721 A1 D76 Ph D1 Ph 3622 A1 D60 Ph D60 Ph 3672 A21 D65 Ph D65 Ph 3722 A20 D1 H D56 H 3623 A1 D64 Ph D64 Ph 3673 A21 D76 Ph D76 Ph 3723 A20 D1 H D57 H 3624 A1 D65 Ph D65 Ph 3674 A1 D1 H D56 H 3724 A20 D1 H D60 H 3625 A1 D76 Ph D76 Ph 3575 A1 D1 H D57 H 3725 A20 D1 H D64 H 3626 A20 D56 H D56 H 3676 A1 D1 H D60 H 3726 A20 D1 H D65 H 3627 A20 D57 H D57 H 3677 A1 D1 H D64 H 3727 A20 D1 H D76 H 3628 A20 D60 H D60 H 3678 A1 D1 H D65 H 3728 A20 D1 Ph D56 H 3629 A20 D64 H D64 H 3679 A1 D1 H D76 H 3729 A20 D1 Ph D57 H 3630 A20 D65 H D65 H 3680 A1 D1 Ph D56 H 3730 A20 D1 Ph D60 H 3631 A20 D76 H D76 H 3681 A1 D1 Ph D57 H 3731 A20 D1 Ph D64 H 3632 A20 D56 Ph D56 H 3682 A1 D1 Ph D60 H 3732 A20 D1 Ph D65 H 3633 A20 D57 Ph D57 H 3683 A1 D1 Ph D64 H 3733 A20 D1 Ph D76 H 3634 A20 D60 Ph D60 H 3684 A1 D1 Ph D65 H 3734 A20 D1 H D56 Ph 3635 A20 D64 Ph D64 H 3685 A1 D1 Ph D76 H 3735 A20 D1 H D57 Ph 3636 A20 D65 Ph D65 H 3686 A1 D1 H D56 Ph 3736 A20 D1 H D60 Ph 3637 A20 D76 Ph D76 H 3687 A1 D1 H D57 Ph 3737 A20 D1 H D64 Ph 3638 A20 D56 H D56 Ph 3688 A1 D1 H D60 Ph 3738 A20 D1 H D65 Ph 3639 A20 D57 H D57 Ph 3689 A1 D1 H D64 Ph 3739 A20 D1 H D76 Ph 3640 A20 D60 H D60 Ph 3690 A1 D1 H D65 Ph 3740 A20 D1 Ph D56 Ph 3641 A20 D64 H D64 Ph 3691 A1 D1 H D76 Ph 3741 A20 D1 Ph D57 Ph 3642 A20 D65 H D65 Ph 3692 A1 D1 Ph D56 Ph 3742 A20 D1 Ph D60 Ph 3643 A20 D76 H D76 Ph 3693 A1 D1 Ph D57 Ph 3743 A20 D1 Ph D64 Ph 3644 A20 D56 Ph D56 Ph 3694 A1 D1 Ph D60 Ph 3744 A20 D1 Ph D65 Ph 3645 A20 D57 Ph D57 Ph 3695 A1 D1 Ph D64 Ph 3745 A20 D1 Ph D76 Ph 3646 A20 D60 Ph D60 Ph 3696 A1 D1 Ph D65 Ph 3746 A20 D56 H D1 H 3647 A20 D64 Ph D64 Ph 3697 A1 D1 Ph D76 Ph 3747 A20 D57 H D1 H 3648 A20 D65 Ph D65 Ph 3698 A1 D56 H D1 H 3748 A20 D60 H D1 H 3649 A20 D76 Ph D76 Ph 3699 A1 D57 H D1 H 3749 A20 D64 H D1 H 3650 A21 D56 H D56 H 3700 A1 D60 H D1 H 3750 A20 D65 H D1 H 3751 A20 D76 H D1 H 3801 A21 D57 Ph D1 H 3851 A20 D64 D64 Ph H 3752 A20 D56 Ph D1 H 3802 A21 D60 Ph D1 H 3852 A20 D65 D65 Ph H 3753 A20 D57 Ph D1 H 3803 A21 D64 Ph D1 H 3853 A20 D76 D76 Ph H 3754 A20 D60 Ph D1 H 3804 A21 D65 Ph D1 H 3854 A20 D56 D56 H Ph 3755 A20 D64 Ph D1 H 3805 A21 D76 Ph D1 H 3855 A20 D57 D57 H Ph 3756 A20 D65 Ph D1 H 3806 A21 D56 H D1 Ph 3856 A20 D60 D60 H Ph 3757 A20 D76 Ph D1 H 3807 A21 D57 H D1 Ph 3857 A20 D64 D64 H Ph 3758 A20 D56 H D1 Ph 3808 A21 D60 H D1 Ph 3858 A20 D65 D65 H Ph 3759 A20 D57 H D1 Ph 3809 A21 D64 H D1 Ph 3859 A20 D76 D76 H Ph 3760 A20 D60 H D1 Ph 3810 A21 D65 H D1 Ph 3860 A20 D56 D56 Ph Ph 3761 A20 D64 H D1 Ph 3811 421 D76 H D1 Ph 3861 420 D57 D57 Ph Ph 3762 A20 D65 H D1 Ph 3812 A21 D56 Ph D1 Ph 3862 A20 D60 D60 Ph Ph 3763 A20 D76 H D1 Ph 3813 A21 D57 Ph D1 Ph 3863 A20 D64 D64 Ph Ph 3764 A20 D56 Ph D1 Ph 3814 A21 D60 Ph D1 Ph 3864 A20 D65 D65 Ph Ph 3765 A20 D57 Ph D1 Ph 3815 A21 D64 Ph D1 Ph 3865 A20 D76 D76 Ph Ph 3766 A20 D60 Ph D1 Ph 3816 A21 D65 Ph D1 Ph 3866 AP1 D56 D56 H H 3767 A20 D64 Ph D1 Ph 3817 A21 D76 Ph D1 Ph 3867 A21 D57 D57 H H 3768 A20 D65 Ph D1 Ph 3818 A1 D56 D56 H H 3868 A21 D60 D60 H H 3769 A20 D76 Ph D1 Ph 3819 A1 D57 D57 H H 3869 A21 D64 D64 H H 3770 A21 D1 H D56 H 3820 A1 D60 D60 H H 3870 A21 D65 D65 H H 3771 A21 D1 H D57 H 3821 A1 D64 D64 H H 3871 A21 D76 D76 H H 3772 A21 D1 H D60 H 3822 A1 D65 D65 H H 3872 A21 D56 D56 Ph H 3773 A21 D1 H D64 H 3823 A1 D76 D76 H H 3873 A21 D57 D57 Ph H 3774 A21 D1 H D65 H 3824 A1 D56 D56 Ph H 3874 A21 D60 D60 Ph H 3775 A21 D1 H D76 H 3825 A1 D57 D57 Ph H 3875 A21 D64 D64 Ph H 3776 A21 D1 Ph D56 H 3826 A1 D60 D60 Ph H 3876 A21 D65 D65 Ph H 3777 A21 D1 Ph D57 H 3827 A1 D64 D64 Ph H 3877 A21 D76 D76 Ph H 3778 A21 D1 Ph D60 H 3828 A1 D65 D65 Ph H 3878 A21 D56 D56 H Ph 3779 A21 D1 Ph D64 H 3829 A1 D76 D76 Ph H 3879 A21 D57 D57 H Ph 3780 A21 D1 Ph D65 H 3830 A1 D56 D56 H Ph 3880 A21 D60 D60 H Ph 3781 A21 D1 Ph D76 H 3831 A1 D57 D57 H Ph 3881 A21 D64 D64 H Ph 3782 A21 D1 H D56 Ph 3832 A1 D60 D60 H Ph 3882 A21 D65 D65 H Ph 3783 A21 D1 H D57 Ph 3833 A1 D64 D64 H Ph 3883 A21 D76 D76 H Ph 3784 A21 D1 H D60 Ph 3834 A1 D65 D65 H Ph 3884 AP1 D56 D56 Ph Ph 3785 A21 D1 H D64 Ph 3835 A1 D76 D76 H Ph 3885 A21 D57 D57 Ph Ph 3786 A21 D1 H D65 Ph 3836 A1 D56 D56 Ph Ph 3886 A21 D60 D60 Ph Ph 3787 A21 D1 H D76 Ph 3837 A1 D57 D57 Ph Ph 3887 A21 D64 D64 Ph Ph 3788 A21 D1 Ph D56 Ph 3838 A1 D60 D60 Ph Ph 3888 A21 D65 D65 Ph Ph 3789 A21 D1 Ph D57 Ph 3839 A1 D64 D64 Ph Ph 3889 A21 D76 D76 Ph Ph 3790 A21 D1 Ph D60 Ph 3840 A1 D65 D65 Ph Ph 3890 A1 D1 D56 H H 3791 A21 D1 Ph D64 Ph 3841 A1 D76 D76 Ph Ph 3891 A1 D1 D57 H H 3792 A21 D1 Ph D65 Ph 3842 A20 D56 D56 H H 3892 A1 D1 D60 H H 3793 A21 D1 Ph D76 Ph 3843 A20 D57 D57 H H 3893 A1 D1 D64 H H 3794 A21 D56 H D1 H 3844 A20 D60 D60 H H 3894 A1 D1 D65 H H 3795 A21 D57 H D1 H 3845 A20 D64 D64 H H 3895 A1 D1 D76 H H 3796 A21 D60 H D1 H 3846 A20 D65 D65 H H 3896 A1 D1 D56 Ph H 3797 A21 D64 H D1 H 3847 A20 D76 D76 H H 3897 A1 D1 D57 Ph H 3798 A21 D65 H D1 H 3848 A20 D56 D56 Ph H 3898 A1 D1 D60 Ph H 3799 A21 D76 H D1 H 3849 A20 D57 D57 Ph H 3899 A1 D1 D64 Ph H 3800 A21 D56 Ph D1 H 3850 A20 D60 D60 Ph H 3900 A1 D1 D65 Ph H 3901 A1 D1 D76 Ph H 3951 A20 D56 D1 Ph H 4001 A1 D60 H H D60 3902 A1 D1 D56 H Ph 3952 A20 D57 D1 Ph H 4002 A1 D64 H H D64 3903 A1 D1 D57 H Ph 3953 A20 D60 D1 Ph H 4003 A1 D65 H H D65 3904 A1 D1 D60 H Ph 3954 A20 D64 D1 Ph H 4004 A1 D76 H H D76 3905 A1 D1 D64 H Ph 3955 A20 D65 D1 Ph H 4005 A1 D56 Ph H D56 3906 41 D1 D65 H Ph 3956 A20 D76 D1 Ph H 4006 A1 D57 Ph H D57 3907 A1 D1 D76 H Ph 3957 A20 D56 D1 H Ph 4007 A1 D60 Ph H D60 3908 A1 D1 D76 Ph Ph 3958 A20 D57 D1 H Ph 4008 A1 D64 Ph H D64 3909 A1 D56 D1 H H 3959 A20 D60 D1 H Ph 4009 A1 D65 Ph H D65 3910 A1 D57 D1 H H 3960 A20 D64 D1 H Ph 4010 A1 D76 Ph H D76 3911 A1 D60 D1 H H 3961 A20 D65 D1 H Ph 4011 A1 D56 H Ph D56 3912 A1 D64 D1 H H 3962 A20 D76 D1 H Ph 4012 A1 D57 H Ph D57 3913 A1 D65 D1 H H 3963 A21 D1 D56 H H 4013 A1 D60 H Ph D60 3914 A1 D76 D1 H H 3964 A21 D1 D57 H H 4014 A1 D64 H Ph D64 3915 A1 D56 D1 Ph H 3965 A21 D1 D60 H H 4015 A1 D65 H Ph D65 3916 A1 D57 D1 Ph H 3966 A21 D1 D64 H H 4016 A1 D76 H Ph D76 3917 A1 D60 D1 Ph H 3967 A21 D1 D65 H H 4017 A1 D56 Ph Ph D56 3918 A1 D64 D1 Ph H 3968 A21 D1 D76 H H 4018 A1 D57 Ph Ph D57 3919 A1 D65 D1 Ph H 3989 A21 D1 D56 Ph H 4019 A1 D60 Ph Ph D60 3920 A1 D76 D1 Ph H 3970 A21 D1 D57 Ph H 4020 A1 D64 Ph Ph D64 3921 A1 D56 D1 H Ph 3971 A21 D1 D60 Ph H 4021 A1 D65 Ph Ph D65 3922 A1 D57 D1 H Ph 3972 A21 D1 D64 Ph H 4022 A1 D76 Ph Ph D76 3923 A1 D60 D1 H Ph 3973 A21 D1 D65 Ph H 4023 A20 D56 H H D56 3924 A1 D64 D1 H Ph 3974 A21 D1 D76 Ph H 4024 A20 D57 H H D57 3925 41 D65 D1 H Ph 3975 AP1 D1 D56 H Ph 4025 A20 D60 H H D60 3926 A1 D76 D1 H Ph 3976 A21 D1 D57 H Ph 4026 A20 D64 H H D64 3927 A20 D1 D56 H H 3977 A21 D1 D60 H Ph 4027 A20 D65 H H D65 3928 A20 D1 D57 H H 3978 A21 D1 D64 H Ph 4028 A20 D76 H H D76 3929 A20 D1 D60 H H 3979 A21 D1 D65 H Ph 4029 A20 D56 Ph H D56 3930 A20 D1 D64 H H 3980 A21 D1 D76 H Ph 4030 A20 D57 Ph H D57 3931 A20 D1 D65 H H 3981 A21 D56 D1 H H 4031 A20 D60 Ph H D60 3932 A20 D1 D76 H H 3982 A21 D57 D1 H H 4032 A20 D64 Ph H D64 3933 A20 D1 D56 Ph H 3983 A21 D60 D1 H H 4033 A20 D65 Ph H D65 3934 420 D1 D57 Ph H 3934 421 D64 D1 H H 4034 420 D76 Ph H D76 3935 A20 D1 D60 Ph H 3985 A21 D65 D1 H H 4035 A20 D56 H Ph D56 3936 A20 D1 D64 Ph H 3986 A21 D76 D1 H H 4036 A20 D57 H Ph D57 3937 A20 D1 D65 Ph H 3987 A21 D56 D1 Ph H 4037 A20 D60 H Ph D60 3938 A20 D1 D76 Ph H 3988 A21 D57 D1 Ph H 4038 A20 D64 H Ph D64 3939 A20 D1 D56 H Ph 3989 A21 D60 D1 Ph H 4039 A20 D65 H Ph D65 3940 A20 D1 D57 H Ph 3990 A21 D64 D1 Ph H 4040 A20 D76 H Ph D76 3941 A20 D1 D60 H Ph 3991 A21 D65 D1 Ph H 4041 A20 D56 Ph Ph D56 3942 A20 D1 D64 H Ph 3992 A21 D76 D1 Ph H 4042 A20 D57 Ph Ph D57 3943 A20 D1 D65 H Ph 3993 A21 D56 D1 H Ph 4043 A20 D60 Ph Ph D60 3944 A20 D1 D7R H Ph 3994 AP1 D57 D1 H Ph 4044 A20 D64 Ph Ph D64 3945 A20 D56 D1 H H 3995 A21 D60 D1 H Ph 4045 A20 D65 Ph Ph D65 3946 A20 D57 D1 H H 3996 A21 D64 D1 H Ph 4046 A20 D76 Ph Ph D76 3947 A20 D60 D1 H H 3997 A21 D65 D1 H Ph 4047 A21 D56 H H D56 3948 A20 D64 D1 H H 3998 A21 D76 D1 H Ph 4048 A21 D57 H H D57 3949 A20 D65 D1 H H 3999 A1 D56 H H D56 4049 A21 D60 H H D60 3950 A20 D76 D1 H H 4000 A1 D57 H H D57 4050 A21 D64 H H D64 4051 A21 D65 H H D65 4101 A1 D56 H Ph D1 4151 A21 D1 Ph H D60 4052 A21 D76 H H D76 4102 A1 D57 H Ph D1 4152 A21 D1 Ph H D64 4053 A21 D56 Ph H D56 4103 A1 D60 H Ph D1 4153 A21 D1 Ph H D65 4054 A21 D57 Ph H D57 4104 A1 D64 H Ph D1 4154 A21 D1 Ph H D76 4055 A21 D60 Ph H D60 4105 A1 D65 H Ph D1 4155 A21 D1 H Ph D56 4056 A21 D64 Ph H D64 4106 A1 D76 H Ph D1 4156 A21 D1 H Ph D57 4057 A21 D65 Ph H D65 4107 A20 D1 H H D56 4157 A21 D1 H Ph D60 4058 A21 D76 Ph H D76 4108 A20 D1 H H D57 4158 A21 D1 H Ph D64 4059 A21 D56 H Ph D56 4109 A20 D1 H H D60 4159 A21 D1 H Ph D65 4060 A21 D57 H Ph D57 4110 A20 D1 H H D64 4160 A21 D1 H Ph D76 4061 A21 D60 H Ph D60 4111 A20 D1 H H D65 4161 A21 D56 H H D1 4062 A21 D64 H Ph D64 4112 A20 D1 H H D76 4162 A21 D57 H H D1 4063 A21 D65 H P1 D65 4113 A20 D1 Ph H D56 4163 A21 D60 H H D1 4064 A21 D76 H Ph D76 4114 A20 D1 Ph H D57 4164 A21 D64 H H D1 4065 A21 D56 Ph Ph D56 4115 A20 D1 Ph H D60 4165 A21 D65 H H D1 4066 A21 D57 Ph Ph D57 4116 A20 D1 Ph H D64 4166 A21 D76 H H D1 4067 A21 D60 Ph Ph D60 4117 A20 D1 Ph H D65 4167 A21 D56 Ph H D1 4068 A21 D64 Ph Ph D64 4118 A20 D1 Ph H D76 4168 A21 D57 Ph H D1 4069 A21 D65 Ph Ph D65 4119 A20 D1 H Ph D56 4169 A21 D60 Ph H D1 4070 A21 D76 Ph Ph D76 4120 A20 D1 H Ph D57 4170 A21 D64 Ph H D1 4071 A1 D1 H H D56 4121 A20 D1 H Ph D60 4171 A21 D65 Ph H D1 4072 A1 D1 H H D57 4122 A20 D1 H Ph D64 4172 A21 D76 Ph H D1 4073 A1 D1 H H D60 4123 A20 D1 H Ph D65 4173 A21 D56 H Ph D1 4074 A1 D1 H H D64 4124 A20 D1 H Ph D78 4174 A21 D57 H Ph D1 4075 A1 D1 H H D65 4125 A20 D56 H H D1 4175 A21 D60 H Ph D1 4076 A1 D1 H H D76 4126 A20 D57 H H D1 4176 A21 D64 H Ph D1 4077 A1 D1 Ph H D56 4127 A20 D60 H H D1 4177 A21 D65 H Ph D1 4078 A1 D1 Ph H D57 4128 A20 D64 H H D1 4178 A21 D76 H Ph D1 4079 A1 D1 Ph H D60 4129 A20 D65 H H D1 4179 A1 D56 D56 H D56 4080 A1 D1 Ph H D64 4130 A20 D76 H H D1 4180 A1 D57 D57 H D57 4081 A1 D1 Ph H D65 4131 A20 D56 Ph H D1 4181 A1 D60 D60 H D60 4082 A1 D1 Ph H D76 4132 A20 D57 Ph H D1 4182 A1 D64 D64 H D64 4083 A1 D1 H Ph D56 4133 A20 D60 Ph H D1 4183 A1 D65 D65 H D65 4084 A1 D1 H Ph D57 4134 A20 D64 Ph H D1 4184 A1 D76 D76 H D76 4085 A1 D1 H P1 D60 4135 A20 D65 Ph H D1 4185 A1 D56 D56 Ph D56 4086 A1 D1 H Ph D64 4136 A20 D76 Ph H D1 4186 A1 D57 D57 Ph D57 4087 A1 D1 H Ph D65 4137 A20 D56 H Ph D1 4187 A1 D60 D60 Ph D60 4088 A1 D1 H Ph D76 4138 A20 D57 H Ph D1 4188 A1 D64 D64 Ph D64 4089 A1 D56 H H D1 4139 A20 D60 H Ph D1 4189 A1 D65 D65 Ph D65 4090 A1 D57 H H D1 4140 A20 D64 H Ph D1 4190 A1 D76 D76 Ph D76 4091 A1 D60 H H D1 4141 A20 D65 H Ph D1 4191 A20 D56 D56 H D56 4092 A1 D64 H H D1 4142 A20 D76 H Ph D1 4192 A20 D57 D57 H D57 4093 A1 D65 H H D1 4143 A21 D1 H H D56 4193 A20 D60 D60 H D60 4094 A1 D76 H H D1 4144 A21 D1 H H D57 4194 A20 D64 D64 H D64 4095 A1 D56 Ph H D1 4145 A21 D1 H H D60 4195 A20 D65 D65 H D65 4096 A1 D57 Ph H D1 4146 A21 D1 H H D64 4196 A20 D76 D76 H D76 4097 A1 D60 Ph H D1 4147 A21 D1 H H D65 4197 A20 D56 D56 Ph D56 4098 A1 D64 Ph H D1 4148 A21 D1 H H D76 4198 A20 D57 D57 Ph D57 4099 A1 D65 Ph H D1 4149 A21 D1 Ph H D56 4199 A20 D60 D60 Ph D60 4100 A1 D76 Ph H D1 4150 A21 D1 Ph H D57 4200 A20 D64 D64 Ph D64 4201 A20 D65 D65 Ph D65 4251 A20 D1 D56 H D56 4301 A21 D60 D1 H D60 4202 A20 D76 D76 Ph D76 4252 A20 D1 D57 H D57 4302 A21 D64 D1 H D64 4203 A21 D56 D56 H D56 4253 A20 D1 D60 H D60 4303 A21 D65 D1 H D65 4204 A21 D57 D57 H D57 4254 A20 D1 D64 H D64 4304 A21 D76 D1 H D76 4205 A21 D60 D60 H D60 4255 A20 D1 D65 H D65 4305 A21 D56 D1 Ph D56 4206 A21 D64 D64 H D64 4256 A20 D1 D76 H D76 4306 A21 D57 D1 Ph D57 4207 A21 D65 D65 H D65 4257 A20 D1 D56 Ph D56 4307 A21 D60 D1 Ph D60 4208 A21 D76 D76 H D76 4258 A20 D1 D57 Ph D57 4308 A21 D64 D1 Ph D64 4209 A21 D56 D56 Ph D56 4259 A20 D1 D60 Ph D60 4309 A21 D65 D1 Ph D65 4210 A21 D57 D57 Ph D57 4260 A20 D1 D64 Ph D64 4310 A21 D76 D1 Ph D76 4211 A21 D60 D60 Ph D60 4261 A20 D1 D65 Ph D65 4311 A21 D56 D56 H D1 4212 A21 D64 D64 Ph D64 4262 A20 D1 D76 Ph D76 4312 A21 D57 D57 H D1 4213 A21 D65 D65 P1 D65 4263 A20 D56 D1 H D56 4313 A21 D60 D60 H D1 4214 A21 D76 D76 Ph D76 4264 A20 D57 D1 H D57 4314 A21 D64 D64 H D1 4215 A1 D1 D56 H D56 4265 A20 D60 D1 H D60 4315 A21 D65 D65 H D1 4216 A1 D1 D57 H D57 4266 A20 D64 D1 H D64 4316 A21 D76 D76 H D1 4217 A1 D1 D60 H D60 4267 A20 D65 D1 H D65 4317 A21 D56 D56 Ph D1 4218 A1 D1 D64 H D64 4268 A20 D76 D1 H D76 4318 A21 D57 D57 Ph D1 4219 A1 D1 D65 H D65 4269 A20 D56 D1 Ph D56 4319 A21 D60 D60 Ph D1 4220 A1 D1 D76 H D76 4270 A20 D57 D1 Ph D57 4320 A21 D64 D64 Ph D1 4221 A1 D1 D56 Ph D56 4271 A20 D60 D1 Ph D60 4321 A21 D65 D65 Ph D1 4222 A1 D1 D57 Ph D57 4272 A20 D64 D1 Ph D64 4322 A21 D76 D76 Ph D1 4223 A1 D1 D60 Ph D60 4273 A20 D65 D1 Ph D65 4323 A1 D56 H D56 D56 4224 A1 D1 D64 Ph D64 4274 A20 D76 D1 Ph D76 4324 A1 D57 H D57 D57 4225 A1 D1 D65 P1 D65 4275 A20 D56 D56 H D1 4325 A1 D60 H D60 D60 4226 A1 D1 D76 Ph D76 4276 A20 D57 D57 H D1 4326 A1 D64 H D64 D64 4227 A1 D56 D1 H D56 4277 A20 D60 D60 H D1 4327 A1 D65 H D65 D65 4228 A1 D57 D1 H D57 4278 A20 D64 D64 H D1 4328 A1 D76 H D76 D76 4229 A1 D60 D1 H D60 4279 A20 D65 D65 H D1 4329 A1 D56 Ph D56 D56 4230 A1 D64 D1 H D64 4280 A20 D76 D76 H D1 4330 A1 D57 Ph D57 D57 4231 A1 D65 D1 H D65 4281 A20 D56 D56 Ph D1 4331 A1 D60 Ph D60 D60 4232 A1 D76 D1 H D76 4282 A20 D57 D57 Ph D1 4332 A1 D64 Ph D64 D64 4233 A1 D56 D1 Ph D56 4283 A20 D60 D60 Ph D1 4333 A1 D65 Ph D65 D65 4234 A1 D57 D1 Ph D57 4284 A20 D64 D64 Ph D1 4334 A1 D76 Ph D76 D76 4235 A1 D60 D1 P1 D60 4285 A20 D65 D65 Ph D1 4335 A20 D56 H D56 D56 4236 A1 D64 D1 Ph D64 4286 A20 D76 D76 Ph D1 4336 A20 D57 H D57 D57 4237 A1 D65 D1 Ph D65 4287 A21 D1 D56 H D56 4337 A20 D60 H D60 D60 4238 1 D76 D1 Ph D76 4288 A21 D1 D57 H D57 4338 A20 D64 H D64 D64 4239 A1 D56 D56 H D1 4289 A21 D1 D60 H D60 4339 A20 D65 H D65 D65 4240 A1 D57 D57 H D1 4290 A21 D1 D64 H D64 4340 A20 D76 H D76 D76 4241 A1 D60 D60 H D1 4291 A21 D1 D65 H D65 4341 A20 D56 Ph D56 D56 4242 A1 D64 D64 H D1 4292 A21 D1 D76 H D76 4342 A20 D57 Ph D57 D57 4243 A1 D65 D65 H D1 4233 A21 D1 D56 Ph D56 4343 A20 D60 Ph D60 D60 4244 A1 D76 D76 H D1 4294 A21 D1 D57 Ph D57 4344 A20 D64 Ph D64 D64 4245 A1 D56 D56 Ph D1 4295 A21 D1 D60 Ph D60 4345 A20 D65 Ph D65 D65 4246 A1 D57 D57 Ph D1 4296 A21 D1 D64 Ph D64 4346 A20 D76 Ph D76 D76 4247 A1 D60 D60 P1 D1 4297 A21 D1 D65 Ph D65 4347 A21 D56 H D56 D56 4248 A1 D64 D64 Ph D1 4298 A21 D1 D76 Ph D76 4348 A21 D57 H D57 D57 4249 A1 D65 D65 P1 D1 4299 A21 D56 D1 H D56 4349 A21 D60 H D60 D60 4250 A1 D76 D76 Ph D1 4300 A21 D57 D1 H D57 4350 A21 D64 H D64 D64 4351 A21 D65 H D65 D65 4401 A20 D1 Ph D56 D56 4451 A21 D60 Ph D1 D60 4352 A21 D76 H D76 D76 4402 A20 D1 Ph D57 D57 4452 A21 D64 Ph D1 D64 4353 A21 D56 Ph D56 D56 4403 A20 D1 Ph D60 D60 4453 A21 D65 Ph D1 565 4354 A21 D57 Ph D57 D57 4404 A20 D1 Ph D64 D64 4454 A21 D76 Ph D1 D76 4355 A21 D60 Ph D60 D60 4405 A20 D1 Ph D65 D65 4455 A21 D56 H D56 D1 4358 A21 D64 Ph D64 D64 4406 A20 D1 Ph D76 D76 4456 A21 D57 H D57 D1 4357 A21 D65 Ph D65 D65 4407 A20 D56 H D1 D56 4457 A21 D60 H D60 D1 4358 A21 D76 Ph D76 D76 4408 A20 D57 H D1 D57 4458 A21 D64 H D64 D1 4359 A1 D1 H D56 D56 4409 A20 D60 H D1 D60 4459 A21 D65 H D65 D1 4360 A1 D1 H D57 D57 4410 A20 D64 H D1 D64 4460 A21 D76 H D76 D1 4361 A1 D1 H D60 D60 4411 A20 D65 H D1 D65 4461 A21 D56 Ph D56 D1 4362 A1 D1 H D64 D64 4412 A20 D76 H D1 D76 4462 A21 D57 Ph D57 D1 4363 A1 D1 H D65 D65 4413 A20 D56 Ph D1 D56 4463 A21 D60 Ph D60 D1 4364 A1 D1 H D76 D76 4414 A20 D57 Ph D1 D57 4464 A21 D64 Ph D64 D1 4365 A1 D1 Ph D56 D56 4415 A20 D60 Ph D1 D60 4465 A21 D65 Ph D65 D1 4366 A1 D1 Ph D57 D57 4416 A20 D64 Ph D1 D64 4466 A21 D76 Ph D76 D1 4367 A1 D1 Ph D60 D60 4417 A20 D65 Ph D1 D65 4467 D56 A1 H D56 D56 4368 A1 D1 Ph D64 D64 4418 A20 D76 Ph D1 D76 4468 D57 A1 H D57 D57 4369 A1 D1 Ph D65 D65 4419 A20 D56 H D56 D1 4469 D60 A1 H D60 D60 4370 A1 D1 Ph D76 D76 4420 A20 D57 H D57 D1 4470 D64 A1 H D64 D64 4371 A1 D56 H D1 D56 4421 A20 D60 H D60 D1 4471 D65 A1 H D65 D65 4372 A1 D57 H D1 D57 4422 A20 D64 H D64 D1 4472 D76 A1 H D76 D76 4373 A1 D60 H D1 D60 4423 A20 D65 H D65 D1 4473 D56 A1 Ph D56 D56 4374 A1 D64 H D1 D64 4424 A20 D76 H D76 D1 4474 D57 A1 Ph D57 D57 4375 A1 D65 H D1 D65 4425 A20 D56 Ph D56 D1 4475 D60 A1 Ph D60 D60 4376 A1 D76 H D1 D76 4426 A20 D57 Ph D57 D1 4476 D64 A1 Ph D64 D64 4377 A1 D56 Ph D1 D56 4427 A20 D60 Ph D60 D1 4477 D65 A1 Ph D65 D65 4378 A1 D57 Ph D1 D57 4428 A20 D64 Ph D64 D1 4478 D76 A1 Ph D76 576 4379 A1 D60 Ph D1 D60 4429 A20 D65 Ph D65 D1 4479 D56 A20 H D56 D56 4380 A1 D64 Ph D1 D64 4430 A20 D76 Ph D76 D1 4480 D57 A20 H D57 D57 4381 A1 D65 Ph D1 D65 4431 A21 D1 H D56 D56 4481 D60 A20 H D60 D60 4382 A1 D76 Ph D1 D76 4432 A21 D1 H D57 D57 4482 D64 A20 H D64 D64 4383 A1 D56 H D56 D1 4433 A21 D1 H D60 D60 4483 D65 A20 H D65 D65 4384 A1 D57 H D57 D1 4434 A21 D1 H D64 D64 4484 D76 A20 H D76 D76 4385 A1 D60 H D60 D1 4435 A21 D1 H D65 D65 4485 D56 A20 Ph D56 D56 4386 A1 D64 H D64 D1 4436 A21 D1 H D76 D76 4486 D57 A20 Ph D57 D57 4387 A1 D65 H D65 D1 4437 A21 D1 Ph D56 D56 4487 D60 A20 Ph D60 D60 4388 A1 D76 H D76 D1 4438 A21 D1 Ph D57 D57 4488 D64 A20 Ph D64 D64 4389 A1 D56 Ph D56 D1 4439 A21 D1 Ph D60 D60 4489 D65 A20 Ph D65 D65 4390 A1 D57 Ph D57 D1 4440 A21 D1 Ph D64 D64 4490 D76 A20 Ph D76 D76 4391 A1 D60 Ph D60 D1 4441 A21 D1 Ph D65 D65 4491 D56 A21 H D56 D56 4392 A1 D64 Ph D64 D1 4442 A21 D1 Ph D76 D76 4492 D57 A21 H D57 D57 4393 A1 D65 Ph D65 D1 4443 A21 D56 H D1 D56 4493 D60 A21 H D60 D60 4394 A1 D76 Ph D76 D1 4444 A21 D57 H D1 D57 4494 D64 A21 H D64 D64 4395 A20 D1 H D56 D56 4445 A21 D60 H D1 D60 4495 D65 A21 H D65 D65 4396 A20 D1 H D57 D57 4446 A21 D64 H D1 D64 4496 D76 A21 H D76 D76 4397 A20 D1 H D60 D60 4447 A21 D65 H D1 D65 4497 D56 A21 Ph D56 D56 4398 A20 D1 H D64 D64 4448 A21 D76 H D1 D76 4498 D57 A21 Ph D57 D57 4399 A20 D1 H D65 D65 4449 A21 D56 Ph D1 D56 4499 D60 A21 Ph D60 D60 4400 A20 D1 H D76 D76 4450 A21 D57 Ph D1 D57 4500 D64 A21 Ph D64 D64 4501 D65 A21 Ph D65 D65 4551 D56 A20 H D1 D56 4601 D60 A21 H D60 D1 4502 D76 A21 Ph D76 D76 4552 D57 A20 H D1 D57 4602 D54 A21 H D64 D1 4503 D1 A1 H D56 D56 4553 D60 A20 H D1 D60 4603 D65 A21 H D65 D1 4504 D1 A1 H D57 D57 4554 D64 A20 H D1 D64 4604 D76 A21 H D76 D1 4505 D1 A1 H D60 D60 4555 D65 A20 H D1 D65 4605 D50 A21 Ph D50 D1 4506 D1 A1 H D64 D64 4556 D76 A20 H D1 D76 4606 D57 A21 Ph D57 D1 4507 D1 A1 H D65 D65 4557 D56 A20 Ph D1 D56 4607 D60 A21 Ph D60 D1 4508 D1 A1 H D7S D76 4558 D57 A20 Ph D1 D57 4608 D64 AP1 Ph D64 D1 4509 D1 A1 Ph D56 D56 4559 D60 A20 Ph D1 D60 4609 D65 A21 Ph D65 D1 4510 D1 A1 Ph D57 D57 4560 D64 A20 Ph D1 D64 4610 D76 A21 Ph D76 D1 4511 D1 A1 Ph D60 D60 4561 D65 A20 Ph D1 D65 4611 D56 A1 H H D56 4512 D1 A1 Ph D64 D64 4562 D76 A20 Ph D1 D76 4612 D57 A1 H H D57 4513 D1 A1 Ph D65 D65 4563 D56 A20 H D56 D1 4613 D60 A1 H H D60 4514 D1 A1 Ph D76 D76 4564 D57 A20 H D57 D1 4614 D64 A1 H H D64 4515 D56 A1 H D1 D56 4565 D60 A20 H D60 D1 4615 D65 A1 H H D65 4518 D57 A1 H D1 D57 4566 D64 A20 H D64 D1 4616 D76 A1 H H D76 4517 D60 A1 H D1 D60 4567 D65 A20 H D65 D1 4617 D56 A1 Ph H D56 4518 D64 A1 H D1 D64 4568 D76 A20 H D76 D1 4618 D57 A1 Ph H D57 4519 D65 A1 H D1 D65 4569 D56 A20 Ph D58 D1 4619 D60 A1 Ph H D60 4520 D76 A1 H D1 D76 4570 D57 A20 Ph D57 D1 4620 D64 A1 Ph H D64 4521 D56 A1 Ph D1 D56 4571 D60 A20 Ph D60 D1 4621 D65 A1 Ph H D65 4522 D57 A1 Ph D1 D57 4572 D64 A20 Ph D04 D1 4622 D76 A1 Ph H D76 4523 D60 A1 Ph D1 D60 4573 D65 A20 Ph D65 D1 4623 D56 A1 H Ph D56 4524 D64 A1 Ph D1 D64 4574 D76 A20 Ph D76 D1 4624 D57 A1 H Ph D57 4525 D65 A1 Ph D1 D65 4575 D1 A21 H D56 D56 4625 D60 A1 H Ph D60 4526 D78 A1 Ph D1 D76 4576 D1 A21 H D57 D57 4626 D64 A1 H Ph D64 4527 D56 A1 H D56 D1 4577 D1 A21 H D60 D60 4627 D65 A1 H Ph D65 4528 D57 A1 H D57 D1 4578 D1 A21 H D64 D64 4628 D76 A1 H Ph D76 4529 D60 A1 H D60 D1 4579 D1 A21 H D65 D65 4629 D56 A1 Ph Ph D56 4530 D64 A1 H D64 D1 4580 D1 A21 H D76 D76 4630 D57 A1 Ph Ph D57 4531 D65 A1 H D65 D1 4581 D1 A21 Ph D56 D56 4631 D60 A1 Ph Ph D60 4532 D76 A1 H D76 D1 4582 D1 A21 Ph D57 D57 4632 D64 A1 Ph Ph D64 4533 D56 A1 Ph D56 D1 4583 D1 A21 Ph D60 D60 4633 D65 A1 Ph Ph D65 4534 D57 A1 Ph D57 D1 4584 D1 A21 Ph D64 D64 4634 D76 A1 Ph Ph D76 4535 D60 A1 Ph D60 D1 4585 D1 A21 Ph D65 D65 4635 D56 A20 H H D56 4538 D64 A1 Ph D84 D1 4586 D1 A21 Ph D76 D76 4636 D57 A20 H H D57 4537 D65 A1 Ph D65 D1 4587 D56 A21 H D1 D56 4637 D60 A20 H H D60 4538 D76 A1 Ph D76 D1 4588 D57 A21 H D1 D57 4638 D64 A20 H H D64 4539 D1 A20 H D56 D58 4589 D60 A21 H D1 D60 4639 D65 A20 H H D65 4540 D1 A20 H D57 D57 4590 D64 A21 H D1 D64 4640 D76 A20 H H D76 4541 D1 A20 H D60 D60 4591 D65 A21 H D1 D65 4641 D56 A20 Ph H D56 4542 D1 A20 H D64 D84 4592 D76 A21 H D1 D76 4642 D57 A20 Ph H D57 4543 D1 A20 H D65 D65 4593 D56 A21 Ph D1 D56 4643 D60 A20 Ph H D60 4544 D1 A20 H D76 D76 4594 D57 A21 Ph D1 D57 4644 D64 A20 Ph H D64 4545 D1 A20 Ph D56 D56 4595 D60 A21 Ph D1 D60 4645 D65 A20 Ph H D65 4546 D1 A20 Ph D57 D57 4596 D64 A21 Ph D1 D64 4646 D76 A20 Ph H D76 4547 D1 A20 Ph D60 D60 4597 D65 A21 Ph D1 D65 4647 D56 A20 H Ph D56 4548 D1 A20 Ph D64 D84 4598 D76 A21 Ph D1 D76 4648 D57 A20 H Ph D57 4549 D1 A20 Ph D65 D65 4599 D56 A21 H D56 D1 4649 D60 A20 H Ph D60 4550 D1 A20 Ph D76 D76 4600 D57 A21 H D57 D1 4650 D64 A20 H Ph D64 4651 D65 A20 H Ph D65 4701 D56 A1 H H D1 4751 D60 A20 H Ph D1 4652 D76 A20 H Ph D76 4702 D57 A1 H H D1 4752 D64 A20 H Ph D1 4653 D56 A20 Ph Ph D56 4703 D60 A1 H H D1 4753 D65 A20 H Ph D1 4654 D57 A20 Ph Ph D57 4704 D64 A1 H H D1 4754 D76 A20 H Ph D1 4655 D60 A20 Ph Ph D60 4705 D65 A1 H H D1 4755 D1 A21 H H D56 4656 D64 A20 Ph Ph D64 4706 D76 A1 H H D1 4756 D1 A21 H H D57 4657 D65 A2D Ph Ph D65 4707 D56 A1 Ph H D1 4757 D1 A21 H H D60 4658 D76 A20 Ph Ph D76 4708 D57 A1 Ph H D1 4758 D1 A21 H H D64 4859 D56 A21 H H D56 4709 D60 A1 Ph H D1 4759 D1 A21 H H D65 4660 D57 A21 H H D57 4710 D64 A1 Ph H D1 4760 D1 A21 H H D76 4661 D60 A21 H H D60 4711 D65 A1 Ph H D1 4761 D1 A21 Ph H D56 4662 D64 A21 H H D64 4712 D76 A1 Ph H D1 4762 D1 A21 Ph H D57 4663 D65 A21 H H D65 4713 D56 A1 H Ph D1 4763 D1 A21 Ph H D60 4664 D76 A21 H H D76 4714 D57 A1 H Ph D1 4764 D1 A21 Ph H D64 4665 D56 A21 Ph H D56 4715 D60 A1 H Ph D1 4765 D1 A21 Ph H D65 4686 D57 A21 Ph H D57 4716 D64 A1 H Ph D1 4766 D1 A21 Ph H D76 4667 D60 A21 Ph H D60 4717 D65 A1 H Ph D1 4767 D1 A21 H Ph D56 4668 D64 A21 Ph H D64 4718 D76 A1 H Ph D1 4768 D1 A21 H Ph D57 4669 D65 A21 Ph H D65 4719 D1 A20 H H D56 4769 D1 A21 H Ph D60 4670 D76 A21 Ph H D76 4720 D1 A20 H H D57 4770 D1 A21 H Ph D64 4871 D56 A21 H Ph D56 4721 D1 A20 H H D60 4771 D1 A21 H Ph D65 4672 D57 A21 H Ph D57 4722 D1 A20 H H D64 4772 D1 A21 H Ph D76 4673 D60 A21 H Ph D60 4723 D1 A20 H H D65 4773 D56 A21 H H D1 4674 D64 A21 H Ph D64 4724 D1 A20 H H D76 4774 D57 A21 H H D1 4675 D65 A21 H Ph D65 4725 D1 A20 Ph H D56 4775 D60 A21 H H D1 4676 D76 A21 H Ph D76 4726 D1 A20 Ph H D57 4776 D64 A21 H H D1 4677 D56 A21 Ph Ph D56 4727 D1 A20 Ph H D60 4777 D65 A21 H H D1 4678 D57 A21 Ph Ph D57 4728 D1 A20 Ph H D64 4778 D76 A21 H H D1 4679 D60 A21 Ph Ph D60 4729 D1 A20 Ph H D65 4779 D56 A21 Ph H D1 4680 D64 A21 Ph Ph D64 4730 D1 A20 Ph H D76 4780 D57 A21 Ph H D1 4681 D65 A21 Ph Ph D65 4731 D1 A20 H Ph D56 4781 D60 A21 Ph H D1 4682 D76 A21 Ph Ph D76 4732 D1 A20 H Ph D57 4782 D64 A21 Ph H D1 4683 D1 A1 H H D56 4733 D1 A20 H Ph D60 4783 D65 A21 Ph H D1 4684 D1 A1 H H D57 4734 D1 A20 H Ph D64 4784 D76 A21 Ph H D1 4685 D1 A1 H H D60 4735 D1 A20 H Ph D65 4785 D56 A21 H Ph D1 4686 D1 A1 H H D64 4736 D1 A20 H Ph D76 4786 D57 A21 H Ph D1 4687 D1 A1 H H D65 4737 D56 A20 H H D1 4787 D60 A21 H Ph D1 4688 D1 A1 H H D76 4738 D57 A20 H H D1 4788 D64 A21 H Ph D1 4689 D1 A1 Ph H D56 4739 D60 A20 H H D1 4789 D65 A21 H Ph D1 4690 D1 A1 Ph H D57 4740 D64 A20 H H D1 4790 D76 A21 H Ph D1 4691 D1 A1 Ph H D60 4741 D65 A20 H H D1 4791 D56 A1 H D56 H 4692 D1 A1 Ph H D64 4742 D76 A20 H H D1 4792 D57 A1 H D57 H 4693 D1 A1 Ph H D65 4743 D56 A20 Ph H D1 4793 D60 A1 H D60 H 4694 D1 1 Ph H D76 4744 D57 A20 Ph H D1 4794 D64 A1 H D64 H 4695 D1 A1 H Ph D56 4745 D60 A20 Ph H D1 4795 D65 A1 H D65 H 4698 D1 A3 H Ph D57 4746 D64 A20 Ph H D1 4796 D76 A1 H D76 H 4697 D1 A1 H Ph D60 4747 D65 A20 Ph H D1 4797 D56 A1 Ph D56 H 4698 D1 A1 H Ph D64 4748 D76 A20 Ph H D1 4798 D57 A1 Ph D57 H 4699 D1 A1 H Ph D65 4749 D56 A20 H Ph D1 4799 D60 A1 Ph D60 H 4700 D1 A1 H Ph D76 4750 D57 A20 H Ph D1 4800 D64 A1 Ph D64 H 4801 D65 A1 Ph D65 H 4851 D56 A21 H D56 Ph 4901 D60 A1 H D1 Ph 4802 D76 A1 Ph D76 H 4852 D57 A21 H D57 Ph 4902 D64 A1 H D1 Ph 4803 D56 A1 H D56 Ph 4853 D60 A21 H D60 Ph 4903 D65 A1 H D1 Ph 4804 D57 A1 H D57 Ph 4854 D64 A21 H D64 Ph 4904 D76 A1 H D1 Ph 4805 D60 1 H D60 Ph 4855 D65 A21 H D65 Ph 4905 D56 A1 Ph D1 Ph 4806 D64 1 H D64 Ph 4856 D76 A21 H D76 Ph 4906 D57 A1 Ph D1 Ph 4807 D65 A1 H D65 Ph 4857 D56 A21 Ph D56 Ph 4907 D60 A1 Ph D1 Ph 4808 D76 A1 H D76 Ph 4858 D57 A21 Ph D57 Ph 4908 D64 A1 Ph D1 Ph 4809 D56 A1 Ph D56 Ph 4859 D60 A21 Ph D60 Ph 4909 D65 A1 Ph D1 Ph 4810 D57 A1 Ph D57 Ph 4860 D64 A21 Ph D64 Ph 4910 D76 A1 Ph D1 Ph 4811 D60 A1 Ph D60 Ph 4861 D65 A21 Ph D65 Ph 4911 D1 A20 H D56 H 4812 D64 A1 Ph D64 Ph 4862 D76 A21 Ph D76 Ph 4912 D1 A20 H D57 H 4813 D65 A1 Ph D65 Ph 4863 D1 A1 H D56 H 4913 D1 A20 H D60 H 4814 D76 A1 Ph D76 Ph 4864 D1 A1 H D57 H 4914 D1 A20 H D64 H 4815 D56 A20 H D56 H 4865 D1 A1 H D60 H 4915 D1 A20 H D65 H 4816 D57 A20 H D57 H 4866 D1 A1 H D64 H 4916 D1 A20 H D76 H 4817 D60 A20 H D60 H 4867 D1 A1 H D65 H 4917 D1 A20 Ph D56 H 4818 D64 A20 H D64 H 4868 D1 A1 H D76 H 4918 D1 A20 Ph D57 H 4819 D65 A20 H D65 H 4869 D1 A1 Ph D56 H 4919 D1 A20 Ph D60 H 4820 D76 A20 H D76 H 4870 D1 A1 Ph D57 H 4920 D1 A20 Ph D64 H 4821 D56 A20 Ph D56 H 4871 D1 A1 Ph D60 H 4921 D1 A20 Ph D65 H 4822 D57 A20 Ph D57 H 4872 D1 A1 Ph D64 H 4922 D1 A20 Ph D76 H 4823 D60 A20 Ph D60 H 4873 D1 A1 Ph D65 H 4923 D1 A20 H D56 Ph 4824 D64 A20 Ph D64 H 4874 D1 A1 Ph D76 H 4924 D1 A20 H D57 Ph 4825 D65 A20 Ph D65 H 4875 D1 A1 H D56 Ph 4925 D1 A20 H D60 Ph 4826 D76 A20 Ph D76 H 4876 D1 A1 H D57 Ph 4926 D1 A20 H D64 Ph 4827 D56 A20 H D56 Ph 4877 D1 A1 H D60 Ph 4927 D1 A20 H D65 Ph 4828 D57 A20 H D57 Ph 4878 D1 A1 H D64 Ph 4928 D1 A20 H D76 Ph 4829 D60 A20 H D60 Ph 4879 D1 A1 H D65 Ph 4929 D1 A20 Ph D56 Ph 4830 D64 A20 H D64 Ph 4880 D1 A1 H D76 Ph 4930 D1 A20 Ph D57 Ph 4831 D65 A20 H D65 Ph 4881 D1 A1 Ph D56 Ph 4931 D1 A20 Ph D60 Ph 4832 D76 A20 H D76 Ph 4882 D1 A1 Ph D57 Ph 4932 D1 A20 Ph D64 Ph 4833 D56 A20 Ph D56 Ph 4883 D1 A1 Ph D60 Ph 4933 D1 A20 Ph D65 Ph 4834 D57 A20 Ph D57 Ph 4884 D1 A1 Ph D64 Ph 4934 D1 A20 Ph D76 Ph 4835 D60 A20 Ph D60 Ph 4885 D1 A1 Ph D65 Ph 4935 D56 A20 H D1 H 4836 D64 A20 Ph D64 Ph 4886 D1 A1 Ph D76 Ph 4936 D57 A20 H D1 H 4837 D65 A20 Ph D65 Ph 4887 D56 A1 H D1 H 4937 D60 A20 H D1 H 4838 D76 A20 Ph D76 Ph 4888 D57 A1 H D1 H 4938 D64 A20 H D1 H 4839 D56 A21 H D56 H 4889 D60 A1 H D1 H 4939 D65 A20 H D1 H 4840 D57 A21 H D57 H 4890 D64 A1 H D1 H 4940 D76 A20 H D1 H 4841 D60 A21 H D60 H 4891 D65 A1 H D1 H 4941 D56 A20 Ph D1 H 4842 D64 A21 H D64 H 4892 D76 A1 H D1 H 4942 D57 A20 Ph D1 H 4843 D65 A21 H D65 H 4893 D56 A1 Ph D1 H 4943 D60 A20 Ph D1 H 4844 D76 A21 H D76 H 4894 D57 A1 Ph D1 H 4944 D64 A20 Ph D1 H 4845 D56 A21 Ph D56 H 4895 D60 A1 Ph D1 H 4945 D65 A20 Ph D1 H 4846 D57 A21 Ph D57 H 4896 D64 1 Ph D1 H 4946 D76 A20 Ph D1 H 4847 D60 A21 Ph D60 H 4897 D65 A1 Ph D1 H 4947 D56 A20 H D1 Ph 4848 D64 A21 Ph D64 H 4898 D76 A1 Ph D1 H 4948 D57 A20 H D1 Ph 4849 D65 A21 Ph D65 H 4899 D56 A1 H D1 Ph 4949 D60 A20 H D1 Ph 4850 D76 A21 Ph D76 H 4900 D57 A1 H D1 Ph 4950 D64 A20 H D1 Ph 4951 D65 A20 H D1 Ph 5001 D56 A21 Ph D1 Ph 5051 Ph A20 D60 Ph D60 4952 D76 A20 H D1 Ph 5002 D57 A21 Ph D1 Ph 5052 Ph A20 D64 Ph D64 4953 D56 A20 Ph D1 Ph 5003 D60 A21 Ph D1 Ph 5053 Ph A20 D65 Ph D65 4954 D57 A20 Ph D1 Ph 5004 D64 A21 Ph D1 Ph 5054 Ph A20 D76 Ph D76 4955 D60 A20 Ph D1 Ph 5005 D65 A21 Ph D1 Ph 5055 H A21 D56 H D56 4956 D64 A20 Ph D1 Ph 5006 D76 A21 Ph D1 Ph 5056 H A21 D57 H D57 4957 D65 A20 Ph D1 Ph 5007 H A1 D56 H D56 5057 H A21 D60 H D60 4958 D76 A20 Ph D1 Ph 5008 H A1 D57 H D57 5058 H A21 D64 H D64 4959 D1 A21 H D56 H 5009 H A1 D60 H D60 5059 H A21 D65 H D65 4960 D1 A21 H D57 H 5010 H A1 D64 H D64 5060 H A21 D75 H D76 4961 D1 A21 H D60 H 5011 H A1 D65 H D65 5061 Ph A21 D56 H D56 4962 D1 A21 H D64 H 5012 H A1 D76 H D76 5062 Ph A21 D57 H D57 4963 D1 A21 H D65 H 5013 Ph A1 D56 H D56 5063 Ph A21 D60 H D60 4964 D1 A21 H D76 H 5014 Ph A1 D57 H D57 5064 Ph A21 D64 H D64 4965 D1 A21 Ph D56 H 5015 Ph A1 D60 H D60 5065 Ph A21 D65 H D65 4966 D1 A21 Ph D57 H 5016 Ph A1 D64 H D64 5066 Ph A21 D76 H D76 4967 D1 A21 Ph D60 H 5017 Ph A1 D65 H D65 5067 H A21 D56 Ph D56 4968 D1 A21 Ph D64 H 5018 Ph A1 D76 H D76 5068 H A21 D57 Ph D57 4969 D1 A21 Ph D65 H 5019 H A1 D56 Ph D56 5069 H A21 D60 Ph D60 4970 D1 A21 Ph D76 H 5020 H A1 D57 Ph D57 5070 H A21 D64 Ph D64 4971 D1 A21 H D56 Ph 5021 H A1 D60 Ph D60 5071 H A21 D65 Ph 765 4972 D1 A21 H D57 Ph 5022 H A1 D64 Ph D64 5072 H A21 D76 Ph D76 4973 D1 A21 H D60 Ph 5023 H A1 D65 Ph D65 5073 Ph A21 D56 Ph D56 4974 D1 A21 H D64 Ph 5024 H A1 D76 Ph D76 5074 Ph A21 D57 Ph D57 4975 D1 A21 H D65 Ph 5025 Ph A1 D56 Ph D56 5075 Ph A21 D60 Ph D60 4976 D1 A21 H D76 Ph 5026 Ph A1 D57 Ph D57 5076 Ph A21 D64 Ph D64 4977 D1 A21 Ph D56 Ph 5027 Ph A1 D60 Ph D60 5077 Ph A21 D65 Ph D65 4978 D1 A21 Ph D57 Ph 5028 Ph A1 D64 Ph D64 5078 Ph A21 D76 Ph D76 4979 D1 A21 Ph D60 Ph 5029 Ph A1 D65 Ph D65 5079 H A1 D1 H D56 4980 D1 A21 Ph D64 Ph 5030 Ph A1 D76 Ph D76 5080 H A1 D1 H D57 4981 D1 A21 Ph D65 Ph 5031 H A20 D56 H D56 5081 H A1 D1 H D60 4982 D1 A21 Ph D76 Ph 5032 H A20 D57 H D57 5082 H A1 D1 H D64 4983 D56 A21 H D1 H 5033 H A20 D60 H D60 5083 H A1 D1 H D65 4984 D57 A21 H D1 H 5034 H A20 D64 H D64 5084 H A1 D1 H D76 4985 D60 A21 H D1 H 5035 H A20 D65 H D65 5085 Ph A1 D1 H D56 4986 D64 A20 H D1 H 5036 H A20 D76 H D76 5086 Ph A1 D1 H D57 4987 D65 A21 H D1 H 5037 Ph A20 D56 H D56 5087 Ph A1 D1 H D60 4988 D76 A21 H D1 H 5038 Ph A20 D57 H D57 5088 Ph A1 D1 H D64 4989 D56 A21 Ph D1 H 5039 Ph A20 D60 H D60 5089 Ph A1 D1 H D65 4990 D57 A21 Ph D1 H 5040 Ph A20 D64 H D64 5090 Ph A1 D1 H D76 4991 D60 A21 Ph D1 H 5041 Ph A20 D65 H D65 5091 H A1 D1 Ph D56 4992 D64 A21 Ph D1 H 5042 Ph A20 D76 H D76 5092 H A1 D1 Ph D57 4993 D65 A21 Ph D1 H 5043 H A20 D56 Ph D56 5083 H A1 D1 Ph D60 4994 D76 A21 Ph D1 H 5044 H A20 D57 Ph D57 5094 H A1 D1 Ph D64 4995 D56 A21 H D1 Ph 5045 H A20 D60 Ph D60 5095 H A1 D1 Ph D65 4996 D57 A21 H D1 Ph 5046 H A20 D64 Ph D64 5096 H A1 D1 Ph D76 4997 D60 A21 H D1 Ph 5047 H A20 D65 Ph D65 5097 Ph A1 D1 Ph D56 4998 D64 A21 H D1 Ph 5048 H A20 D76 Ph D76 5098 Ph A1 D1 Ph D57 4999 D65 A21 H D1 Ph 5049 Ph A20 D56 Ph D56 5099 Ph A1 D1 Ph D60 5000 D76 A21 H D1 Ph 5050 Ph A20 D57 Ph D57 5100 Ph A1 D1 Ph D64 5101 Ph A1 D1 Ph D65 5151 H 420 D56 H D1 5201 H A21 D60 H D1 5102 Ph A1 D1 Ph D76 5152 H A20 D57 H D1 5202 H A21 D64 H D1 5103 H A1 D56 H D1 5153 H A20 D60 H D1 5203 H A21 D65 H D1 5104 H A1 D57 H D1 5154 H A20 D64 H D1 5204 H A21 D76 H D1 5105 H A1 D60 H D1 5155 H A20 D65 H D1 5205 Ph A21 D56 H D1 5106 H A1 D64 H D1 5156 H A20 D76 H D1 5206 Ph A21 D57 H D1 5107 H A1 D65 H D1 5157 Ph A20 D56 H D1 5207 Ph A21 D60 H D1 5108 H A1 D76 H D1 5158 Ph A20 D57 H D1 5208 Ph A21 D64 H D1 5109 Ph A1 D56 H D1 5159 Ph A20 D60 H D1 5209 Ph A21 D65 H D1 5110 Ph A1 D57 H D1 5160 Ph A20 D64 H D1 5210 Ph A21 D76 H D1 5111 Ph A1 D60 H D1 5161 Ph A20 D65 H D1 5211 H A21 D56 Ph D1 5112 Ph A1 D64 H D1 5162 Ph A20 D76 H D1 5212 H A21 D57 Ph D1 5113 Ph A1 D65 H D1 5163 H A20 D56 Ph D1 5213 H A21 D60 Ph D1 5114 Ph A1 D76 H D1 5164 H A20 D57 Ph D1 5214 H A21 D64 Ph D1 5115 H A1 D56 Ph D1 5165 H A20 D60 Ph D1 5215 H A21 D65 Ph D1 5116 H A1 D57 Ph D1 5160 H A20 D64 Ph D1 5216 H A21 D76 Ph D1 5117 H A1 D60 Ph D1 5167 H A20 D65 Ph D1 5217 Ph A21 D56 Ph D1 5118 H A1 D64 Ph D1 5168 H A20 D76 Ph D1 5218 Ph A21 D57 Ph D1 5119 H A1 D65 Ph D1 5169 Ph A20 D56 Ph D1 5219 Ph A21 D60 Ph D1 5120 H A1 D76 Ph D1 5170 Ph A20 D57 Ph D1 5220 Ph A21 D64 Ph D1 5121 Ph A1 D56 Ph D1 5171 Ph A20 D60 Ph D1 5221 Ph A21 065 Ph D1 5122 Ph A1 D57 Ph D1 5172 Ph A20 D64 Ph D1 5222 Ph A21 D76 Ph D1 5123 Ph A1 D60 Ph D1 5173 Ph A20 D65 Ph D1 5223 D72 A1 H H D72 5124 Ph A1 D64 Ph D1 5174 Ph A20 D76 Ph D1 5224 D1 A1 H H D72 5125 Ph A1 D65 Ph D1 5175 H A21 D1 H D56 5225 D72 A1 H H D1 5126 Ph A1 D76 Ph D1 5176 H A21 D1 H D57 5226 D72 A20 H H D72 5127 H A20 D1 H D56 5177 H A21 D1 H D60 5227 D1 A20 H H D72 5128 H A20 D1 H D57 5178 H A21 D1 H D64 5228 D72 A20 H H D1 5129 H A20 D1 H D60 5179 H A21 D1 H D65 5229 D72 A21 H H D72 5130 H A20 D1 H D64 5180 H A21 D1 H D76 5230 D1 A21 H H D72 5131 H A20 D1 H D65 5181 Ph A21 D1 H D56 5231 D72 A21 H H D1 5132 H A20 D1 H D76 5182 Ph A21 D1 H D57 5133 Ph A20 D1 H D56 5183 Ph A21 D1 H D60 5134 Ph A20 D1 H D57 5184 Ph A21 D1 H D64 5135 Ph A20 D1 H D60 5185 Ph A21 D1 H D65 5136 Ph A20 D1 H D64 5186 Ph A21 D1 H D76 5137 Ph A20 D1 H D65 5187 H A21 D1 Ph D56 5138 Ph A20 D1 H D76 5188 H A21 D1 Ph D57 5139 H A20 D1 Ph D56 5189 H A21 D1 Ph D60 5140 H A20 D1 Ph D57 5190 H A21 D1 Ph D64 5141 H A20 D1 Ph D60 5191 H A21 D1 Ph D65 5142 H A20 D1 Ph D64 5192 H A21 D1 Ph D76 5143 H A20 D1 Ph D65 5193 Ph A21 D1 Ph D56 5144 H A20 D1 Ph D76 5194 Ph A21 D1 Ph D57 5145 Ph A20 D1 Ph D56 5195 Ph A21 D1 Ph D60 5146 Ph A20 D1 Ph D57 5196 Ph A21 D1 Ph D64 5147 Ph A20 D1 Ph D60 5197 Ph A21 D1 Ph D65 5148 Ph A20 D1 Ph D64 5198 Ph A21 D1 Ph D76 5149 Ph A20 D1 Ph D65 5199 H A21 D56 H D1 5150 Ph A20 D1 Ph D76 5200 H A21 D57 H D1

[Synthesis Method of Compound Represented by Formula (1)]

The compound represented by the formula (1) can be synthesized by combining existing reactions. For example, a compound of the formula (1), in which R¹, R⁴ and R⁵ are D1's, and R² is A1, can be synthesized via an intermediate through the following reaction scheme.

In this reaction scheme, halogenated pyridine is used as a starting material. Here, halogenated pyridine having a fluorine atom at a position where D1 is to be introduced and having a chlorine atom at a position where A1 is to be introduced is prepared. The halogenated pyridine is reacted with 4,4,4′,5,5′,5′-octamethyl-2,2′-bi(1,3,2-oxaborane) in the presence of a catalyst, and then is reacted with A1-Cl so as to obtain an intermediate in which the chlorine atom is substituted with A1. The intermediate is further reacted with D1-H in the presence of a catalyst so as to obtain a target compound in which the fluorine atom is substituted with D1. In this two-step reaction, the first reaction and the second reaction can be performed in reverse order.

The reaction is an application of a conventionally known reaction, and conventionally known reaction conditions can be appropriately selected and used. For the details of the reaction, synthesis examples to be described below can be referred to. Further, the compound represented by the formula (1) can also be synthesized by combining conventionally known other synthesis reactions.

A compound represented by the following formula (1′), which is a synthetic intermediate of the compound represented by the formula (1), includes a novel compound.

R¹ to R⁵ in the formula (1′) satisfy the following condition 1 or condition 2.

(Condition 1) Among R¹ to R⁵,

one of R¹ and R² is a halogen atom,

among the rest of R¹ to R⁵, p are D's, and

the remaining 4-p are R's.

(Condition 2) Among R¹ to R⁵,

one of R¹ and R² is A,

among the rest of R¹ to R⁵, p are halogen atoms, and

the remaining 4-p are R's.

Here,

A is a group represented by Het-L^(A)-* or CN-L^(A)-*, in which Het represents a substituted or unsubstituted heteroaryl group bonded via a carbon atom (meanwhile, at least one nitrogen atom is included as a ring skeleton-forming atom of the heteroaryl group), L^(A) represents a single bond or a substituted or unsubstituted arylene group, and * represents a bond position.

D is a group represented by the following formula (IIa), (IIb), (IIc) or (IId).

Here, X′ represents N—R^(D)′, an oxygen atom, or a sulfur atom,

each R^(D) independently represents a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted amino group, a cyano group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted heteroaryl group, a substituted or unsubstituted heteroaryloxy group or a silyl group, and two or more R^(D)'s may be bonded to each other to form a cyclic structure.

R^(D)′ represents a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heteroaryl group, and R^(D), may be bonded to one or more R^(D)'s to form a cyclic structure, each L^(D) independently represents a single bond, a substituted or unsubstituted arylene group, or a substituted or unsubstituted heteroarylene group, and

* represents a bond position.

R is a hydrogen atom, a deuterium atom, or a substituted or unsubstituted aryl group (but, other than a group that may be A or D).

p is any integer of 1 to 3. When p is 2 or 3, D's present in the molecule may be the same or different. When p is 1 or 2, R's present in the molecule may be the same or different.

The descriptions and preferable ranges of A, D, R, and p of the formula (1′) can be made with reference to the corresponding descriptions of the formula (1).

In some embodiments, the condition 1 is satisfied. In some embodiments, p is 2. In some embodiments, D is a group represented by the formula (IIb). In some embodiments, the halogen atom is a chlorine atom. In some embodiments, the halogen atom is an iodine atom. In some embodiments, R is a substituted or unsubstituted aryl group. In some embodiments, R is an unsubstituted phenyl group.

In some embodiments, the condition 2 is satisfied. In some embodiments, p is 2 or 3. In some embodiments, A has a substituted or unsubstituted triazinyl group. In some embodiments, the halogen atom is a fluorine atom.

Synthetic intermediates of Synthesis Examples 1 to 3 to be described below can be mentioned as preferable examples.

All the definitions of terms described in 100391 to [0101] of US2020/0168814A1 are incorporated herein, as a part of the present specification, and are used as definitions of terms of the present invention.

In some embodiments, the compound represented by the formula (I) is a light-emitting material.

In some embodiments, the compound represented by the formula (I) is a compound capable of emitting delayed fluorescence.

In some embodiments of the present disclosure, the compound represented by the formula (1) is, when excited thermally or by an electronic means, able to emit light in a UV region, light of blue, green, yellow or orange in a visible region, in a red region (e.g., about 420 nm to about 500 nm, about 500 nm to about 600 nm, or about 600 nm to about 700 nm) or in a near IR region.

In some embodiments of the present disclosure, the compound represented by the formula (1) is, when excited thermally or by an electronic means, able to emit light of red or orange in a visible region (e.g., about 620 nm to about 780 nm, about 650 nm).

In some embodiments of the present disclosure, the compound represented by the formula (1) is, when excited thermally or by an electronic means, able to emit light of orange or yellow in a visible region (e.g., about 570 nm to about 620 nm, about 590 nm, about 570 nm).

In some embodiments of the present disclosure, the compound represented by the formula (1) is, when excited thermally or by an electronic means, able to emit light of green in a visible region (e.g., about 490 nm to about 575 nm, about 510 nm).

In some embodiments of the present disclosure, the compound represented by the formula (1) is, when excited thermally or by an electronic means, able to emit light of blue in a visible region (e.g., about 400 nm to about 490 nm, about 475 nm).

In some embodiments of the present disclosure, the compound represented by the formula (1) is, when excited thermally or by an electronic means, able to emit light in a UV region (e.g., about 280 to 400 nm).

In some embodiments of the present disclosure, the compound represented by the formula (1) is, when excited thermally or by an electronic means, able to emit light in an IR region (e.g., about 780 nm to 2 μm). In some embodiments of the present disclosure, the compound represented by the formula (I) is a charge transport material.

In some embodiments of the present disclosure, the compound represented by the formula (I) is used for a charge transport layer. In some embodiments of the present disclosure, the compound represented by the formula (I), as a charge transport material, has high mobility, and is excellent in durability.

In some embodiments of the present disclosure, an organic semiconductor device using the compound represented by the formula (I), such as CMOS (complementary metal oxide semiconductor), can be manufactured. In some embodiments of the present disclosure, it is possible to manufacture an organic optical device such as an organic electroluminescence device or a solid-state image sensing device (for example, a CMOS image sensor) by using the compound represented by the formula (I).

Electronic characteristics of small-molecule chemical substance libraries can be calculated by known ab initio quantum chemistry calculation. For example, according to time-dependent density functional theory calculation using 6-31G* as a basis, and a functional group known as Becke's three parameters, Lee-Yang-Parr hybrid functionals, the Hartree-Fock equation (TD-DFT/B3LYP/6-31G*) is analyzed and molecular fractions (parts) having HOMO not lower than a specific threshold value and LUMO not higher than a specific threshold value can be screened, and the calculated triplet state of the parts is more than 2.75 eV.

With that, for example, in the presence of a HOMO energy (for example, ionizing potential) of −6.5 eV or more, a donor part (“D”) can be selected. On the other hand, for example, in the presence of a LUMO energy (for example, electron affinity) of −0.5 eV or less, an acceptor part (“A”) can be selected. A bridge part (“B”) is a strong conjugated system, for example, capable of strictly limiting the acceptor part and the donor part in a specific three-dimensional configuration, and therefore prevents the donor part and the acceptor part from overlapping in the pai-conjugated system.

In some embodiments, a compound library is screened using at least one of the following characteristics.

1. Light emission around a specific wavelength.

2. A triplet state over a calculated specific energy level.

3. ΔE_(ST) value lower than a specific value.

4. Quantum yield more than a specific value.

5. HOMO level.

6. LUMO level.

In some embodiments, the difference (ΔE_(ST)) between the lowest singlet excited state and the lowest triplet excited state at 77 K is less than about 0.5 eV, less than about 0.4 eV, less than about 0.3 eV, less than about 0.2 eV, or less than about 0.1 eV. In some embodiments, ΔE_(ST) value is less than about 0.09 eV, less than about 0.08 eV, less than about 0.07 eV, less than about 0.06 eV, less than about 0.05 eV, less than about 0.04 eV, less than about 0.03 eV, less than about 0.02 eV, or less than about 0.01 eV In some embodiments, the compound represented by the formula (1) shows a quantum yield of more than 25%, for example, about 30%, about 35%, about 40%, about 45%, about 50%, about 55%, about 60%, about 65%, about 70%, about 75%, about 80%, about 85%, about 90%, about 95% or more.

[Components Using Compound of the Present Disclosure]

In some embodiments, a solid-state film or layer is formed through combining with the compound represented by the formula (I), dispersing of the compound, covalent bonding with the compound, coating of the compound, carrying of the compound, or the co-use of one or more materials that associate with the compound (for example, small molecules, polymers, metals, metal complexes, etc.). For example, the compound represented by the formula (I) can be combined with an electrically active material to form a film. In some cases, the compound represented by the formula (I) may be combined with a hole transport polymer. In some cases, the compound represented by the formula (I) may be combined with an electron transport polymer. In some cases, the compound represented by the formula (I) may be combined with a hole transport polymer and an electron transport polymer. In some cases, the compound represented by the formula (I) may be combined with a copolymer having both a hole transport part and an electron transport part. According to the above embodiments, electrons and/or holes formed within the solid-state film or layer can interact with the compound represented by the formula (I).

[Film Formation]

In some embodiments, a film containing the compound represented by the formula (1) can be formed in a wet process. In a wet process, a solution prepared by dissolving a composition containing the compound of the present invention is applied onto a surface, and then the solvent is removed to form a film. The wet process includes a spin coating method, a slit coating method, an ink jet method (a spraying method), a gravure printing method, an offset printing method and flexographic printing method, which, however, are not limitative. In the wet process, an appropriate organic solvent capable of dissolving a composition containing the compound of the present invention is selected and used. In some embodiments, a substituent (for example, an alkyl group) capable of increasing the solubility in an organic solvent can be introduced into the compound to be contained in the composition.

In some embodiments, a film containing the compound of the present invention can be formed in a dry process. In some embodiments, a vacuum evaporation method is employable as a dry process, which, however, is not limitative. In the case where a vacuum evaporation method is employed, compounds to constitute a film can be co-evaporated from individual evaporation sources, or can be co-evaporated from a single evaporation source formed by mixing the compounds. In the case where a single evaporation source is used, a mixed powder prepared by mixing compound powders can be used, or a compression molded body prepared by compression-molding the mixed powder can be used, or a mixture prepared by heating and melting the constituent compounds and cooling the resulting melt can be used. In some embodiments, by co-evaporation under the condition where the evaporation rate (weight reduction rate) of the plural compounds contained in a single evaporation source is the same or is nearly the same, a film having a compositional ratio corresponding to the compositional ratio of the plural compounds contained in the evaporation source can be formed. When plural compounds are mixed in the same compositional ratio as the compositional ratio of the film to be formed to prepare an evaporation source, a film having a desired compositional ratio can be formed in a simplified manner. In some embodiments, the temperature at which the compounds to be co-evaporated has the same weight reduction ratio is specifically defined, and the temperature can be employed as the temperature of co-evaporation.

All the descriptions on use examples, a device, a display, a screen, etc., which are described in [0141] to [0169] and [0192] to [0242] of US2020/0168814A1, are incorporated herein as a part of the present specification, and are used as descriptions of the present invention.

In some embodiments of the present invention, the following compounds can be preferably used as host materials.

In some embodiments of the present invention, the following compounds can be preferably used as electron blocking materials.

In some embodiments of the present invention, the following compounds can be preferably used as hole blocking materials.

Hereinafter, preferable compounds that can be used as a hole injection material of an organic electroluminescence device will be exemplified. MoO₃,

Next, preferable compounds that can be used as an electron injection material of an organic electroluminescence device will be exemplified.

Further, preferable compounds as materials that can be added to each organic layer of an organic electroluminescence device will be exemplified. For example, addition as a stabilizing material, or the like may be taken into consideration.

Examples

Hereinafter, the features of the present invention will be described in more detail with reference to Synthesis examples and Examples. The materials, the processing contents, the processing procedures, etc. illustrated below can be appropriately changed as long as they do not deviate from the gist of the present invention. Therefore, the scope of the present invention should not be construed as limiting to specific examples illustrated below. Further, the features of the following samples were evaluated by using NMR (manufactured by Bruker, nuclear magnetic resonance 500 MHz), LC/MS (manufactured by Waters, liquid chromatography mass spectrometer), AC3 (manufactured by RIKEN KEIKI), a high-performance UV/Vis/NIR spectrophotometer (manufactured by PerkinElmer, Lambda950), a fluorescence spectrophotometer (manufactured by Horiba, FluoroMax-4), a photonic multi-channel analyzer (manufactured by Hamamatsu Photonics, PMA-12 C10027-01), an absolute PL quantum yield measuring system (manufactured by Hamamatsu Photonics, C11347), an automatic current voltage luminance measuring system (manufactured by System GIKEN, ETS-170), a lifetime measuring system (manufactured by System GIKEN, EAS-26C) and a streak camera (manufactured by Hamamatsu Photonics, model C4334). As a host material, PYD-2Cz was employed in Examples, and mCBP was employed in Comparative Compound A. Further, the compounds of Examples of the present application were used for manufacturing a device and the like after sublimation purification.

(Synthesis Example 1) Synthesis of Compound 939

Synthesis of Intermediate 1-1

Potassium acetate (2.93 g, 29.85 mmol), 4,4′,4′,5,5′,5′-octamethyl-2,2′-bi(1,3,2-oxaborane) (3.34 g, 13.13 mmol), tris(dibenzylideneacetone)dipalladium(0) (0.22 g, 2 mol %), 2-dicyclohexylphosphino-2′,4′,6-triisopropylbiphenyl (0.34 g, 6 mol %) and 3-chloro-2,5,6-trifluoropyridine (2.00 g, 11.94 mmol) were dissolved in 1,4-dioxane under a nitrogen atmosphere. The mixture was heated to 110° C., and was stirred overnight. After the starting compounds were no longer detected through thin-layer chromatography, the temperature of the mixture was lowered to a room temperature. To a flask containing the mixture, 2-chloro-4,6-diphenyl-1,3,5-triazine (3.97 g, 14.82 mmol), tetrakis(triphenylphosphine)palladium(0) (0.43 g, 3 mol %) and potassium carbonate (2.56 g, 18.53 mmol, 2M aqueous solution) were added while a nitrogen atmosphere was maintained. The mixture was heated to 100° C. and was stirred overnight under a nitrogen atmosphere. The reaction was stopped with a brine solution at a room temperature, and the mixture was extracted with chloroform and dried over MgSO₄, and then was concentrated by a vacuum evaporator system. This mixture was purified through silica gel column chromatography using n-hexane/chloroform as an eluent to obtain 2,4-diphenyl-6-(2,5,6-trifluoropyridine-3-yl)-1,3,5-triazine (Intermediate 1-1) as a powdery product (yield 2.30 g, yield 51.1%).

¹H NMR (500 MHz, CDCl₃) S 7.59 (t, J=8.0 Hz, 4H), 7.65 (t, J=7.5 Hz, 2H), 8.73 (d, J=8.0 Hz, 4H), 8.91 (q, J=8.0 Hz, 1H), ¹⁹F NMR (470 MHz, CDCl₃) δ −144.64 (t, J_(F)=29.1 Hz, 1F), −81.56 (t, J_(F)=13.63 Hz, 1F), −65.22 (t, J_(F)=19.74 Hz, 1F). MS (APCI) m/z 365.24 [(M+H)⁺].

Synthesis of Compound 939

Potassium carbonate (1.90 g, 13.72 mmol), 2,4-diphenyl-6-(2,5,6-trifluoropyridine-3-yl)-1,3,5-triazine (Intermediate 1-1) (1.00 g, 2.74 mmol) and 9H-carbazole (1.84 g, 10.98 mmol) were placed in a three-necked round-bottom flask. The mixture was dried in a vacuum system, and then DMF (dimethylformamide), as a solvent, was added thereto under a nitrogen atmosphere. The reaction mixture was stirred overnight while being kept at 160° C. The reaction was stopped with a NH₄Cl aqueous solution, and extraction with chloroform was performed. An organic layer separated after extraction was dried over MgSO₄, and the solvent was concentrated by a vacuum evaporator system. Through column chromatography using a mixture of toluene and hexane (1:4) as an eluent, the reaction product, 9,9′,9″-((2r,3r,6r)-5-(4,6-diphenyl-1,3,5-triazine-2,3,6-triyl)pyridine-2,3,6-triyl)tris(9H-carbazole) (compound 939), was separated (yield 2.20 g, yield 99.5%).

¹H NMR (500 MHz, CDCl₃) δ 6.99 (t, J=6.5 Hz, 2H), 7.08 (t, J=7.5 Hz, 2H), 7.13 (t, J=7.0 Hz, 4H) 7.22-7.35 (m, 10H), 7.47-7.51 (m, 4H), 7.62 (d, J=9.0 Hz, 2H), 7.78 (d, J=8.5 Hz, 2H), 7.89 (d, J=8.0 Hz, 2H), 8.01 (d, J=7.5 Hz, 2H), 8.07 (d, J=8.0 Hz, 2H), 9.42 (s, 1H), MS (APCI) m/z 806.50 [(M+H)⁺]

(Synthesis Example 2) Synthesis of Compound 962

Synthesis of Intermediate 2-1

Potassium carbonate (1.51 g, 10.89 mmol), 5-chloro-2,3-difluoro-4-iodopyridine (1.00 g, 3.63 mmol) and 9H-carbazole (1.82 g, 10.89 mmol) were placed in a three-necked round-bottom flask. The mixture was dried under vacuum, and then DMF, as a solvent, was added thereto under a nitrogen atmosphere. After the reaction mixture was stirred overnight while being kept at 160° C., the reaction was stopped with a NH₄Cl aqueous solution, and the mixture was extracted with chloroform. An organic layer separated after extraction was dried over MgSO₄, and was concentrated by a vacuum evaporator system. Through column chromatography using a mixture of toluene and hexane (1:4) as an eluent, the reaction product, 9,9′-(((2r,3s)-5-chloro-4-iodopyridine-2,3-diyl)bis(9H-carbazole)(intermediate 2-1), was separated (yield 2.00 g, yield 96.7%).

¹H NMR (500 MHz, CDCl₃) δ 6.77-7.18 (m, 12H), 7.68 (d, J=7.5 Hz, 2H), 7.75-7.77 (m, 2H) 8.83 (s, 1H), MS (APCI) m/z 570.28 [(M+H)⁺]

Synthesis of Intermediate 2-2

9′-((2r,3s)-5-chloro-4-iodopyridine-2,3-diyl)bis(9H-carbazole) (intermediate 2-1) (2.50 g, 4.39 mmol), phenylboronic acid (0.64 g, 5.26 mmol), potassium carbonate (1.82 g in an aqueous solution, 13.16 mmol, 2M) and tetrakis(triphenylphosphine)palladium (0.15 g, 3 mol %) were dissolved in THF and distilled water (depending on the amount of K₂CO₃). The resultant solution was refluxed under a nitrogen atmosphere for 12 h, and then was cooled to a room temperature. After extraction using ethyl acetate and distilled water, the solvent of an organic layer was evaporated under vacuum. Through purification with column chromatography using toluene:hexane (1:1) as an eluent, 9,9′-(((2r,3r)-5-chloro-4-phenylpyridine-2,3-diyl)bis(9H-carbazole)(Intermediate 2-2) was obtained as a white powdery product (yield 2.19 g, yield 96.1%).

¹H NMR (500 MHz, CDCl₃) δ 6.59-7.05 (m, 15H), 7.21 (d, J=8.5 Hz, 2H), 7.58-7.59 (m, 2H) 7.72 (d, J=7.5 Hz, 2H), 9.00 (s, 1H), MS (APCI) m/z 520.42 [(M+H)⁺]

Synthesis of Compound 962

Potassium acetate (1.13 g, 4,4′,5′,5′-octamethyl-2,2′-bi(1,3,2-dioxaborane) (2.93 g, 11.54 mmol), tris(dibenzylideneacetone)dipalladium (0.11 g, 3 mol %), and 2-dicyclohexylphosphino-2′,4′-triisopropylbiphenyl (0.11 g) ((2r,3r)-5-chloro-4-phenylpyridine-2,3-diyl)bis(9H-carbazole) (Intermediate 2-2) (2.00 g, 3.85 mmol) were dissolved in 1,4-dioxane under a nitrogen atmosphere. The mixture was heated to 110° C. and was stirred overnight. After the starting compounds were no longer detected through thin-layer chromatography, the temperature of the mixture was lowered to a room temperature. To the mixture in a flask, 2-chloro-4,6-diphenyl-1,3,5-triazine (1.58 g, 5.89 mmol), tetrakis(triphenylphosphine)palladium(0) (0.14 g, 3 mol %) and potassium carbonate (1.63 g, 11.77 mmol, 2M aqueous solution) were added while a nitrogen atmosphere was maintained. The mixture was heated to 100° C. and was stirred overnight under a nitrogen atmosphere. The reaction was stopped with a brine solution at a room temperature, and the mixture was extracted with chloroform and dried over MgSO₄, and then was concentrated by a vacuum evaporator system. This mixture was purified through silica gel column chromatography using n-hexane/methylene chloride as an eluent to obtain 9,9′-((2r,3r)-5-(4,6-diphenyl-1,3,5-triazine-2-yl)-4-phenylpyridine-2,3-diyl)bis(9H-carbazole)(Compound 962) as a powdery product (yield 0.37 g, yield 13.0%).

¹H NMR (500 MHz, CDCl₃) δ 6.84-7.05 (m, 16H), 7.26 (d, J=8.0 Hz, 1H), 7.46 (t, J=7.5 Hz, 4H), 7.57 (t, J=7.0 Hz, 2H), 7.62-7.64 (m, 2H), 7.74 (d, J=7.5 Hz, 2H), 8.35 (d, J=8.0 Hz, 4H), 9.61 (s, 1H), MS (APCI) m/z 717.42 [(M+H)⁺]

(Synthesis Example 3) Synthesis of Compound 950

Synthesis of Intermediate 3-1

Potassium acetate (5.06 g, 51.55 mmol), 4.4′,4′4′,5,5′,5′,5′-octamethyl-2,2′-bi(1,3,2-dioxaborane) (7.20 g, 28.35 mmol), [1,1′-bis(diphenylphosphino)ferrocene]dichloropalladium(II) (0.57 g, 3 mol %) and 5-bromo-2,3-difluoropyridine (5.00 g, 25.78 mmol) were dissolved in 1,4-dioxane under a nitrogen atmosphere. The mixture was heated to 100° C. and was stirred overnight. After the starting compounds were no longer detected through thin-layer chromatography, the temperature of the mixture was lowered to a room temperature. To a flask containing the mixture, 2-chloro-4,6-diphenyl-1,3,5-triazine (8.66 g, 32.36 mmol), tetrakis(triphenylphosphine)palladium(0) (0.93 g, 3 mol %) and potassium carbonate (5.59 g, 40.45 mmol, 2M aqueous solution) were added while a nitrogen atmosphere was maintained. The mixture was heated to 100° C. and was stirred overnight under a nitrogen atmosphere. The reaction was stopped with a brine solution at a room temperature, and the mixture was extracted with chloroform and dried over MgSO₄, and then was concentrated by a vacuum evaporator system. This mixture was purified through silica gel column chromatography using n-hexane/toluene as an eluent to obtain 2-(5,6-difluoropyridine-3-yl)-4,6-diphenyl-1,3,5-triazine (Intermediate 3-1) as a powdery product (yield 8.80 g, yield 94.2%).

¹H NMR (500 MHz, CDCl₃) δ 7.60 (t, J=7.5 Hz, 4H), 7.66 (t, J=7.5 Hz, 2H), 8.74 (d, J=8.0 Hz, 4H), 8.86 (t, J=9.0 Hz, 1H), 9.36 (s, 1H), MS (APCI) m/z 347.23 [(M+H)⁺]

Synthesis of Compound 950

Potassium carbonate (1.20 g, 8.66 mmol), 2-(5,6-difluoropyridine-3-yl)-4,6-diphenyl-1,3,5-triazine (Intermediate 3-1) (1.00 g, 2.89 mmol) and 9H-carbazole (1.45 g, 8.66 mmol) were placed in a three-necked round-bottom flask. The mixture was dried in a vacuum system, and then DMF, as a solvent, was added thereto under a nitrogen atmosphere. The reaction mixture was stirred overnight while being kept at 160° C. The reaction was stopped with a NH₄Cl aqueous solution, and the mixture was extracted with chloroform. An organic layer separated after extraction was dried over MgSO₄, and the solvent was concentrated by a vacuum evaporator system. Through column chromatography using a mixture of toluene and hexane (1:4) as an eluent, the reaction product, 9,9′-(((2r,3r)-5-(4,6-diphenyl-1,3,5-triazine-2,3-diyl)pyridine-2,3-diyl)bis(9H-carbazole) (Compound 950), was separated (yield 1.50 g, yield 81.1%).

¹H NMR (500 MHz, CDCl₃) δ 7.03 (t, J=7.5 Hz, 2H), 7.07-7.15 (m, 6H), 7.19 (d, J=7.5 Hz, 2H), 7.36 (d, J=8.0 Hz, 2H), 7.59 (t, J=8.0 Hz, 4H), 7.65 (t, J=7.5 Hz, 2H), 7.78 (d, J=7.5 Hz, 2H), 7.87 (d, J=7.5 Hz, 2H), 8.78 (d, J=7.5 Hz, 4H), 9.48 (s, 1H), 10.19 (s, 1H), MS (APCI) m/z 641.52 [(M+H)⁺]

The synthesized compound 950 is superior to 9,9′-(((2r,3r)-5-(4,6-di-p-tolyl-1,3,5-triazine-2,3-diyl)pyridine-2,3-diyl)bis(9H-carbazole), which is a substituent of 4,6-di-p-tolyl, in the luminescence characteristics. A substituent of unsubstituted diphenyl-1,3,5-triazinyl is superior to a substituent of dialkylphenyl-1,3,5-triazinyl, in the luminescence characteristics.

(Synthesis Example 4) Synthesis of Compound 947

Synthesis of Intermediate 4-1

Under a nitrogen stream, dichlorobis(triphenylphosphine)palladium (II) (0.13 g, 0.19 mmol) was added to a THF solution (20 mL) of 2,6-difluoro-3-pyridineboronic acid (1.00 g, 6.29 mmol), 2-chloro-4,6-diphenyl-1,3,5-triazine (1.77 g, 6.61 mmol), and a 2M sodium carbonate aqueous solution (6.3 mL, 12.6 mmol), followed by heat-reflux for 12 h. The reaction solution was returned to a room temperature, and then was quenched through addition of water and was extracted with dichloromethane. The solvent was distilled off with an evaporator, and then through purification with silica gel column chromatography (hexane:toluene=1:1), Intermediate 4-1 (2.00 g, 5.77 mmol, yield 91.7%) was obtained as a white solid.

¹H NMR (400 MHz, CDCl₃) δ 7.05-7.07 (m, 1H), 7.57-7.64 (m, 6H), 8.74 (d, J=6.8 Hz, 1H), 9.11 (dd, J=9.2 Hz, J=8.4 Hz, 1H)

ASAP MS spectral analysis: C₂₀H₁₂F₂N₄: theoretical value 346, observed value 347.

Synthesis of Compound 947

Under a nitrogen stream, a dimethylformamide solution (10 mL) of 9H-carbazole (0.87 g, 5.20 mmol), potassium carbonate (0.72 g, 5.20 mmol), and intermediate 4-1 (0.60 g, 1.73 mmol) was stirred at 120° C. overnight. This mixture was returned to a room temperature, and then was quenched through addition of a saturated ammonium chloride solution and was extracted with chloroform. The solvent was distilled off with an evaporator, and then through purification with silica gel column chromatography (toluene:hexane), Compound 947 (1.10 g, 1.72 mmol, yield 99.1%) was obtained.

¹H NMR (400 MHz, CDCl₃) δ 7.21 (t, J=6.8 Hz, 2H), 7.27-7.38 (m, 13H), 8.00 (d, J=8.4 Hz, 3H), 8.08 (d, J=6.8 Hz, 3H), 8.12 (d, J=6.8 Hz, 2H), 8.19 (d, J=8.0 Hz, 2H), 9.13 (d, J=8.8 Hz, 1H).

ASAP MS spectral analysis: C₄₄H₂₈N₅: theoretical value 640, observed value 640.

(Synthesis Example 5) Synthesis of Compound 5225

Synthesis of Intermediate 5-1

Under a nitrogen stream, a dimethylformamide solution (20 mL) of 9H-carbazole (0.48 g, 2.89 mmol), potassium carbonate (0.51 g, 3.76 mmol), and Compound 1 (1.0 g, 2.89 mmol) was stirred at 70° C. overnight. This mixture was returned to a room temperature, and then was quenched through addition of a saturated ammonium chloride solution, and was extracted with chloroform. The solvent was distilled off with an evaporator, and then through purification with silica gel column chromatography (toluene:hexane), Intermediate 5-1 (1.08 g, 2.19 mmol, yield 75.7%) was obtained.

¹H NMR (400 MHz, CDCl₃) δ 7.38 (t, J=7.2 Hz, 2H), 7.51 (t, J=8.4 Hz, 2H), 7.58-7.66 (m, 6H), 7.79 (d, J=8.0 Hz, 1H), 8.12 (t, J=8.0 Hz, 4H), 8.78 (d, J=6.4 Hz, 4H), 9.20 (t, J=9.6 Hz, 1H).

ASAP MS spectral analysis: C₃₂H₂₀FN₅: theoretical value 493, observed value 494.

Synthesis of Compound 5225

Under a nitrogen stream, a dimethylformamide solution (30 mL) of 12H-[3,2-a]-benzofurocarbazole (0.76 g, 2.96 mmol), potassium carbonate (0.41 g, 2.96 mmol), and Intermediate 5-1 (0.73 g, 1.48 mmol) was stirred at 110° C. overnight. This mixture was returned to a room temperature, and then was quenched through addition of a saturated ammonium chloride solution, and was extracted with chloroform. The solvent was distilled off with an evaporator, and then through purification with silica gel column chromatography (toluene:hexane), Compound 5225 (0.91 g, 1.25 mmol, yield 84.1%) was obtained.

¹H NMR (400 MHz, CDCl₃) δ 6.21 (d, J=7.6 Hz, 1H), 6.94 (t, J=6.8 Hz, 1H), 7.23-7.47 (m, 15H), 7.55 (d, J=7.6 Hz, 1H), 7.87 (d, J=7.6 Hz, 4H), 8.02 (d, J=8.8 Hz, 2H), 8.08 (t, J=6.8 Hz, 4H), 8.22 (d, J=8.4 Hz, 1H), 9.14 (d, J=8.8 Hz, 1H).

ASAP MS spectral analysis: C₅₀H₃₀N₆₀: theoretical value 730, observed value 731.

(Synthesis Example 6) Synthesis of Compound 5223

Under a nitrogen stream, a dimethylformamide solution (30 mL) of 12H-[3,2-a]-benzofurocarbazole (0.93 g, 3.61 mmol), potassium carbonate (0.60 g, 4.33 mmol), and Compound 1 (0.50 g, 1.44 mmol) was stirred at 100° C. overnight. This mixture was returned to a room temperature, and then was quenched through addition of a saturated ammonium chloride solution and was extracted with chloroform. The solvent was distilled off with an evaporator, and then through purification with silica gel column chromatography (toluene:hexane), Compound 5223 (0.70 g, 0.85 mmol, yield 59.2%) was obtained.

¹H NMR (400 MHz, CDCl₃) δ 6.34 (d, J=8.0 Hz, 1H), 6.72 (d, J=7.6 Hz, 1H), 6.90 (t, J=6.8 Hz, 1H), 7.10 (t, J=7.6 Hz, 1H), 7.18 (t, J=6.8 Hz, 1H), 7.24-7.35 (m, 8H), 7.41-7.47 (m, 5H), 7.54-7.56 (m, 1H), 7.67-7.73 (m, 3H), 7.88-7.91 (m, 4H), 7.95 (d, J=8.4 Hz, 1H) 8.01 (d, J=8.4 Hz, 1H), 8.05-8.11 (m, 2H), 8.24 (d, J=8.0 Hz, 1H), 9.04 (d, J=8.0 Hz, 1H).

ASAP MS spectral analysis: C₅₆H₃₂N₆O₂: theoretical value 820, observed value 821.

(Synthesis Example 7) Synthesis of Compound 90

Synthesis of Intermediate 7-1

Under a nitrogen stream, a 1M diisopropylamide lithium solution (5.23 mL, 5.23 mmol) was added little by little to a tetrahydrofuran solution (15 mL) of 2,4-difluoro-3-phenylpyridine (1.0 g, 5.23 mmol), and 2-isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane bromobenzene (0.97 g, 5.23 mmol), which was cooled to −85° C. After 10 min, the temperature was raised to −75° C., and stirring was performed for 1 h. This mixture was slowly returned to a room temperature, and then 2-chloro-4,6-diphenyl-1,3,5-triazine (1.68 g, 6.28 mmol), a 2M sodium carbonate aqueous solution (3.9 mL, 7.85 mmol), tetrahydrofuran (20 mL), and tetrakis(triphenylphosphine)palladium(0) (0.3 g, 0.26 mmol) were added thereto, followed by heat-reflux for 12 h. The reaction solution was returned to a room temperature, and then was quenched through addition of water and was extracted with chloroform. The solvent was distilled off with an evaporator, and then through purification with silica gel column chromatography (hexane:toluene=1:1), Intermediate 7-1 (1.77 g, 4.19 mmol, yield 80.1%) was obtained as a white solid.

¹H NMR (400 MHz, CDCl₃) δ 7.50-7.65 (m, 11H), 8.77-8.76 (m, 4H), 9.32 (d, J=9.6 Hz, 1H).

ASAP MS spectral analysis: C₂₆H₁₆F₂N₄: theoretical value 422, observed value 423.

Synthesis of Compound 960

Under a nitrogen stream, a dimethylformamide solution (10 mL) of 9H-carbazole (1.19 g, 7.10 mmol), potassium carbonate (1.31 g, 9.47 mmol), and Compound 7-1 (1.0 g, 2.37 mmol) was stirred at 120° C. overnight. This mixture was returned to a room temperature, and then was quenched through addition of a saturated ammonium chloride solution, and was extracted with chloroform. The solvent was distilled off with an evaporator, and then through purification with silica gel column chromatography (toluene:hexane), Compound 960 (1.60 g, 2.23 mmol, yield 94.2%) was obtained.

¹H NMR (400 MHz, CDCl₃) δ 6.56 (t, J=7.6 Hz, 2H), 6.64 (t, J=7.2 Hz, 1H), 6.74 (d, J=7.2 Hz, 2H), 7.13 (t, J=7.6 Hz, 4H), 7.19-7.24 (m, 4H), 7.30-7.35 (m, 8H), 7.48 (d, J=7.2 Hz, 2H), 7.86 (d, J=7.2 Hz, 2H), 8.00 (t, J=8.4 Hz, 6H), 9.71 (s, 1H).

ASAP MS spectral analysis: C₅₀H₃₂N₆: theoretical value 716, observed value 717.

Compounds 1 to 5231, excluding the compounds synthesized in Synthesis Examples 1 to 7, can also be similarly synthesized.

Examples and Comparative Examples

Compound 939 and a host material were vapor-deposited on a quartz substrate by a vacuum deposition method under a condition of a vacuum degree of 5×10⁻⁵ Pa or less from different vapor deposition sources to form a thin film having a thickness of 100 nm in which the content of the compound 939 was 20 mass %. This was used as a doped thin film in Example 1. Further, thin films were formed only with a change in a point that Compound 947, Compound 5225, Compound 5223, Compound 960, and the following Comparative Compound A were used instead of the Compound 939. These were used as doped thin films in Examples 2 to 5, and Comparative Example 1. Each prepared doped thin film was irradiated with excitation light of 360 nm, and an emission spectrum and a transient decay curve of light emission were measured. Delayed fluorescence was observed from all thin films. Table 2 illustrates the emission maximum wavelength λmax, the emission quantum yield PLQY, and the lifetime τ_(d) of delayed fluorescence (unit: milliseconds).

Further, Compound 939 was vapor-deposited alone on a quartz substrate by a vacuum deposition method under a condition of a vacuum degree of 5×10⁻⁵ Pa or less to form a neat thin film of Example 1. Under the same conditions, Compound 947, Compound 5225, Compound 5223, Compound 960, and Comparative compound A were vapor-deposited alone to form neat thin films of Examples 2 to 5, and Comparative Example 1. Energy levels of HOMO and LUMO of each compound were measured by using each neat thin film, and Table 2 illustrates the results.

TABLE 2 Compound No. PLQY (%) Λmax (nm) τ_(d) (μs) HOMO (eV) LUMO (eV) Example 1 Compound 939 77 493 9.3 6.13 3.25 Example 2 Compound 947 70 492 4.0 5.92 3.10 Example 3 Compound 5225 82 472 — 6.04 3.20 Example 4 Compound 5223 77 489 8.5 6.00 3.08 Example 5 Compound 960 80 473 3.9 5.97 3.07 Comparative Comparative 50 534 19.0  6.00 3.51 Example 1 Compound A

The results of Table 2 indicate that the compound represented by the formula (1) has a better luminous efficiency, and a shorter delayed fluorescence lifetime than Comparative compound A. Further, these also indicate that the compound represented by the formula (1) is useful as a blue light-emitting material. Like in the compound 939, in other compounds synthesized in Synthesis Examples as well, excellent luminescence characteristics are recognized.

INDUSTRIAL APPLICABILITY

The compound of the present invention has excellent luminescence characteristics, and is also useful as a delayed fluorescence material. Thus, the light-emitting material of the present invention is effectively used for an organic optical device such as an organic electroluminescence device. Therefore, the present invention has high industrial applicability. 

1. A compound represented by the following formula (1),

wherein, among R¹ to R⁵, one of R¹ and R² is A, among the rest of R¹ to R⁵, p are D's, and the remaining 4-p are R's, here, A is a group represented by Het-L^(A)-* or CN-L^(A)-*, in which Het represents a substituted or unsubstituted heteroaryl group bonded via a carbon atom and at least one nitrogen atom is included as a ring skeleton-forming atom of the heteroaryl group, L^(A) represents a single bond or a substituted or unsubstituted arylene group, and * represents a bond position, D is a group represented by the following formula (IIa), (IIb), (IIc) or (IId),

here, X′ represents N—R^(D)′, an oxygen atom, or a sulfur atom, each R^(D) independently represents a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted amino group, a cyano group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted heteroaryl group, a substituted or unsubstituted heteroaryloxy group or a silyl group, and two or more R^(D)'s may be bonded to each other to form a cyclic structure, R^(D)′ represents a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heteroaryl group, and R^(D), may be bonded to one or more R^(D)'s to form a cyclic structure, each L^(D) independently represents a single bond, a substituted or unsubstituted arylene group, or a substituted or unsubstituted heteroarylene group, and * represents a bond position, R is a hydrogen atom, a deuterium atom, or a substituted or unsubstituted aryl group except a group that may be A or D, p is any integer of 1 to 3, when p is 2 or 3, D's present in the molecule may be the same or different, and when p is 1 or 2, R's present in the molecule may be the same or different.
 2. The compound according to claim 1, wherein R² is A.
 3. The compound according to claim 1, wherein R¹ is A.
 4. The compound according to claim 1, wherein at least one of R¹ to R⁵ is a hydrogen atom or a deuterium atom.
 5. The compound according to claim 1, wherein p is
 3. 6. The compound according to claim 1, wherein p is
 2. 7. The compound according to claim 1, wherein each of R⁴ and R⁵ is independently D.
 8. The compound according to claim 1, wherein A is represented by any of the following formulas (IIIa) to (IIIe),

wherein each of R²¹ to R²⁵ independently represents a hydrogen atom or a substituent, R²¹ and R²², R²² and R²³, R²³ and R²⁴, and R²⁴ and R²⁵ may be bonded to each other to form cyclic structures, and L^(A) represents a single bond or a substituted or unsubstituted arylene group.
 9. The compound according to claim 1, wherein L^(A) is a single bond.
 10. The compound according to claim 1, wherein D is a group represented by the formula (IIb). 11-12. (canceled)
 13. An organic optical device comprising the compound according to claim
 1. 14. The organic optical device according to claim 13, which is an organic light emitting diode (OLED).
 15. A compound represented by the following formula (1′),

wherein R¹ to R⁵ satisfy the following condition 1 or condition 2, (Condition 1) Among R¹ to R⁵, one of R¹ and R² is a halogen atom, among the rest of R¹ to R⁵, p are D's, and the remaining 4-p are R's, (Condition 2) Among R¹ to R⁵, one of R¹ and R² is A, among the rest of R¹ to R⁵, p are halogen atoms, and the remaining 4-p are R's, here, A is a group represented by Het-L^(A)-* or CN-L^(A)-*, in which Het represents a substituted or unsubstituted heteroaryl group bonded via a carbon atom and at least one nitrogen atom is included as a ring skeleton-forming atom of the heteroaryl group, L^(A) represents a single bond or a substituted or unsubstituted arylene group, and * represents a bond position, D is a group represented by the following formula (IIa), (IIb), (IIc) or (IId),

here, X′ represents N—R^(D)′, an oxygen atom, or a sulfur atom, each R^(D) independently represents a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted amino group, a cyano group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted heteroaryl group, a substituted or unsubstituted heteroaryloxy group or a silyl group, and two or more R^(D)'s may be bonded to each other to form a cyclic structure, R^(D), represents a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heteroaryl group, and R^(D), may be bonded to one or more R^(D)'s to form a cyclic structure, each L^(D) independently represents a single bond, a substituted or unsubstituted arylene group, or a substituted or unsubstituted heteroarylene group, and * represents a bond position, R is a hydrogen atom, a deuterium atom, or a substituted or unsubstituted aryl group except a group that may be A or D, p is any integer of 1 to 3, when p is 2 or 3, D's present in the molecule may be the same or different, and when p is 1 or 2, R's present in the molecule may be the same or different. 